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US4147593A Expired / Lapsed US ⏱️ 0.0 years remaining

Flash pyrolysis of organic solid waste employing ash recycle

Assignee: Occidental Petroleum Corp
•
Filing: 1977-03-10
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Granted: 1979-04-03
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Expires: 1997-03-10
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Abstract

Abstract Essentially carbon free inorganic particles formed from the decarbonization of a carbon containing solid residue of pyrolysis of comminuted organic solid waste is employed as the prime heat source for the pyrolysis of the comminuted organic solid waste.

Inventors

  • 👤 Robert W. Frischmuth
  • 👤 Allan Sass

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 20:35
CPC Classifications
C; C10; C10B; C10B53/00; C10B49/00; C10B49/16; C10B49/20; Y; Y02; Y02E; Y02E50/00; Y02E50/10; Y02P; Y02P20/00; Y02P20/10; Y02P20/129

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 287 words
In a process for the treatment of solid waste in which a waste solid is separated into an organic fraction and solid organic solid waste fraction containing entrained particulate inorganic constituents and in which after comminution and drying the organic solid is pyrolyzed to form a carbon containing solid residue of pyrolysis, a condensable pyrolytic oil and gas, the improvement which comprises: (a) combining and transporting the dried comminuted organic solid waste fraction, including the particulate inorganics, which fraction is of a particle size in which the largest particle dimension is less than one inch, a carrier gas which is nondeleteriously reactive with the pyrolysis products, and a hot particulate inorganic solid heat source formed from decarbonization of the carbon containing solid residue of pyrolysis and having a bulk density from about 35 to about 70 lbs./cu. ft. as the prime source of heat for pyrolysis under transport turbulent flow conditions through a pyrolysis zone maintained at a temperature from about 600° F. to less than the sintering temperature of the inorganic solid heat source for a time sufficient to form from the organic solid waste the carbon containing solid residue and condensable pyrolytic oils and gases; (b) separating the carbon containing solid residue of pyrolysis in admixture with the inorganic solid heat source from the condensable pyrolytic oils and gases; (c) decarbonizing at least a portion of the carbon containing solid residue of pyrolysis to form additional hot inorganic solid heat source, the decarbonization of the carbon containing solid residue of pyrolysis occurring at a temperature below the fusion temperature of the resultant inorganic solid heat source; (d) recycling at least a portion of the formed hot inorganic solid source of heat to the pyrolysis zone.
Claim 2
Dependent Claim 287 words
In a process for the treatment of solid waste in which a waste solid is separated into an organic fraction and solid organic solid waste fraction containing entrained particulate inorganic constituents and in which after comminution and drying the organic solid is pyrolyzed to form a carbon containing solid residue of pyrolysis, a condensable pyrolytic oil and gas, the improvement which comprises: (a) combining and transporting the dried comminuted organic solid waste fraction, including the particulate inorganics, which fraction is of a particle size in which the largest particle dimension is less than one inch, a carrier gas which is nondeleteriously reactive with the pyrolysis products, and a hot particulate inorganic solid heat source formed from decarbonization of the carbon containing solid residue of pyrolysis and having a bulk density from about 35 to about 70 lbs./cu. ft. as the prime source of heat for pyrolysis under transport turbulent flow conditions through a pyrolysis zone maintained at a temperature from about 600° F. to less than the sintering temperature of the inorganic solid heat source for a time sufficient to form from the organic solid waste the carbon containing solid residue and condensable pyrolytic oils and gases; (b) separating the carbon containing solid residue of pyrolysis in admixture with the inorganic solid heat source from the condensable pyrolytic oils and gases; (c) decarbonizing at least a portion of the carbon containing solid residue of pyrolysis to form additional hot inorganic solid heat source, the decarbonization of the carbon containing solid residue of pyrolysis occurring at a temperature below the fusion temperature of the resultant inorganic solid heat source; (d) recycling at least a portion of the formed hot inorganic solid source of heat to the pyrolysis zone.
Claim 3
Dependent Claim 20 words
The process of claim 1 in which pyrolysis is conducted at a temperature from about 600° to about 1700° F.
Claim 4
Dependent Claim 20 words
The process of claim 1 in which pyrolysis is conducted at a temperature from about 800° to about 1400° F.
Claim 5
Dependent Claim 24 words
The process of claim 1 in which the particle size of the inorganic solid heat source is from about 10 to about 2000 microns.
Claim 6
Dependent Claim 24 words
The process of claim 1 in which the particle size of the inorganic solid heat source is from about 20 to about 1000 microns.
Claim 7
Dependent Claim 24 words
The process of claim 3 in which the particle size of the inorganic solid heat source is from about 20 to about 2000 microns.
Claim 8
Dependent Claim 24 words
The process of claim 3 in which the particle size of the inorganic solid heat source is from about 20 to about 1000 microns.
Claim 9
Dependent Claim 50 words
The process of claim 1 in which the carbon containing solid residue of pyrolysis is decarbonized by high temperature oxidation in the presence of a source of oxygen at a temperature below the fusion temperature of the inorganic solid heat source, the temperature being controlled by the introduction of water.
Claim 10
Dependent Claim 12 words
The process of claim 8 in the source of oxygen is air.
Claim 11
Dependent Claim 31 words
The process of claim 8 in which oxygen is present in an amount sufficient to oxidize at least 80% of the carbon contained in the carbon containing solid residue of pyrolysis.
Claim 12
Dependent Claim 49 words
The process of claim 3 in which the carbon containing solid residue of pyrolysis is decarbonized by high temperature oxidation in the presence of a source of oxygen at a temperature below the fusion temperature of the inorganic solid source, the temperature being controlled by the introduction of water.
Claim 13
Dependent Claim 13 words
The process of claim 11 in which the source of oxygen is air.
Claim 14
Dependent Claim 31 words
The process of claim 11 in which oxygen is present in an amount sufficient to oxidize at least 80% of the carbon contained in the carbon containing solid residue of pyrolysis.
Claim 15
Dependent Claim 30 words
The process of claim 1 in which the weight ratio of inorganic solid heat source to organic solid waste is from about 2 to 1 to about 20 to 1.
Claim 16
Dependent Claim 30 words
The process of claim 3 in which the weight ratio of inorganic solid heat source to organic solid waste is from about 2 to 1 to about 20 to 1.
Claim 17
Dependent Claim 30 words
The process of claim 1 in which the weight ratio of inorganic solid heat source to organic solid waste is from about 4 to 1 to about 6 to 1.
Claim 18
Dependent Claim 30 words
The process of claim 3 in which the weight ratio of inorganic solid heat source to organic solid waste is from about 4 to 1 to about 6 to 1.
Claim 19
Dependent Claim 21 words
The process of claim 1 in which solids residence time in the pyrolysis zone is from 0.1 to about 2 seconds.
Claim 20
Dependent Claim 22 words
The process of claim 1 in which solids residence time in the pyrolysis zone is from about 0.2 to about 0.5 seconds.
Claim 21
Dependent Claim 21 words
The process of claim 3 in which solids residence time in the pyrolysis zone is from 0.1 to about 2 seconds.
Claim 22
Dependent Claim 22 words
The process of claim 3 in which solids residence time in the pyrolysis zone is from about 0.2 to about 0.5 seconds.
Claim 23
Dependent Claim 20 words
The process of claim 1 in which the organic solid waste is of a particle size less than 8 mesh.
Claim 24
Dependent Claim 20 words
The process of claim 1 in which the organic solid waste is of a particle size less than 5 mesh.

References Cited (Backward Citations)

US3251751A Cited
US3444048A Cited
US3655518A Cited
US3574065A Cited
US3698882A Cited
US3736111A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-04-02 1982-10-02 1983-04-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-04-02 1986-10-02 1987-04-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-04-02 1990-10-02 1991-04-03 $7700.00 Window Closed / Lapsed

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