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US4147678A Expired / Lapsed US ⏱️ 0.0 years remaining

Flame-retardant polyurethane compositions

Assignee: Uniroyal Chemical Co Inc
•
Filing: 1977-05-13
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Granted: 1979-04-03
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Expires: 1997-05-13
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Abstract

Abstract This inventon relates to flame-retarded cross-linked elastomer compositions obtained from an elastomeric polyurethane prepolymer; an organic fire-retardant additive containing chlorine and/or bromine; a compound of antimony; and a hexaalkoxymethyl melamine. These new compositions are self-extinguishing as well as non-dripping.

Inventors

  • 👤 Chung-Ling Mao
  • 👤 Walter Nudenberg

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:28
CPC Classifications
C; C08; C08L; C08L75/00; C08L75/04; C08K; C08K13/00; C08K13/02; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08K3/30; C08K5/00; C08K5/02; C08K5/04; C08K5/05; C08K5/06; C08K5/09; C08K5/10; C08K5/16; C08K5/20; C08K5/59; C08L61/00; C08L61/20; C08L61/26; C08L61/28; C08L91/00; C08L91/06; Y; Y10; Y10S; Y10S521/00; Y10S521/906

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 205 words
A flame-retarded composition comprising a chain extendable crosslinkable polyurethane prepolymer and (a) about 10 to about 50 parts by weight per 100 parts by weight of polyurethane of an organic additive selected from the group consisting of chlorine-substituted and bromine-substituted aliphatic, aromatic, alicyclic and mixed hydrocarbyl compounds having a halogen content in the range of about 35 to about 80 weight percent and optionally containing oxygen substituents in the form of hydroxyl, anhydride, ether, ester or amide groups and which are substantially non-volatile, stable and non-reactive toward said polyurethane and any auxiliary ingredients of said composition at the curing temperature of said polyurethane, and mixtures thereof; (b) about 1 to about 10 parts by weight per 100 parts by weight of polyurethane of a metallic compound selected from the group consisting of the antimony oxides, sulfides of antimony, antimony salts of the alkali metals of Group I of the Periodic Table, antimony salts of organic acids and their pentavalent derivatives, esters of antimonius acids and their pentavalent derivatives, cyclic antimonites, the oxides of arsenic and the oxides of bismuth; and (c) about 3 to about 40 parts by weight per 100 parts by weight of polyurethane to a C 1 to C 5 hexaalkoxymethyl melamine.
Claim 2
Dependent Claim 205 words
A flame-retarded composition comprising a chain extendable crosslinkable polyurethane prepolymer and (a) about 10 to about 50 parts by weight per 100 parts by weight of polyurethane of an organic additive selected from the group consisting of chlorine-substituted and bromine-substituted aliphatic, aromatic, alicyclic and mixed hydrocarbyl compounds having a halogen content in the range of about 35 to about 80 weight percent and optionally containing oxygen substituents in the form of hydroxyl, anhydride, ether, ester or amide groups and which are substantially non-volatile, stable and non-reactive toward said polyurethane and any auxiliary ingredients of said composition at the curing temperature of said polyurethane, and mixtures thereof; (b) about 1 to about 10 parts by weight per 100 parts by weight of polyurethane of a metallic compound selected from the group consisting of the antimony oxides, sulfides of antimony, antimony salts of the alkali metals of Group I of the Periodic Table, antimony salts of organic acids and their pentavalent derivatives, esters of antimonius acids and their pentavalent derivatives, cyclic antimonites, the oxides of arsenic and the oxides of bismuth; and (c) about 3 to about 40 parts by weight per 100 parts by weight of polyurethane to a C 1 to C 5 hexaalkoxymethyl melamine.
Claim 3
Dependent Claim 14 words
The composition of claim 1 in which said organic additive is a cycloaliphatic chloride.
Claim 4
Dependent Claim 14 words
The composition of claim 1 in which said organic additive is a chlorinated paraffin.
Claim 5
Dependent Claim 12 words
The composition of claim 1 in which said organic additive is 2,2',3,3',4,4',5,5',7,7,7',7'-dodecachloro-1,1',2,2',5,5',6,6'-octahydro-2,5,2',5'-dimethanobiphenyl.
Claim 6
Dependent Claim 12 words
The composition of claim 1 in which said organic additive is 6-(1',4',5',6',7',7'-hexachloronorborn-5'-en-2'yl)-1,2,3,4,10,10-hexachloro-1,4,4a,5,6,7,8,8a-octahydro-1,4:5,8-dimethanonaphthalene.
Claim 7
Dependent Claim 13 words
The composition of claim 1 in which said metallic compound is antimony trioxide.
Claim 8
Dependent Claim 11 words
The composition of claim 1 in which said melamine is hexamethoxymethylmelamine.
Claim 9
Dependent Claim 19 words
The composition of claim 1 which has been chain-extended and cross-linked by reacting the polyurethane prepolymer with a polyisocyanate.
Claim 10
Dependent Claim 11 words
The composition of claim 8 wherein the polyisocyanate is toluene diisocyanate
Claim 11
Dependent Claim 14 words
The composition of claim 8 in which said organic additive is a cycloaliphatic chloride.
Claim 12
Dependent Claim 14 words
The composition of claim 8 in which said organic additive is a chlorinated paraffin.
Claim 13
Dependent Claim 12 words
The composition of claim 8 in which said organic additive is 2,2',3,3',4,4',5,5',7,7,7',7'-dodecachloro-1,1',2,2',5,5',6,6'-octahydro-2,5,2',5'-dimethanobiphenyl.
Claim 14
Dependent Claim 12 words
The composition of claim 8 in which said organic additive is 6-(1',4',5',6',7',7'-hexachloronorborn-5'-en-2'yl)-1,2,3,4,10,10-hexachloro-1,4,4a,5,6,7,8,8a-octahydro-1,4:5,8-dimethanohaphthalene.
Claim 15
Dependent Claim 13 words
The composition of claim 8 in which said metallic compound is antimony trioxide.
Claim 16
Dependent Claim 11 words
The composition of claim 8 in which said melamine is hexamethoxymethylmelamine.

References Cited (Backward Citations)

US3211676A Cited
US3651003A Cited
US3897372A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-04-02 1982-10-02 1983-04-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-04-02 1986-10-02 1987-04-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-04-02 1990-10-02 1991-04-03 $7700.00 Window Closed / Lapsed

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