Cell regulators in structural foams

Claim 2

In the preparation of structural foams from foamable polyphenylene oxide resins, the method of improving the cellulose structure of such foams which comprises incorporating into the resin composition prior to blowing thereof 0.5 to 5 parts per hundred parts by weight of said resin composition of a cell regulating additive comprising an acrylamide polymer containing at least 80% of the moiety of the formula ##STR8## wherein R 1 is H or an alkyl group of 1 to 4 carbon atoms wherein R 2 and R 3 are independently selected from the group consisting of H, hydrocarbyl of 1 to 20 carbon atoms and oxygenated hydrocarbyl radicals; provided that when R 2 is other than H or a linear alkyl of 1 to 10 carbon atoms, R 3 must be H.

Claim 3

The method as defined in claim 1 wherein said acrylamide polymer is a homopolymer of acrylamide having an average molecular weight below 20,000.

Claim 4

The method as defined in claim 2 wherein said polyphenylene oxide resin comprises a blend of polyphenylene oxide and polystyrene.

Claim 5

The method as defined in claim 3 wherein said acrylamide polymer is an interpolymer obtained by co-polymerizing an acrylamide compound with another monomer containing a vinyl group.

Claim 6

The method as defined in claim 4 wherein said vinyl group-containing monomer is styrene.

Claim 7

The method as defined in claim 4 wherein said vinyl group-containing monomer is an alkyl acrylate or alkyl methacrylate.

Claim 8

The method as defined in claim 4 wherein said vinyl group-containing monomer is a C 10 to C 20 alkyl acrylate or methacrylate.

Claim 9

The method as defined in claim 4 wherein said vinyl group-containing monomer is a vinyl ester of a C 10 to C 20 fatty acid.

Claim 10

Molding composition for the production of formed structural foam resin articles comprising a foamable polyphenylene oxide-polystyrene resin blend, a chemical blowing agent, and 0.5 to 5 parts per hundred parts by weight of said resin blend of a cell regulator for said foam, said cell regulator consisting essentially of an acrylamide polymer having an acrylamide content of at least 80%.

Claim 11

Molding composition for the production of formed structural foam resin articles comprising a foamable polyphenylene oxide-polystyrene resin blend, a chemical blowing agent, and 0.5 to 5 parts per hundred parts by weight of said resin blend of a cell regulator for said foam, said cell regulator consisting essentially of an acrylamide polymer having an acrylamide content of at least 80%.

Claim 12

Composition as defined in claim 9 wherein said acrylamide polymer is one having an average molecular weight of less than 20,000.

Claim 13

Composition as defined in claim 10 wherein said acrylamide polymer is a homopolymer of acrylamide having an intrinsic viscosity of about 0.15.

Claim 14

Composition as defined in claim 9 wherein said acrylamide is an interpolymer of an acrylamide compound with at least one other monomer compound containing a vinyl group.

Claim 15

Composition as defined in claim 12 wherein said other monomer compound corresponds to the formula: ##STR9## wherein R 4 and R 5 are independently selected from the group consisting of H, hydrocarbyl of 1 to 20 carbon atoms and substituents of hereinafter recited groups (A), (B), (C) and (D), provided that if R 4 is H, hydrocarbyl or (A) then R 5 , is taken from group (B), (C) or (D); said group (A) consisting of hydrocarbyl of 1 to 20 carbon atoms substituted by one or more substituents from the group consisting of halogen, cyano, hydroxy, mercapto, acyl of 1 to 20 carbon atoms, carboxyalkyl of 1 to 20 carbon atoms, oxyacyl of 1 to 20 carbon atoms, amino, mono- and dialkyl amino having 1 to 20 carbon atoms in the alkyl group; said group (B) consisting of halogen, cyano, oxa-alkyl, thia-alkyl, acyl of 1 to 10 carbon atoms, --SO 3 H, pyridyl, imidazolyl, pyrrolidyl, pyrrolidonyl and furanyl; said group (C) consisting of carboxyalkyl residues of the formula ##STR10## wherein R 6 is H, hydrocarbyl of 1 to 20 carbon atoms, oxa-alkenyl, thia-alkenyl, hydrocarbyl of 1 to 20 carbon atoms substituted by at least one substituent of the above-recited (A) group, furfuryl, tetrahydrofurfuryl, and polyalkylene glycols of the formulae -- (CH.sub.2 -- CH.sub.2 -- O).sub.m -- R.sub.7 and -- (CH.sub.2 -- CH(CH.sub.3) -- O).sub.m -- R.sub.7 wherein m is 2 to 15 and R 7 is H or a hydrocarbyl radical of 1 to 10 carbon atoms; and said group (D) consists of oxyacyl residues of the formula ##STR11## wherein R 8 is H, hydrocarbyl of 1 to 20 carbon atoms, or a substituted hydrocarbyl radical containing one or more substituents from the above-recited (A) group.

Claim 16

Composition as defined in claim 12 wherein said other monomer compound is styrene.

Claim 17

Composition as defined in claim 12 wherein said other monomer is a C 10 to C 20 alkyl acylate or methacrylate.

Claim 18

Composition as defined in claim 9 wherein said acylamide polymer has an acrylamide content of above 85%.

Claim 19

Composition as defined in claim 9 wherein said acrylamide polymer is one obtained by copolymerizing of two different acrylamides each corresponding to the structural formula ##STR12## wherein: R 1 is H or a lower alkyl group and R 2 and R 3 are each independently selected from the group consisting of H, hydrocarbyl of 1 to 20 carbon atoms, and oxygenated hydrocarbyl radicals; provided that if R 2 is other than H or a linear alkyl group of 1 to 10 carbon atoms, then R 3 is H.

Claim 20

Molding composition for the production of formed structural foam resin articles, comprising a foamable blend of polyphenylene oxide-polystyrene resins, a chemical blowing agent and a cell regulator for such foam, said cell regulator consisting essentially of a copolymer of acrylamide and stearyl methacrylate.

Claim 21

Molding composition for the production of formed structural foam resin articles, comprising a foamable blend of polyphenylene oxide-polystyrene resins, a chemical blowing agent and a cell regulator for such foam, said cell regulator consisting essentially of a copolymer of acrylamide and stearyl methacrylate.

Claim 22

Molding composition for the production of formed structural foam resin articles, comprising a foamable blend of polyphenylene oxide - polystyrene resins, a chemical blowing agent comprising p-toluene sulfonyl semicarbazide, and a cell regulator for such foam, said cell regulator consisting essentially of a copolymer of acrylamide and N-t-butyl acrylamide.

Claim 23

Molding composition for the production of formed structural foam resin articles, comprising a foamable blend of polyphenylene oxide - polystyrene resins, a chemical blowing agent comprising p-toluene sulfonyl semicarbazide, and a cell regulator for such foam, said cell regulator consisting essentially of a copolymer of acrylamide and N-t-butyl acrylamide.