Patent US4153423A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4153423A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymer combinations useful in distillate hydrocarbon oils to improve cold flow properties

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1975-03-28
•
Granted: 1979-05-08
•
Expires: 1995-03-28
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Oil soluble ethylene polymers or copolymers having a Mn greater than about 4000 in combination with an oil soluble polyester material such as a homopolymer or copolymer, comprising at least 10% by weight C4 to C16 substantially straight-chain alkyl esters of acrylic or methacrylic acid, are useful in improving the cold flow properties of distillate hydrocarbon oils.

Inventors

  • 👤 Max J. Wisotsky

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 19:59
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/146; C10L1/16; C10L1/1625; C10L1/1633; C10L1/1641; C10L1/18; C10L1/192; C10L1/195

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 194 words
A fuel oil consisting of a middle distillate petroleum fuel oil boiling in the range of 150° C. to 400° C., and having at least about 5 wt.% boiling at a temperature greater than 350° C., which has been improved in its low temperature flow properties, containing in the range of about 0.005 to 0.1 wt.%, based on the weight of the total composition, of a synergistic flow improving combination of (a) one part by weight of an oil soluble ethylene backbone polymer having a number average molecular weight in the range of about 5000 up to 20,000 per (b) 0.2 to 4 parts by weight of an oil soluble polyester having a molecular weight in the range of about 2000 to 200,000; wherein said ethylene backbone polymer consists essentially of 4 to 20 molar proportions of ethylene with a molar proportion of ethylenically unsaturated alkyl ester selected from the group consisting of isobutyl acrylate and 2-ethylhexyl acrylate; and, wherein said polyester consists of monomer moieties of alkyl ester of acrylic or methacrylic acid, said monomer moieties consisting essentially of C 8 to C 16 straight chain alkyl ester of acrylic or methacrylic acid.
Claim 2
Dependent Claim 194 words
A fuel oil consisting of a middle distillate petroleum fuel oil boiling in the range of 150° C. to 400° C., and having at least about 5 wt.% boiling at a temperature greater than 350° C., which has been improved in its low temperature flow properties, containing in the range of about 0.005 to 0.1 wt.%, based on the weight of the total composition, of a synergistic flow improving combination of (a) one part by weight of an oil soluble ethylene backbone polymer having a number average molecular weight in the range of about 5000 up to 20,000 per (b) 0.2 to 4 parts by weight of an oil soluble polyester having a molecular weight in the range of about 2000 to 200,000; wherein said ethylene backbone polymer consists essentially of 4 to 20 molar proportions of ethylene with a molar proportion of ethylenically unsaturated alkyl ester selected from the group consisting of isobutyl acrylate and 2-ethylhexyl acrylate; and, wherein said polyester consists of monomer moieties of alkyl ester of acrylic or methacrylic acid, said monomer moieties consisting essentially of C 8 to C 16 straight chain alkyl ester of acrylic or methacrylic acid.
Claim 3
Dependent Claim 20 words
A fuel oil according to claim 1 wherein said ethylene backbone polymer is a copolymer of ethylene and isobutyl acrylate.
Claim 4
Dependent Claim 19 words
A fuel oil according to claim 1 wherein said ethylene backbone polymer is a copolymer of ethylene and 2-ethylhexylacrylate.
Claim 5
Dependent Claim 15 words
A fuel oil according to claim 1 wherein said polyester is a homopolymer of tetradecylacrylate.
Claim 6
Dependent Claim 20 words
A fuel oil according to claim 1 wherein said polyester is a copolymer consisting of hexadecyl acrylate and methyl methacrylate.

References Cited (Backward Citations)

FR1323547A Cited
US3275427A Cited
US3792983A Cited
US3620696A Cited
US3832150A Cited
US3661541A Cited
US4010006A Cited
US3726653A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-05-07 1982-11-06 1983-05-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-05-07 1986-11-06 1987-05-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-05-07 1990-11-06 1991-05-08 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag