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US4151158A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymer composition and method of using same to produce thermostable insulating materials

Assignee: Individual
•
Filing: 1977-01-17
•
Granted: 1979-04-24
•
Expires: 1997-01-17
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Abstract

Abstract According to the invention, the polymer composition comprises 8 to 20 parts by weight of polyborsiloxane having a molecular weight of 2,000 to 5,000 and including structural units [BOSi] [(CH 3 ) 2 SiO] with a B:Si molar ratio of 1:4 to 5, 40 to 90 parts by weight of polysiloxane rubber, 10 to 60 parts by weight of an organic polymer which may be polyolefins, copolymers of olefins and dienes, halogenated polyolefins, and halogenated copolymers of olefins and dienes, taken separately or in combination with one another, 2 to 10 parts by weight of branched polyorganosiloxane having a molecular weight of 2,000 to 5,000, of the general formula: ##STR1## WHEREIN: R=CH 3 , C 6 H 5 , a=43 to 50 mole %, b=0 to 2 mole %, c=50 to 55 mole %, as well as 10 to 25 parts by weight of silicon dioxide, and 5 to 10 parts by weight of a variable valency metal oxide. The proposed method of producing thermostable insulating materials from said polymer composition comprises molding said polymer composition on a substrate so as to obtain a blank which is then exposed to ionizing radiation until the absorbed radiation dose reaches 6 to 35 megarads. Thus, on the basis of the proposed polymer composition there are produced thermostable insulating materials which at room temperature have an adhesion to organic polymers of 3 to 6 kgf/cm 2 and to metals, 3 to 7 kgf/cm 2 . Such materials are self-adhesive at room temperatures. They also possess satisfactory physico-mechanical and dielectric properties, as well as high thermal, cold and ozone resistance. The proposed method of producing thermostable insulating materials is quite simple technologically.

Inventors

  • 👤 Isaak Y. Poddubny
  • 👤 Sergei V. Averyanov
  • 👤 Lidia A. Averyanova
  • 👤 Mark P. Grinblat
  • 👤 Rinat R. Safin
  • 👤 Alexandr K. Breger
  • 👤 Vladimir A. Goldin
  • 👤 Elena Z. Branzburg
  • 👤 Viktor S. Kondratovsky
  • 👤 Albert G. Kabirov
  • 👤 Alexandr T. Sanzharovsky
  • 👤 Valeria B. Shtukareva
  • 👤 Jury N. Svatikov
  • 👤 Nadezhda M. Stepanova

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 07:43
CPC Classifications
C; C08; C08L; C08L23/00; C08L57/00; C08L83/00; C08L83/14

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 159 words
A polymer composition comprising 8 to 20 parts by weight of polyborsiloxane having a molecular weight of 2,000 to 5,000 and containing structural units [BoSi] [(CH 3 ) 2 SiO] with a B:Si molar ratio of 1:4 to 5, 40 to 90 parts by weight of polysiloxane rubber, 10 to 60 parts by weight of an organic polymer selected from the group consisting of polyolefine, copolymers of olefins and dienes, halogenated polyolefins and halogenated copolymers of olefins and dienes, 2 to 10 parts by weight of branched polyorganosiloxane having a molecular weight of 2,000 to 5,000 of the general formula: ##STR6## wherein: R is a radical selected from the group of radicals composed of CH 3 , C 6 H 5 ; a=43 to 50 mole %, b=0 to 2 mole %, c=50 to 55 mole %, 10 to 25 parts by weight of silicon dioxide, and 5 to 10 parts by weight of a variable valency metal oxide.
Claim 2
Dependent Claim 159 words
A polymer composition comprising 8 to 20 parts by weight of polyborsiloxane having a molecular weight of 2,000 to 5,000 and containing structural units [BoSi] [(CH 3 ) 2 SiO] with a B:Si molar ratio of 1:4 to 5, 40 to 90 parts by weight of polysiloxane rubber, 10 to 60 parts by weight of an organic polymer selected from the group consisting of polyolefine, copolymers of olefins and dienes, halogenated polyolefins and halogenated copolymers of olefins and dienes, 2 to 10 parts by weight of branched polyorganosiloxane having a molecular weight of 2,000 to 5,000 of the general formula: ##STR6## wherein: R is a radical selected from the group of radicals composed of CH 3 , C 6 H 5 ; a=43 to 50 mole %, b=0 to 2 mole %, c=50 to 55 mole %, 10 to 25 parts by weight of silicon dioxide, and 5 to 10 parts by weight of a variable valency metal oxide.
Claim 3
Dependent Claim 24 words
A polymer composition as claimed in claim 1, wherein the polyolefin is polyisobutylene taken in an amount of 20 to 60 parts by weight.
Claim 4
Dependent Claim 24 words
A polymer composition as claimed in claim 1, wherein the polyolefin is polyethylene taken in an amount of 10 to 15 parts by weight.
Claim 5
Dependent Claim 40 words
A polymer composition as claimed in claim 1, wherein the polyolefin is a copolymer of ethylene and propylene having a propylene content of 35 to 40 mole % and taken in an amount of 5 to 20 parts by weight.
Claim 6
Dependent Claim 42 words
A polymer composition as claimed in claim 1, wherein the copolymer of olefin and diene is a copolymer of isobutylene and isoprene containing 0.6 to 3 mole % of isoprene and taken in an amount of 20 to 60 parts by weight.
Claim 7
Dependent Claim 56 words
A polymer composition as claimed in claim 1, wherein the copolymer of olefin and diene is a copolymer of ethylene, propylene and ethylidene norbornane taken in an amount of 5 to 20 parts by weight and having a propylene content of 35 to 40 mole % and ethylidene norbornane content of 1 to 3 mole %.
Claim 8
Dependent Claim 26 words
A polymer composition as claimed in claim 1, wherein the halogenated polyolefin is bromated polyisobutylene taken in an amount of 20 to 60 parts by weight.
Claim 9
Dependent Claim 46 words
A polymer composition as claimed in claim 1, wherein the halogenated copolymer of olefin and diene is a bromated copolymer of isobutylene and isoprene taken in an amount of 20 to 60 parts by weight and having an isoprene content of 0.6 to 3 mole %.
Claim 10
Dependent Claim 21 words
A polymer composition as claimed in claim 1, which includes N-bromosuccinimide in an amount of 2 to 6 parts by weight.

References Cited (Backward Citations)

US2569540A Cited
US3255154A Cited
CH531776A Cited
GB1282285A Cited
US3655565A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-04-23 1982-10-23 1983-04-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-04-23 1986-10-23 1987-04-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-04-23 1990-10-23 1991-04-24 $7700.00 Window Closed / Lapsed

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