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US4153648A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic nitrile resin blends

Assignee: Standard Oil Co
•
Filing: 1977-10-28
•
Granted: 1979-05-08
•
Expires: 1997-10-28
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Abstract

Abstract Blends of high-acrylonitrile thermoplastic copolymers with acrylonitrile-indene copolymers have improved softening temperatures, improved gas barrier properties and other improved physical properties.

Inventors

  • 👤 George S. Li
  • 👤 John F. Jones

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 00:53
CPC Classifications
C; C08; C08L; C08L33/00; C08L33/18; C08L33/20

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 248 words
The blend composed of 100 parts by weight of (I) a polymer prepared by the polymerization of 100 parts by weight of (A) from 50 to 90% by weight of at least one nitrile having the structure ##STR8## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (B) from 10 to 50% by weight based on the combined weight of (A) and (B) of at least one member selected from the group consisting of (1) styrene, (2) an ester having the structure ##STR9## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, (3) an alpha-olefin having the structure ##STR10## wherein R' and R" are alkyl groups having from 1 to 7 carbon atoms, (4) a vinyl ether selected from the group consisting of methyl vinyl ether, ethyl vinyl ether, the propyl vinyl ethers, and the butyl vinyl ethers, and (5) vinyl acetate, and from 5 to 15 parts by weight of (II) a polymer resulting from the copolymerization of (A) from 50 to 90% by weight of at least one nitrile having the structure ##STR11## wherein R has the foregoing designation, (B) from 10 to 50% by weight of indene, and (C) from 0 to 40% by weight of an ester having the structure ##STR12## wherein R 1 and R 2 have the foregoing designations.
Claim 2
Dependent Claim 248 words
The blend composed of 100 parts by weight of (I) a polymer prepared by the polymerization of 100 parts by weight of (A) from 50 to 90% by weight of at least one nitrile having the structure ##STR8## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, and (B) from 10 to 50% by weight based on the combined weight of (A) and (B) of at least one member selected from the group consisting of (1) styrene, (2) an ester having the structure ##STR9## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, (3) an alpha-olefin having the structure ##STR10## wherein R' and R" are alkyl groups having from 1 to 7 carbon atoms, (4) a vinyl ether selected from the group consisting of methyl vinyl ether, ethyl vinyl ether, the propyl vinyl ethers, and the butyl vinyl ethers, and (5) vinyl acetate, and from 5 to 15 parts by weight of (II) a polymer resulting from the copolymerization of (A) from 50 to 90% by weight of at least one nitrile having the structure ##STR11## wherein R has the foregoing designation, (B) from 10 to 50% by weight of indene, and (C) from 0 to 40% by weight of an ester having the structure ##STR12## wherein R 1 and R 2 have the foregoing designations.
Claim 3
Dependent Claim 10 words
The blend of claim 1 wherein (I) (A) is acrylonitrile.
Claim 4
Dependent Claim 11 words
The blend of claim 2 wherein (I) (B) (1) is styrene.
Claim 5
Dependent Claim 12 words
The blend of claim 2 wherein (I) (B) (2) is methyl acrylate.
Claim 6
Dependent Claim 10 words
The blend of claim 1 wherein (II) (A) is acrylonitrile.
Claim 7
Dependent Claim 11 words
The blend of claim 1 wherein (II) (C) is methyl acrylate.
Claim 8
Dependent Claim 16 words
The blend of claim 3 wherein (II) (A) is acrylonitrile and (II) (C) is methyl acrylate.
Claim 9
Dependent Claim 16 words
The blend of claim 4 wherein (II) (A) is acrylonitrile and (II) (C) is methyl acrylate.

References Cited (Backward Citations)

US2688008A Cited
US3674536A Cited
US3926926A Cited
US3926871A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-05-07 1982-11-06 1983-05-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-05-07 1986-11-06 1987-05-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-05-07 1990-11-06 1991-05-08 $7700.00 Window Closed / Lapsed

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