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Pigments which are stable in nitrocellulose

Assignee: BASF SE
•
Filing: 1978-02-17
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Granted: 1979-03-06
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Expires: 1998-02-17
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Abstract

Abstract A pigment which is stable in nitrocellulose and comprises at least one trisaminotriarylmethane dye and heteropolyacids based on phosphoric acid, molybdic acid or tungstic acid, the pigment containing from 0.1 to 10% by weight (based on the pigment formulation) of a compound which possesses at least one --N(CH 2 --COOH) 2 group. The pigment may be used for the stable coloration of nitrocellulose-containing printing inks and finishes or of nitrocellulose chips.

Inventors

  • 👤 Klaus Bast
  • 👤 Erwin Plankenhorn

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 16:34
CPC Classifications
C; C09; C09D; C09D101/00; C09D101/08; C09D101/16; C09D101/18; C09B; C09B11/00; C09B11/04; C09B11/10; C09B11/12; C09B67/00; C09B67/0001; C09B67/0017; C09B69/00; C09B69/02; C09B69/06; C09D11/00; C09D11/02; C09D11/03

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 83 words
A pigment which is stable in nitrocellulose and comprises at least one trisamino-triarylmethane dye and molybdo-phosphoric acid or molybdo-tungsto-phosphoric acid (which heteropolyacids may in addition contain silicic acid), and which in addition contains from 0.1 to 10% by weight, based on the pigment formulation, of a compound which possesses at least one --N(CH 2 --COOH) 2 group, said compound being selected from the group consisting of nitrilotriacetic acid, ethylene diaminetetraacetic acid, diethylenetriaminepentaacetic acid, alkali metal salts or ammonium salts thereof, and mixtures thereof.
Claim 2
Dependent Claim 83 words
A pigment which is stable in nitrocellulose and comprises at least one trisamino-triarylmethane dye and molybdo-phosphoric acid or molybdo-tungsto-phosphoric acid (which heteropolyacids may in addition contain silicic acid), and which in addition contains from 0.1 to 10% by weight, based on the pigment formulation, of a compound which possesses at least one --N(CH 2 --COOH) 2 group, said compound being selected from the group consisting of nitrilotriacetic acid, ethylene diaminetetraacetic acid, diethylenetriaminepentaacetic acid, alkali metal salts or ammonium salts thereof, and mixtures thereof.
Claim 3
Dependent Claim 27 words
A pigment as claimed in claim 1, which contains from 1 to 5% by weight of compounds which possess at least one --N(CH 2 --COOH) 2 group.
Claim 4
Dependent Claim 23 words
A pigment as claimed in claim 1, wherein the carboxyl groups are in the form of the alkali metal salts or ammonium salts.
Claim 5
Dependent Claim 160 words
A pigment which is stable in nitrocellulose and comprises at least one trisamino-triarylmethane dye of the formula: ##STR3## where A.sup.θ is one equivalent of an anion and R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are hydrogen, methyl or ethyl and the substituents may be identical or different, and R 1 may may also be phenyl or alkylphenyl (where alkyl is of 1 to 4 carbon atoms), and a heteropolyacid selected from molybdic acid/phosphoric acid or molybdic acid/tungstic acid/phosphoric acid (which heteropolyacids may in addition contain silicic acid), and which in addition contains from 0.1 to 10% by weight, based on pigment, of a compound which possesses at least one --N(CH 2 COOH) 2 group, selected from the group consisting of nitrilotriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, and mixtures thereof, wherein the carboxyl groups are in the free form or in the form of the alkali metal salts or ammonium salts.
Claim 6
Dependent Claim 160 words
A pigment which is stable in nitrocellulose and comprises at least one trisamino-triarylmethane dye of the formula: ##STR3## where A.sup.θ is one equivalent of an anion and R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are hydrogen, methyl or ethyl and the substituents may be identical or different, and R 1 may may also be phenyl or alkylphenyl (where alkyl is of 1 to 4 carbon atoms), and a heteropolyacid selected from molybdic acid/phosphoric acid or molybdic acid/tungstic acid/phosphoric acid (which heteropolyacids may in addition contain silicic acid), and which in addition contains from 0.1 to 10% by weight, based on pigment, of a compound which possesses at least one --N(CH 2 COOH) 2 group, selected from the group consisting of nitrilotriacetic acid, ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, and mixtures thereof, wherein the carboxyl groups are in the free form or in the form of the alkali metal salts or ammonium salts.

References Cited (Backward Citations)

US2635967A Cited
US3336147A Cited
US3387983A Cited
DE2049379A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-03-05 1982-09-04 1983-03-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-03-05 1986-09-04 1987-03-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-03-05 1990-09-04 1991-03-06 $7700.00 Window Closed / Lapsed

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