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US4142899A Expired / Lapsed US ⏱️ 0.0 years remaining

Color diffusion transfer photographic unit

Assignee: Konica Minolta Inc
•
Filing: 1977-06-22
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Granted: 1979-03-06
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Expires: 1997-06-22
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Abstract

Abstract The present invention relates to a color diffusion transfer photographic unit containing a silver halide photosensitive element, and an image receiving element wherein said unit contains a copolymer containing two monomers. The first monomer is noted for having quaternary nitrogen while the second monomer is required to have at least one fluorine atom.

Inventors

  • 👤 Yuzuru Sato
  • 👤 Masao Asano
  • 👤 Masao Ishihara
  • 👤 Sadatugu Terada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 21:59
CPC Classifications
G; G03; G03C; G03C8/00; G03C8/42; G03C8/52; G03C8/56; Y; Y10; Y10S; Y10S430/00; Y10S430/142

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 391 words
A color diffusion transfer photographic unit comprising a silver halide photosensitive element having a light-sensitive silver halide emulsion layer, an image-receiving element having a dye-image receiving layer, and a support, said unit comprising a copolymer containing as comonomers a first monomer having quaternary nitrogen and represented by the following formula ##STR11## wherein R 1 represents hydrogen or an atomic group necessary to form an N-alkylenemaleimide ring together with A, R 2 represents hydrogen or lower alkyl, A represents alkylene, allylene, aralkylene, or a member selected from the group --COOR 6 --, --CONHR 6 --, --OCOR 6 -- and --CONR 6 -- wherein R 6 represents alkylene; R 3 , r 4 and R 5 represent respectively, alkyl, allyl, or aryl, or R 4 and R 5 are an atomic group necessary to form a heterocyclic ring or to form a heterocyclic ring together with A, and X represents an anion, and a second monomer having at least one fluorine atom and represented by the following formula ##STR12## wherein R 7 , R 8 , R 9 and R 10 respectively represent hydrogen, fluorine, lower alkyl, or a member selected from the group consisting of --(CF 2 ) n F (n=1 to 8), --O(CF 2 ) n F (n=2 to 8), --O(CF 2 ) n H (n=2 to 8), --O(CF 2 ) n OC 6 F 5 (n=2 to 3), --C--CH 2 (CF 2 ) n H(n=2 to 8), --OCH 2 (CF 2 ) n F (n=2 to 8) --COOCH 2 (CF 2 ) n H (n=2 to 8), --COO(CH 2 ) m NR 11 SO 2 (CF 2 ) n F (m=2 to 3, n =1 to 8; R 11 represents a C 1-14 alkyl group), --COO(CH 2 ) m NR 12 CO(CF 2 ) n F (m=2 to 3, n=1 to 8; R 12 represents a C 1-4 alkyl), --COO(CH 2 ) m NR 13 CO(CF 2 ) n H (m=2 to 3, n =1 to 8; R 13 represents a C 1-4 alkyl group), --OCO(CF 2 ) n H (n=1 to 8), --OCO(CF 2 ) n F (n=1 to 8), ##STR13## and R 7 , R 8 , R 9 and R 10 may be the same or different with the proviso that at least one of R 7 - R 10 must contain at least one fluorine atom.
Claim 2
Dependent Claim 391 words
A color diffusion transfer photographic unit comprising a silver halide photosensitive element having a light-sensitive silver halide emulsion layer, an image-receiving element having a dye-image receiving layer, and a support, said unit comprising a copolymer containing as comonomers a first monomer having quaternary nitrogen and represented by the following formula ##STR11## wherein R 1 represents hydrogen or an atomic group necessary to form an N-alkylenemaleimide ring together with A, R 2 represents hydrogen or lower alkyl, A represents alkylene, allylene, aralkylene, or a member selected from the group --COOR 6 --, --CONHR 6 --, --OCOR 6 -- and --CONR 6 -- wherein R 6 represents alkylene; R 3 , r 4 and R 5 represent respectively, alkyl, allyl, or aryl, or R 4 and R 5 are an atomic group necessary to form a heterocyclic ring or to form a heterocyclic ring together with A, and X represents an anion, and a second monomer having at least one fluorine atom and represented by the following formula ##STR12## wherein R 7 , R 8 , R 9 and R 10 respectively represent hydrogen, fluorine, lower alkyl, or a member selected from the group consisting of --(CF 2 ) n F (n=1 to 8), --O(CF 2 ) n F (n=2 to 8), --O(CF 2 ) n H (n=2 to 8), --O(CF 2 ) n OC 6 F 5 (n=2 to 3), --C--CH 2 (CF 2 ) n H(n=2 to 8), --OCH 2 (CF 2 ) n F (n=2 to 8) --COOCH 2 (CF 2 ) n H (n=2 to 8), --COO(CH 2 ) m NR 11 SO 2 (CF 2 ) n F (m=2 to 3, n =1 to 8; R 11 represents a C 1-14 alkyl group), --COO(CH 2 ) m NR 12 CO(CF 2 ) n F (m=2 to 3, n=1 to 8; R 12 represents a C 1-4 alkyl), --COO(CH 2 ) m NR 13 CO(CF 2 ) n H (m=2 to 3, n =1 to 8; R 13 represents a C 1-4 alkyl group), --OCO(CF 2 ) n H (n=1 to 8), --OCO(CF 2 ) n F (n=1 to 8), ##STR13## and R 7 , R 8 , R 9 and R 10 may be the same or different with the proviso that at least one of R 7 - R 10 must contain at least one fluorine atom.
Claim 3
Dependent Claim 27 words
A color diffusion transfer photographic unit according to claim 1 wherein a combined amount of the monomers in the copolymer is not less than 50 mole %.
Claim 4
Dependent Claim 19 words
A color diffusion transfer photographic unit according to claim 2 wherein said copolymer is present in said image-receiving element.
Claim 5
Dependent Claim 21 words
The color diffusion transfer photographic unit according to claim 1 wherein said image-receiving element comprises an image-receiving layer containing said copolymer.
Claim 6
Dependent Claim 20 words
The color diffusion transfer photographic unit according to claim 4 wherein the image-receiving layer has a dry thickness of 3-10μ.
Claim 7
Dependent Claim 24 words
The color diffusion transfer photographic unit according to claim 5 wherein the amount of the copolymer in the image-receiving layer is 10-100% by weight.
Claim 8
Dependent Claim 29 words
The color diffusion transfer photographic unit according to claim 4 wherein the unit further comprises a processing sheet having thereupon a photosensitive element having thereon the image receiving element.
Claim 9
Dependent Claim 32 words
The color diffusion transfer photographic unit according to claim 1 wherein the unit further comprises a processing sheet containing said copolymer having thereupon the photosensitive element having thereon the image receiving element.
Claim 10
Dependent Claim 21 words
The color diffusion transfer photographic unit according to claim 8 wherein the processing sheet comprises a scavenger layer containing the copolymer.
Claim 11
Dependent Claim 38 words
The color diffusion transfer photographic unit according to claim 1 wherein an amount of the first monomer is 40-90 mole % of the copolymer while an amount of the second monomer is 10-60 mole % of the copolymer.

References Cited (Backward Citations)

US3709690A Cited
US3944424A Cited
US3930864A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-03-05 1982-09-04 1983-03-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-03-05 1986-09-04 1987-03-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-03-05 1990-09-04 1991-03-06 $7700.00 Window Closed / Lapsed

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