Patent US2111748A successfully refreshed from Google Patents.
Patent US4148772A successfully refreshed from Google Patents.
US4148772A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Amine acid salt-containing polymers for cationic electrodeposition
Assignee: PPG Industries Inc
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Filing: 1977-12-08
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Granted: 1979-04-10
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Expires: 1997-12-08
Abstract
Abstract Novel, chain-extended adducts formed from reacting high molecular weight polyepoxides and polyester polyols containing at least two alcoholic, primary hydroxyls per molecule are disclosed. The chain-extended polyepoxides are adducted with a secondary amine and made dispersible in water with acid. The water-dispersed resins can be applied to a wide variety of substrates by cationic electrodeposition. When compared to resins which are not chain extended, the resins of the invention have higher rupture voltages, improved film-forming properties and deposit as films with improved flexibility.
Inventors
- 👤 Joseph R. Marchetti
- 👤 Robert R. Zwack
- 👤 Robert D. Jerabek
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 06:37
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/44; C09D5/4419; C09D5/443; C09D5/4434; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/0804; C08G18/0809; C08G18/0814; C08G18/28; C08G18/40; C08G18/64; C08G18/6415; C08G18/643; C08G18/70; C08G18/72; C08G18/80; C08G18/8061; C08G59/00; C08G59/18; C08G59/40; C08G59/50; C08G59/56; C08K; C08K5/00; C08K5/16; C08K5/17; C08L; C08L63/00; C08L71/00; C08L71/02
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
100 words
A cationic, water-dispersible resin, electrodepositable on the cathode, comprising the ungelled reaction product of: (A) a polyepoxide having a molecular weight of at least 350, (B) a secondary amine, (C) a polyester polyol containing two alcoholic primary hydroxyl groups, said polyester polyol being selected from the class consisting of polylactones and polyesters prepared by the polyesterification of organic polycarboxylic acids or functional derivatives thereof with organic polyols; the equivalent ratio of polyester polyol to polyepoxide being about 0.1 to about 0.8:1; said reaction product being dispersible in water with the aid of acid to provide cationic groups in the resin.
Claim 2
Dependent Claim
100 words
A cationic, water-dispersible resin, electrodepositable on the cathode, comprising the ungelled reaction product of: (A) a polyepoxide having a molecular weight of at least 350, (B) a secondary amine, (C) a polyester polyol containing two alcoholic primary hydroxyl groups, said polyester polyol being selected from the class consisting of polylactones and polyesters prepared by the polyesterification of organic polycarboxylic acids or functional derivatives thereof with organic polyols; the equivalent ratio of polyester polyol to polyepoxide being about 0.1 to about 0.8:1; said reaction product being dispersible in water with the aid of acid to provide cationic groups in the resin.
Claim 3
Dependent Claim
17 words
The cationic, water-dispersible resin of claim 1 prepared in the presence of an added tertiary amine catalyst.
Claim 4
Dependent Claim
47 words
The cationic, water-dispersible resin of claim 1 in which the polyepoxide is first reacted with a secondary amine in a stoichiometric deficiency so as to form a tertiary amine-containing, epoxy-containing adduct which is then further reacted with said polyester polyol to form a chain extended reaction product.
Claim 5
Dependent Claim
30 words
The cationic, water-dispersible resin of claim 1 in which the polyepoxide is a polyglycidyl ether of a polyphenol having a molecular weight within the range of about 350 to 2,000.
Claim 6
Dependent Claim
30 words
The cationic, water-dispersible resin of claim 4 in which the polyglycidyl ether of the polyphenol is a polyglycidyl ether of bisphenol having an epoxy equivalent of about 180 to 1000.
Claim 7
Dependent Claim
34 words
The cationic, water-dispersible resin of claim 1 in which the secondary amine is a dialkyl amine in which the alkyl groups are the same or different and contain from 1 to 4 carbon atoms.
Claim 8
Dependent Claim
14 words
The resin of claim 6 in which the dialkyl amine is a hydroxyalkyl-containing amine.
Claim 9
Dependent Claim
25 words
The resin of claim 1 in which the polyester polyol is a polycaprolactone polyol having a molecular weight within the range of 530 to 2000.
Claim 10
Dependent Claim
19 words
The resin of claim 8 in which the polycaprolactone polyol is formed from ring opening epsilon-caprolactone with ethylene glycol.
Claim 11
Dependent Claim
20 words
The resin of claim 1 in which the secondary amine contains a polyamine derivative having at least one ketimine group.
Claim 12
Dependent Claim
27 words
The resin of claim 8 in which the polyamine derivative is a ketimine derived from one mole of diethylene triamine and two moles of methyl isobutyl ketone.
Claim 13
Dependent Claim
33 words
The resin of claim 1 which contains in the resin molecule active hydrogens and blocked isocyanate groups which are stable at room temperature but are reactive with said active hydrogens at elevated temperature.
Claim 14
Dependent Claim
32 words
The resin of claim 12 wherein the isocyanate groups and the hydroxyl groups are present in an equivalent ratio of at least 0.1 to 1 blocked isocyanate group for each active hydrogen.
Claim 15
Dependent Claim
45 words
The resin of claim 1 which contains active hydrogens, said resin taken in further combination with a fully blocked polyisocyanate stable at ordinary room temperature in the presence of said active hydrogen-containing resin but reactive with the active hydrogens of said resin at elevated temperatures.
Claim 16
Dependent Claim
31 words
The resin of claim 14 wherein the isocyanate groups and the active hydrogens are present in an equivalent ratio of about 0.1 to 1 blocked isocyanate group for each active hydrogen.
Claim 17
Dependent Claim
29 words
An aqueous dispersion containing the cationic resin of claim 1 dispersed in water with the aid of acid, said dispersion containing from about 5 to 50 percent resin solids.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-04-09 | 1982-10-09 | 1983-04-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-04-09 | 1986-10-09 | 1987-04-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-04-09 | 1990-10-09 | 1991-04-10 | $7700.00 | Window Closed / Lapsed |