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US4144102A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of low expansion superalloy products

Assignee: Huntington Alloys Corp
•
Filing: 1977-08-15
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Granted: 1979-03-13
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Expires: 1997-08-15
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Abstract

Abstract Nickel-iron and nickel-iron-cobalt alloys contain chromium and gamma-prime hardening elements in proportions balanced according to special compositional relationships providing desired thermal expansion, inflection temperature, strength and ductility characteristics, particularly including notch strength needed in machinery and structures subjected in use to varying temperatures and thermal gradients where operating temperatures become elevated above 500° F.

Inventors

  • 👤 Darrell F. Smith, Jr.
  • 👤 Edward F. Clatworthy
  • 👤 Donald E. Wenschhof, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 08:09
CPC Classifications
C; C22; C22C; C22C19/00; C22C19/03; C22C19/05; C22C19/058; C22C38/00; C22C38/18; C22C38/40; C22C38/52

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 188 words
A process for preparing a precipitation-hardened wrought product comprising establishing a melt of an alloy consisting essentially of 30% to 57% nickel, 1.7% to 8.3% chromium, 1% to 2% titanium, metal from the group columbium, tantalum and mixtures thereof in proportions providing the total percentage of columbium plus one-half the percentage of tantalum is 1.5% to 5%, up to 31% cobalt, up to 1.5% aluminum, up to 0.2% carbon, up to about 2% manganese, up to about 1% silicon, up to 0.03% boron and balance essentially iron in an amount of at least 34% of the alloy and having the composition proportioned in accordance with the following four relationships A, B, C' and D' whereby: (A) %Ni+0.88(%Co)-1.70(%Al)-2.01(%Ti)+0.26(%Mn+Cr) equal up to 51.8 (B) %Ni+1.13(%Co)-2.69(%Al)-1.47(%Ti)-1.93(%Mn)-2.51(%Cr)+1.87(%Cr) at least 40.8 (C') %Al+1.3(%Ti)+1.44(%Cb+1/2Ta)-0.12(%Cb+1/2Ta) 2 -0.37(%Cr)+0.03(%Cr) 2 at least 3.81 (D') %Al+1.3(%Ti)+0.25(%Cb+1/2Ta)-0)125(%Cr) up to 3.18 solidifying the alloy in a mold, separating the alloy and the mold, hot working the solidified alloy at temperature of about 2100° F. and below, and thereafter age-hardening the alloy with a heat treatment of at least 8 hours in the temperature range of 1350° F. to 1150° F.
Claim 2
Dependent Claim 188 words
A process for preparing a precipitation-hardened wrought product comprising establishing a melt of an alloy consisting essentially of 30% to 57% nickel, 1.7% to 8.3% chromium, 1% to 2% titanium, metal from the group columbium, tantalum and mixtures thereof in proportions providing the total percentage of columbium plus one-half the percentage of tantalum is 1.5% to 5%, up to 31% cobalt, up to 1.5% aluminum, up to 0.2% carbon, up to about 2% manganese, up to about 1% silicon, up to 0.03% boron and balance essentially iron in an amount of at least 34% of the alloy and having the composition proportioned in accordance with the following four relationships A, B, C' and D' whereby: (A) %Ni+0.88(%Co)-1.70(%Al)-2.01(%Ti)+0.26(%Mn+Cr) equal up to 51.8 (B) %Ni+1.13(%Co)-2.69(%Al)-1.47(%Ti)-1.93(%Mn)-2.51(%Cr)+1.87(%Cr) at least 40.8 (C') %Al+1.3(%Ti)+1.44(%Cb+1/2Ta)-0.12(%Cb+1/2Ta) 2 -0.37(%Cr)+0.03(%Cr) 2 at least 3.81 (D') %Al+1.3(%Ti)+0.25(%Cb+1/2Ta)-0)125(%Cr) up to 3.18 solidifying the alloy in a mold, separating the alloy and the mold, hot working the solidified alloy at temperature of about 2100° F. and below, and thereafter age-hardening the alloy with a heat treatment of at least 8 hours in the temperature range of 1350° F. to 1150° F.
Claim 3
Dependent Claim 49 words
A process as set forth in claim 1 comprising, following said hot-working and preceding said age-hardening, warm working the alloy at a temperature about 30° F. to about 300° F. below the recrystallization temperature and then reheating the alloy sufficiently above the recrystallization temperature of recrystallize the warm-worked alloy.
Claim 4
Dependent Claim 22 words
A product of the process as set forth in claim 1 wherein the amount of chromium is about 2% to about 5%.
Claim 5
Dependent Claim 23 words
A product of the process as set forth in claim 1 characterized by an average grain size of ASTM No. 4.5 or coarser.
Claim 6
Dependent Claim 23 words
A product of the process as set forth in claim 1 characterized by an average grain size of ASTM No. 5 or finer.

References Cited (Backward Citations)

US3157495A Cited
US3514284A Cited
US3705827A Cited
US3940295A Cited
US3930904A Cited
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US4006012A Cited
US3971677A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-03-12 1982-09-11 1983-03-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-03-12 1986-09-11 1987-03-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-03-12 1990-09-11 1991-03-13 $7700.00 Window Closed / Lapsed

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