Patent US4149867A successfully refreshed from Google Patents.
US4149867A
Expired / Lapsed
US
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Method of producing an optical fiber
Assignee: Fujitsu Ltd
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Filing: 1977-06-30
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Granted: 1979-04-17
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Expires: 1997-06-30
Abstract
Abstract An improved method of producing an optical fiber with a low transmission loss for use in an optical communication system. The method comprises a chemical vapor deposition process wherein starting materials in gas phase are oxidized to form a soot on a glass substrate, and the soot which deposits on the substrate is vitrified in an atmosphere of an inert gas which is easily dissolved in the vitrified glass. A preferable soot contains silicon dioxide, a first dopant for effecting an increase of the refraction index of the silicon dioxide and a second dopant for effecting a reduction of the vitrification temperature of the soot.
Inventors
- 👤 Takeshi Akamatsu
- 👤 Koji Okamura
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 19:34
CPC Classifications
C; C03; C03B; C03B37/00; C03B37/01; C03B37/012; C03B37/014; C03B37/018; C03B37/01807; C03B37/01853; C03B2201/00; C03B2201/06; C03B2201/30; C03B2201/31; C03B2207/00; C03B2207/80; C03B2207/85; C03B2207/86
Claims Analysis
Total Claims: 30
Claim 1
Independent Claim
110 words
In a method of producing an optical fiber comprising a gas phase chemcial reaction process wherein starting materials in gas phase are oxidized to form a soot so that the soot is deposited on a glass substrate and said deposited soot is vitrified by fusing; the improvement wherein the step of forming said soot and the step of vitrifying said soot are carried out simultaneously, and the oxidation of said starting materials, the deposition of said soot and the fusing of said soot take place in an atmosphere of an inert gas which is easily dissolved in said fused soot, said inert gas flowing over the length of said substrate.
Claim 2
Dependent Claim
110 words
In a method of producing an optical fiber comprising a gas phase chemcial reaction process wherein starting materials in gas phase are oxidized to form a soot so that the soot is deposited on a glass substrate and said deposited soot is vitrified by fusing; the improvement wherein the step of forming said soot and the step of vitrifying said soot are carried out simultaneously, and the oxidation of said starting materials, the deposition of said soot and the fusing of said soot take place in an atmosphere of an inert gas which is easily dissolved in said fused soot, said inert gas flowing over the length of said substrate.
Claim 3
Dependent Claim
45 words
A method of producing an optical fiber according to claim 1, wherein said soot comprises silicon dioxide, a first dopant for effecting an increase of the refraction index of the silicon dioxide and a second dopant for lowering the vitrification temperature of the silicon dioxide.
Claim 4
Dependent Claim
25 words
A method of producing an optical fiber according to claim 2, wherein said first dopant comprises germanium dioxide and said second dopant is phosphorus pentoxide.
Claim 5
Dependent Claim
17 words
A method of producing an optical fiber according to claim 1, wherein said inert gas comprises helium.
Claim 6
Dependent Claim
17 words
A method of producing an optical fiber according to claim 1, wherein said inert gas is argon.
Claim 7
Independent Claim
164 words
A method of producing an optical fiber comprising: bubbling at least one carrier gas through at least one starting material in liquid phase to generate said starting material(s) into a gas phase; introducing said gas phase starting materials with said carrier gases into a tube reactor of silica glass; introducing a reactant gas comprising oxygen into said reactor; introducing an inert gas into said reactor, said inert gas being easily dissolved in the vitrified soot to be produced; heating said reactor at a local zone, said local zone being shifted toward the output end of said reactor along the length of said reactor, thereby effecting a reaction of said gas phase starting materials with said oxygen to produce a soot that is deposited in the form of a layer on the inner surface of said reactor and vitrifying said deposited soot layer by the fusing of said soot into glass, said soot production, deposition and vitrification occuring simultaneously as a result of said heating.
Claim 8
Independent Claim
164 words
A method of producing an optical fiber comprising: bubbling at least one carrier gas through at least one starting material in liquid phase to generate said starting material(s) into a gas phase; introducing said gas phase starting materials with said carrier gases into a tube reactor of silica glass; introducing a reactant gas comprising oxygen into said reactor; introducing an inert gas into said reactor, said inert gas being easily dissolved in the vitrified soot to be produced; heating said reactor at a local zone, said local zone being shifted toward the output end of said reactor along the length of said reactor, thereby effecting a reaction of said gas phase starting materials with said oxygen to produce a soot that is deposited in the form of a layer on the inner surface of said reactor and vitrifying said deposited soot layer by the fusing of said soot into glass, said soot production, deposition and vitrification occuring simultaneously as a result of said heating.
Claim 9
Dependent Claim
76 words
A method of producing an optical fiber according to claim 6 wherein: the flow rate of said oxygen is set at a value as low as possible, but enough to effect substantially said reaction with said starting materials in gas phase; and, the flow rate of the gas mixture comprising said starting materials in gas phase, said oxygen, said carrier gas and said inert gas is controlled to produce said soot layer with a predetermined thickness.
Claim 10
Dependent Claim
23 words
A method of producing an optical fiber according to claim 6 wherein said starting materials comprise silicon tetrachloride, germanium tetrachloride, and phosphorus trichloride.
Claim 11
Dependent Claim
17 words
A method of producing an optical fiber according to claim 6, wherein said inert gas is helium.
Claim 12
Dependent Claim
17 words
A method of producing an optical fiber according to claim 6, wherein said inert gas is argon.
Claim 13
Dependent Claim
19 words
The method of claim 6, said inert gas flowing the length of said tube reactor where said deposition occurs.
Claim 14
Independent Claim
160 words
A method for producing a high quality preform rod having no voids, said method comprising flowing at least three gases into a glass tube for transfer along said tube, at least one of said gases being an inert gas which dissolves in the vitrified glass to be formed without reaction therewith, and at least two other of said gases being such as to react together upon heating to produce soot particles, and repeatedly heating said glass tube by moving a source of heat in thermal contact with said tube in the direction of said flowing gases, and heating being applied evenly overtime around the periphery of said tube during said motion, whereby each said repeated heating resulting the simultaneous formation of said soot, the deposition of said soot and the fusing of said deposited soot into an even layer of said vitrified glass without any of said voids, said layer having a predetermined thickness on the inside of said tube.
Claim 15
Independent Claim
160 words
A method for producing a high quality preform rod having no voids, said method comprising flowing at least three gases into a glass tube for transfer along said tube, at least one of said gases being an inert gas which dissolves in the vitrified glass to be formed without reaction therewith, and at least two other of said gases being such as to react together upon heating to produce soot particles, and repeatedly heating said glass tube by moving a source of heat in thermal contact with said tube in the direction of said flowing gases, and heating being applied evenly overtime around the periphery of said tube during said motion, whereby each said repeated heating resulting the simultaneous formation of said soot, the deposition of said soot and the fusing of said deposited soot into an even layer of said vitrified glass without any of said voids, said layer having a predetermined thickness on the inside of said tube.
Claim 16
Dependent Claim
21 words
The method of claim 12, said motion of said heat source being in the direction of flow of said flowing gases.
Claim 17
Dependent Claim
22 words
The method of claim 12, said inert gas comprising at least one gas chosen from the group consisting of argon and helium.
Claim 18
Dependent Claim
16 words
The method of claim 12, said at least two other gases comprising oxygen and silicon tetrachloride.
Claim 19
Dependent Claim
36 words
The method of claim 15, the relative amount of said oxygen being such as to prevent the accumulation of oxygen and the product gases of said reaction from accumulating in the interstices of said deposited soot.
Claim 20
Dependent Claim
26 words
The method of claim 15, each said repeated heating producing one of said layers of said vitrified glass with a thickness of at least 20 microns.
Claim 21
Dependent Claim
38 words
The method of claim 12, comprising the step of generating at least one of said gases from the liquid state by means of passing at least one carrier gas through each said liquid state source of said gas(es).
Claim 22
Dependent Claim
32 words
The method of claim 12, said gases including at least one dopant gas for selectively increasing the index of refraction of said vitrified glass and for decreasing the temperature of said fusing.
Claim 23
Dependent Claim
23 words
The method of claim 18, said dopants comprising at least one dopant selected from the group consisting of germanium dioxide and phosphorus pentoxide.
Claim 24
Dependent Claim
38 words
The method of claim 12, said source of heat comprising a flame, said method further comprising rotating said tube and said moving of said flame comprising motion along a straight line parallel to the axis of said tube.
Claim 25
Independent Claim
185 words
A method for forming in a closed system a high quality preform rod having no voids, said method comprising: a first step that includes flowing at least three gases into a glass tube for transfer along the length of said tube, at least one of said gases being an inert gas which dissolves in the vitrified glass to be formed without reacting therewith, and repeatedly heating said gas tube by moving a source of heat in thermal contact with said tube in the direction of said flowing gases, said heating being applied evenly over time around the periphery of said tube during said motion, whereby each said repeated heating results in the simultaneous formation of said soot and the deposition of a layer of said soot of a predetermined thickness on the inside surface of said tube, said repeated heating and deposition continuing to form a plurality of said layers, each said deposition occuring without the inclusion of impurities from outside said closed system, and a second step including a single heating step to fuse said plurality of layers into a layer of vitrified glass.
Claim 26
Independent Claim
185 words
A method for forming in a closed system a high quality preform rod having no voids, said method comprising: a first step that includes flowing at least three gases into a glass tube for transfer along the length of said tube, at least one of said gases being an inert gas which dissolves in the vitrified glass to be formed without reacting therewith, and repeatedly heating said gas tube by moving a source of heat in thermal contact with said tube in the direction of said flowing gases, said heating being applied evenly over time around the periphery of said tube during said motion, whereby each said repeated heating results in the simultaneous formation of said soot and the deposition of a layer of said soot of a predetermined thickness on the inside surface of said tube, said repeated heating and deposition continuing to form a plurality of said layers, each said deposition occuring without the inclusion of impurities from outside said closed system, and a second step including a single heating step to fuse said plurality of layers into a layer of vitrified glass.
Claim 27
Dependent Claim
28 words
The method of claim 22, said motion of said heat source being in the direction of flow of said flowing gases, and said heat source comprising a flame.
Claim 28
Dependent Claim
34 words
The method of claim 22, said inert gas comprising at least one gas chosen from the group consisting of argon and helium and said at least two other gases comprising oxygen and silicon tetrachloride.
Claim 29
Dependent Claim
36 words
The method of claim 22, each said repeated heating producing each of said deposited layers with a thickness of at least 20 microns, and said plurality of layers having a thickness of at least 0.75 millimeter.
Claim 30
Dependent Claim
23 words
The method of claim 22, wherein said single heating step of said tube comprises the same steps as each of said repeated heatings.
References Cited (Backward Citations)
US3933454A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-04-16 | 1982-10-16 | 1983-04-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-04-16 | 1986-10-16 | 1987-04-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-04-16 | 1990-10-16 | 1991-04-17 | $7700.00 | Window Closed / Lapsed |