Patent US4145372A successfully refreshed from Google Patents.
US4145372A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for preparing moldable polyamide polyester compositions
Assignee: British Industrial Plastics Ltd
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Filing: 1977-06-20
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Granted: 1979-03-20
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Expires: 1997-06-20
Abstract
Abstract A polyester/nylon co-condensate which may be made from the two polymers in an extruder. The co-condensate comprises from 50 to 99% by weight of polyamide having a softening point of from 210° C. to 270° C. and a number average molecular weight in the range 10,000 to 30,000 and from 50% to 1% by weight of a polyester which is selected from saturated and unsaturated polyesters and which has an acid value of from 30 to 90 and a number average molecular weight less than 10,000. The co-condensate can also contain an acrylic homo- or co-polymer as a third component.
Inventors
- 👤 Christopher L. Murray
- 👤 Corwyn P. Vale
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 21:39
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/44; C08G81/00
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
209 words
A process for the production of a moldable thermoplastic composition from a polyamide which contains free amine groups and is of softening point in the range 210° to 270° C. and of number average molecular weight in the range 10,000 to 30,000, comprising heating a mixture comprising from 50 to 99% by weight of said polyamide and from 50 to 1% by weight of a polyester which is of number average molecular weight less than 10,000 and of acid value in the range 30 to 90, said polyester being one produced by (a) condensing an aromatic or aliphatic dibasic acid or anhydride with a carboxylic aliphatic di- or poly-hydroxy compound, to produce a hydroxy-terminated polyester intermediate, and (b) reacting said hydroxy-terminated polyester intermediate with an acid which contains at least 3 carboxylic acid groups, or with an anhydride thereof, which is employed in a quantity such as to provide the polyester with an acid value in the range 30 to 90 and with a softening point of at least 100° C., heating of said mixture comprising polyamide and polyester being carried out at a temperature of at least 170° C. whereby water is produced by reaction between the polyamide and polyester and is allowed to escape from said mixture.
Claim 2
Dependent Claim
209 words
A process for the production of a moldable thermoplastic composition from a polyamide which contains free amine groups and is of softening point in the range 210° to 270° C. and of number average molecular weight in the range 10,000 to 30,000, comprising heating a mixture comprising from 50 to 99% by weight of said polyamide and from 50 to 1% by weight of a polyester which is of number average molecular weight less than 10,000 and of acid value in the range 30 to 90, said polyester being one produced by (a) condensing an aromatic or aliphatic dibasic acid or anhydride with a carboxylic aliphatic di- or poly-hydroxy compound, to produce a hydroxy-terminated polyester intermediate, and (b) reacting said hydroxy-terminated polyester intermediate with an acid which contains at least 3 carboxylic acid groups, or with an anhydride thereof, which is employed in a quantity such as to provide the polyester with an acid value in the range 30 to 90 and with a softening point of at least 100° C., heating of said mixture comprising polyamide and polyester being carried out at a temperature of at least 170° C. whereby water is produced by reaction between the polyamide and polyester and is allowed to escape from said mixture.
Claim 3
Dependent Claim
24 words
A process according to claim 1, wherein said anhydride of a carboxylic acid which contains at least 3 carboxylic acid groups is trimellitic anhydride.
Claim 4
Dependent Claim
31 words
A process according to claim 2, wherein said polyester is one produced from (i) a hydroxy-terminated polyester intermediate derived from ethylene or propylene glycol and isophthalic acid, and (ii) trimellitic anhydride.
Claim 5
Dependent Claim
27 words
A process according to claim 1, wherein said polyester of acid value in the range 30 to 90 has a number average molecular weight less than 5,000.
Claim 6
Dependent Claim
26 words
A process according to claim 4, wherein said polyester has an acid value in the range 50-75 and a softening point in the range 100°-120° C.
Claim 7
Dependent Claim
12 words
A process according to claim 1, wherein the polyamide is polyhexamethylene adipamide.
Claim 8
Dependent Claim
11 words
A process according to claim 1, wherein the polyamide is polycaprolactum.
Claim 9
Dependent Claim
46 words
A process according to claim 1, wherein the mixture which is heated at a temperature of at least 170° C. contains, in addition to polyamide and polyester, an acrylic homo- or copolymer in an amount in the range 1-10% by weight of the total polymeric material.
Claim 10
Dependent Claim
36 words
A process according to claim 8, in which the acrylic polymer is a multi-phase acrylic polymer consisting of an elastomeric core with a glass-transition temperature Tg greater than 50° C. and containing amine-reactive carboxylic acid groups.
Claim 11
Dependent Claim
34 words
A process according to claim 8 in which the acrylic polymer is a single phase rigid thermoplastic polymer having a glass transition temperature Tg greater than 50° C. and containing a polymerizable carboxylic acid.
Claim 12
Dependent Claim
24 words
A process according to claim 1, wherein the amount of polyester present in said mixture with polyamide is in the range 1-25% by weight.
Claim 13
Dependent Claim
24 words
A process according to claim 1, wherein the amount of polyester present in said mixture with polyamide is in the range 5-20% by weight.
Claim 14
Dependent Claim
33 words
A process according to claim 1, wherein the mixture comprising said polyamide and polyester is fed in particulate form to an extruder and heated therein at a temperature of at least 170° C.
References Cited (Backward Citations)
US3274289A
Cited
US3288759A
Cited
US3468975A
Cited
US3484339A
Cited
US3810876A
Cited
US4014829A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-03-19 | 1982-09-18 | 1983-03-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-03-19 | 1986-09-18 | 1987-03-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-03-19 | 1990-09-18 | 1991-03-20 | $7700.00 | Window Closed / Lapsed |