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US4142400A
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Nitrogen dioxide sensing element and method of sensing the presence of nitrogen dioxide
Assignee: Johnson Service Co
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Filing: 1977-03-07
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Granted: 1979-03-06
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Expires: 1997-03-07
Abstract
Abstract An element for sensing the presence of nitrogen dioxide gas in the environment. The element comprises a film of a pyrolyzed polyaromatic polymer having semi-conductive properties which is mounted on an electrically non-conductive base. Electrical leads are attached at spaced locations to the film and are connected in an electrical circuit with a signalling or control mechanism. The presence of nitrogen dioxide gas will cause a change in the electrical characteristics of the film to thereby activate the mechanism. A heating element can be associated with the base to insure constant temperature and humidity conditions.
Inventors
- 👤 Jeannine O. Colla
- 👤 Paul E. Thoma
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 08:19
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/02; G01N27/04; G01N27/12; H; H01; H01C; H01C17/00; H01C17/06; H01C17/20
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
49 words
An element capable of sensing the presence of nitrogen dioxide in the environment, comprising a film of a pyrolyzed polyaromatic polymer, and electrical leads connected to said film at spaced locations, the presence of nitrogen dioxide in the environment causing a change in the electrical characteristics of the film.
Claim 2
Dependent Claim
49 words
An element capable of sensing the presence of nitrogen dioxide in the environment, comprising a film of a pyrolyzed polyaromatic polymer, and electrical leads connected to said film at spaced locations, the presence of nitrogen dioxide in the environment causing a change in the electrical characteristics of the film.
Claim 3
Dependent Claim
20 words
The element of claim 1, wherein said polymer is selected from the group consisting of polyamides, polyamideimides, polyimides and polybenzimidazoles.
Claim 4
Dependent Claim
15 words
The element of claim 1, and including an electrically non-conductive base to support the film.
Claim 5
Dependent Claim
19 words
The element of claim 3, wherein said film has a thickness in the range of 0.3 to 5 mils.
Claim 6
Dependent Claim
35 words
The element of claim 3, and including heating means connected to said base for maintaining the base at a temperature substantially above ambient temperature to thereby minimize the effect of ambient temperature and humidity variations.
Claim 7
Dependent Claim
27 words
The element of claim 1, and including non-corroding metal layers disposed on a surface of said film at spaced locations, said leads being connected to said layers.
Claim 8
Dependent Claim
72 words
An element capable of sensing the presence of nitrogen dioxide in the environment, comprising a film of pyrolyzed polyaromatic polymer having nitrogen as a part of the ring structure and being electrically responsive to nitrogen dioxide, an electrically non-conductive base to support the film, and electrical leads connected to said film at spaced locations, the presence of nitrogen dioxide in the environment causing a change in the electrical characteristics of the film.
Claim 9
Dependent Claim
72 words
An element capable of sensing the presence of nitrogen dioxide in the environment, comprising a film of pyrolyzed polyaromatic polymer having nitrogen as a part of the ring structure and being electrically responsive to nitrogen dioxide, an electrically non-conductive base to support the film, and electrical leads connected to said film at spaced locations, the presence of nitrogen dioxide in the environment causing a change in the electrical characteristics of the film.
Claim 10
Dependent Claim
84 words
An element capable of sensing the presence of nitrogen dioxide gas in the environment, comprising an electrically non-conductive base, a film of pyrolyzed polyaromatic polymer secured to a surface of said base and having semi-conductor characteristics, electrical leads connected to the film at spaced locations thereon, the presence of nitrogen dioxide gas causing a change in the electrical characteristics of said film, and heating means connected to the opposite surface of the base for heating the base to a temperature substantially above ambient temperature.
Claim 11
Dependent Claim
84 words
An element capable of sensing the presence of nitrogen dioxide gas in the environment, comprising an electrically non-conductive base, a film of pyrolyzed polyaromatic polymer secured to a surface of said base and having semi-conductor characteristics, electrical leads connected to the film at spaced locations thereon, the presence of nitrogen dioxide gas causing a change in the electrical characteristics of said film, and heating means connected to the opposite surface of the base for heating the base to a temperature substantially above ambient temperature.
Claim 12
Independent Claim
101 words
A system for sensing the presence of nitrogen dioxide gas in the environment, comprising a sensing element including an electrically non-conductive base, and a film of a pyrolyzed polyaromatic polymer secured to a surface of said base, said element also including a pair of electrical terminals connected to the film at spaced locations thereon, a source of electrical power, signalling means, and an electrical circuit connecting said terminals, said source of power and said signaling means, the presence of nitrogen dioxide gas in the atmosphere causing a change in the electrical characteristics of said film to thereby actuate said signaling means.
Claim 13
Independent Claim
101 words
A system for sensing the presence of nitrogen dioxide gas in the environment, comprising a sensing element including an electrically non-conductive base, and a film of a pyrolyzed polyaromatic polymer secured to a surface of said base, said element also including a pair of electrical terminals connected to the film at spaced locations thereon, a source of electrical power, signalling means, and an electrical circuit connecting said terminals, said source of power and said signaling means, the presence of nitrogen dioxide gas in the atmosphere causing a change in the electrical characteristics of said film to thereby actuate said signaling means.
Claim 14
Dependent Claim
20 words
The system of claim 9, wherein said polymer is selected from the group consisting of polyamides, polyamideimides, polyimides and polybenzimidazoles.
Claim 15
Dependent Claim
24 words
The system of claim 9, and including heating means connected to the base for heating the base to a temperature substantially above ambient temperature.
Claim 16
Independent Claim
53 words
A method of sensing the presence of nitrogen dioxide in the environment, comprising the steps of exposing a film composed of a pyrolyzed polyaromatic polymer to a gaseous environment containing nitrogen dioxide gas, and measuring the change in electrical characteristics of said film caused by adsorption and/or absorption of said nitrogen dioxide gas.
Claim 17
Independent Claim
53 words
A method of sensing the presence of nitrogen dioxide in the environment, comprising the steps of exposing a film composed of a pyrolyzed polyaromatic polymer to a gaseous environment containing nitrogen dioxide gas, and measuring the change in electrical characteristics of said film caused by adsorption and/or absorption of said nitrogen dioxide gas.
Claim 18
Dependent Claim
20 words
The method of claim 12, wherein said polymer is selected from the group consisting of polyamides, polyamideimides, polyimides and polybenzimidazoles.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-03-05 | 1982-09-04 | 1983-03-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-03-05 | 1986-09-04 | 1987-03-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-03-05 | 1990-09-04 | 1991-03-06 | $7700.00 | Window Closed / Lapsed |