Patent US4153423A successfully refreshed from Google Patents.
US4153423A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polymer combinations useful in distillate hydrocarbon oils to improve cold flow properties
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1975-03-28
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Granted: 1979-05-08
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Expires: 1995-03-28
Abstract
Abstract Oil soluble ethylene polymers or copolymers having a Mn greater than about 4000 in combination with an oil soluble polyester material such as a homopolymer or copolymer, comprising at least 10% by weight C4 to C16 substantially straight-chain alkyl esters of acrylic or methacrylic acid, are useful in improving the cold flow properties of distillate hydrocarbon oils.
Inventors
- 👤 Max J. Wisotsky
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 19:59
CPC Classifications
C; C10; C10L; C10L1/00; C10L1/10; C10L1/14; C10L1/146; C10L1/16; C10L1/1625; C10L1/1633; C10L1/1641; C10L1/18; C10L1/192; C10L1/195
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
194 words
A fuel oil consisting of a middle distillate petroleum fuel oil boiling in the range of 150° C. to 400° C., and having at least about 5 wt.% boiling at a temperature greater than 350° C., which has been improved in its low temperature flow properties, containing in the range of about 0.005 to 0.1 wt.%, based on the weight of the total composition, of a synergistic flow improving combination of (a) one part by weight of an oil soluble ethylene backbone polymer having a number average molecular weight in the range of about 5000 up to 20,000 per (b) 0.2 to 4 parts by weight of an oil soluble polyester having a molecular weight in the range of about 2000 to 200,000; wherein said ethylene backbone polymer consists essentially of 4 to 20 molar proportions of ethylene with a molar proportion of ethylenically unsaturated alkyl ester selected from the group consisting of isobutyl acrylate and 2-ethylhexyl acrylate; and, wherein said polyester consists of monomer moieties of alkyl ester of acrylic or methacrylic acid, said monomer moieties consisting essentially of C 8 to C 16 straight chain alkyl ester of acrylic or methacrylic acid.
Claim 2
Dependent Claim
194 words
A fuel oil consisting of a middle distillate petroleum fuel oil boiling in the range of 150° C. to 400° C., and having at least about 5 wt.% boiling at a temperature greater than 350° C., which has been improved in its low temperature flow properties, containing in the range of about 0.005 to 0.1 wt.%, based on the weight of the total composition, of a synergistic flow improving combination of (a) one part by weight of an oil soluble ethylene backbone polymer having a number average molecular weight in the range of about 5000 up to 20,000 per (b) 0.2 to 4 parts by weight of an oil soluble polyester having a molecular weight in the range of about 2000 to 200,000; wherein said ethylene backbone polymer consists essentially of 4 to 20 molar proportions of ethylene with a molar proportion of ethylenically unsaturated alkyl ester selected from the group consisting of isobutyl acrylate and 2-ethylhexyl acrylate; and, wherein said polyester consists of monomer moieties of alkyl ester of acrylic or methacrylic acid, said monomer moieties consisting essentially of C 8 to C 16 straight chain alkyl ester of acrylic or methacrylic acid.
Claim 3
Dependent Claim
20 words
A fuel oil according to claim 1 wherein said ethylene backbone polymer is a copolymer of ethylene and isobutyl acrylate.
Claim 4
Dependent Claim
19 words
A fuel oil according to claim 1 wherein said ethylene backbone polymer is a copolymer of ethylene and 2-ethylhexylacrylate.
Claim 5
Dependent Claim
15 words
A fuel oil according to claim 1 wherein said polyester is a homopolymer of tetradecylacrylate.
Claim 6
Dependent Claim
20 words
A fuel oil according to claim 1 wherein said polyester is a copolymer consisting of hexadecyl acrylate and methyl methacrylate.
References Cited (Backward Citations)
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Cited
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US3620696A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-05-07 | 1982-11-06 | 1983-05-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-05-07 | 1986-11-06 | 1987-05-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-05-07 | 1990-11-06 | 1991-05-08 | $7700.00 | Window Closed / Lapsed |