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US4148714A Expired / Lapsed US ⏱️ 0.0 years remaining

Metals passivation with catalyst fines

Assignee: Phillips Petroleum Co
•
Filing: 1978-06-30
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Granted: 1979-04-10
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Expires: 1998-06-30
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Abstract

Abstract Used cracking catalyst fines from a cracking process wherein antimony or a compound thereof is used as a metals passivation agent are used as an efficient passivation agent in a cracking process.

Inventors

  • 👤 Richard H. Nielsen
  • 👤 Dwight L. McKay
  • 👤 Glenn H. Dale

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 12:16
CPC Classifications
C; C10; C10G; C10G11/00; C10G11/02; C10G11/04

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 51 words
A process for passivating metals in a catalytic cracking process that is carried out essentially in the absence of added hydrogen by contacting a metals containing hydrocarbon feedstock under cracking conditions with a cracking catalyst in the presence of an added passivating agent consisting essentially of used antimony-containing cracking catalyst fines.
Claim 2
Dependent Claim 51 words
A process for passivating metals in a catalytic cracking process that is carried out essentially in the absence of added hydrogen by contacting a metals containing hydrocarbon feedstock under cracking conditions with a cracking catalyst in the presence of an added passivating agent consisting essentially of used antimony-containing cracking catalyst fines.
Claim 3
Dependent Claim 52 words
A process in accordance with claim 1 comprising contacting said hydrocarbon feedstock simultaneously with said cracking catalyst and with used antimony-containing cracking catalyst fines obtained and separated from a hydrocarbon catalytic cracking process in which antimony or antimony compounds are used to mitigate the detrimental effect of metals in this cracking process.
Claim 4
Dependent Claim 27 words
A process in accordance with claim 1 wherein said used catalyst fines are those that have been removed from said cracking process with the cracked hydrocarbon product.
Claim 5
Dependent Claim 22 words
A process in accordance with claim 1 wherein said catalyst fines have an antimony content of about 0.4 to 10 wt. %.
Claim 6
Dependent Claim 27 words
A process in accordance with claim 1 wherein said catalyst fines have a particle size to pass essentially completely through a sieve of 325 mesh (U.S. Sieve).
Claim 7
Dependent Claim 15 words
A process in accordance with claim 2 wherein said Sb compound is antimony tris(O,O-dihydrocarbyl dithiophosphate).
Claim 8
Dependent Claim 50 words
A process for passivating metals in a catalytic cracking process by contacting a metals-containing hydrocarbon feedstock under cracking conditions with a cracking catalyst in the presence of added passivating agent comprising Sb-containing used cracking catalyst fines from a cracking process wherein an organic Sb thiophosphate is employed as passivating agent.
Claim 9
Dependent Claim 50 words
A process for passivating metals in a catalytic cracking process by contacting a metals-containing hydrocarbon feedstock under cracking conditions with a cracking catalyst in the presence of added passivating agent comprising Sb-containing used cracking catalyst fines from a cracking process wherein an organic Sb thiophosphate is employed as passivating agent.
Claim 10
Dependent Claim 15 words
A process in accordance with claim 7 wherein the Sb compound is antimony tris(O,O-dihydrocarbyl dithiophosphate).
Claim 11
Dependent Claim 78 words
A process for passivating metals in a catalytic cracking process by contacting a metals-containing hydrocarbon feedstock under cracking conditions with a cracking catalyst in the presence of an added passivating agent consisting essentially of used antimony containing cracking catalyst fines wherein the used antimony containing cracking catalyst fines are obtained by withdrawing said fines from a hydrocarbon catalytic cracking process in which organic antimony compounds are used to mitigate the detrimental effect of metals in the cracking process.
Claim 12
Dependent Claim 78 words
A process for passivating metals in a catalytic cracking process by contacting a metals-containing hydrocarbon feedstock under cracking conditions with a cracking catalyst in the presence of an added passivating agent consisting essentially of used antimony containing cracking catalyst fines wherein the used antimony containing cracking catalyst fines are obtained by withdrawing said fines from a hydrocarbon catalytic cracking process in which organic antimony compounds are used to mitigate the detrimental effect of metals in the cracking process.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-04-09 1982-10-09 1983-04-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-04-09 1986-10-09 1987-04-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-04-09 1990-10-09 1991-04-10 $7700.00 Window Closed / Lapsed

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