US4141927A
Expired / Lapsed
US
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Novel polyetherimide-polyester blends
Assignee: General Electric Co
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Filing: 1975-05-22
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Granted: 1979-02-27
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Expires: 1995-05-22
Abstract
Abstract This invention is concerned with a new class of polyetherimide-polyester blends. More particularly, the invention is concerned with polyetherimide-polyester blends which exhibit melt viscosities lower than those associated with the polyetherimide component of the blends. The polyetherimide-polyester blends are suitable for the manufacture of filaments, fibers, films, molding compounds, coatings, etc.
Inventors
- 👤 Dwain M. White
- 👤 Robert O. Matthews
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 20:57
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; C08L79/00; C08L79/04; C08L79/08
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
211 words
A polyetherimide-polyester blend comprising: (A) a PEI of the formula ##STR11## where a represents a whole number in excess of 1, --O-Z-O-- is in the 3 or 4-, and 3' or 4'- positions and Z is a member of the class consisting of (1) ##STR12## and (2) divalent organic radicals of the general formula ##STR13## where X is a member selected from the class consisting of divalent radicals of the formulas ##STR14## where q is 0 or 1, y is a whole number from 1 to 5, R is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (c) divalent radicals included by the formula ##STR15## where Q is a member selected from the class consisting of ##STR16## and x is a whole number from 1 to 5 inclusive, and (B) a PE of the formula ##STR17## where b represents a whole number in excess of 1, R' is a divalent alkylene radical containing from 1 to 10 carbon atoms, and the two carbonyl groups are located on the aromatic ring in a para- or meta- position relative to each other.
Claim 2
Dependent Claim
211 words
A polyetherimide-polyester blend comprising: (A) a PEI of the formula ##STR11## where a represents a whole number in excess of 1, --O-Z-O-- is in the 3 or 4-, and 3' or 4'- positions and Z is a member of the class consisting of (1) ##STR12## and (2) divalent organic radicals of the general formula ##STR13## where X is a member selected from the class consisting of divalent radicals of the formulas ##STR14## where q is 0 or 1, y is a whole number from 1 to 5, R is a divalent organic radical selected from the class consisting of (a) aromatic hydrocarbon radicals having from 6-20 carbon atoms and halogenated derivatives thereof, (b) alkylene radicals and cycloalkylene radicals having from 2-20 carbon atoms, C.sub.(2-8) alkylene terminated polydiorganosiloxane, and (c) divalent radicals included by the formula ##STR15## where Q is a member selected from the class consisting of ##STR16## and x is a whole number from 1 to 5 inclusive, and (B) a PE of the formula ##STR17## where b represents a whole number in excess of 1, R' is a divalent alkylene radical containing from 1 to 10 carbon atoms, and the two carbonyl groups are located on the aromatic ring in a para- or meta- position relative to each other.
Claim 3
Dependent Claim
42 words
The PEI-PE blend of claim 1, where the PEI component has an intrinsic viscosity of at least 0.2 dl./g. in m-cresol at 25° C. and the PE component has an intrinsic viscosity of at least 0.2 dl./g. in o-chlorophenol at 25° C.
Claim 4
Dependent Claim
19 words
The PEI-PE blend of claim 1, where the PEI:PE weight ratio range is from about 99:1 to about 1:99.
Claim 5
Dependent Claim
19 words
The PEI-PE blend of claim 1, where the PEI:PE weight ratio range is from about 99:1 to about 75:25.
Claim 6
Dependent Claim
19 words
The PEI-PE blend of claim 1, where the PEI-PE weight ratio range is from about 10:90 to about 1:99.
Claim 7
Dependent Claim
73 words
A polyetherimide-polyester blend comprising (A) a PEI of the formula ##STR18## where a represents a whole number in excess of 1, and (B) a PE of the formula ##STR19## where b represents a whole number in excess of 1, R' is a divalent alkylene radical containing from 1 to 10 carbon atoms, and the two carbonyl groups are located on the aromatic ring in a para- or meta- position relative to each other.
Claim 8
Dependent Claim
73 words
A polyetherimide-polyester blend comprising (A) a PEI of the formula ##STR18## where a represents a whole number in excess of 1, and (B) a PE of the formula ##STR19## where b represents a whole number in excess of 1, R' is a divalent alkylene radical containing from 1 to 10 carbon atoms, and the two carbonyl groups are located on the aromatic ring in a para- or meta- position relative to each other.
Claim 9
Dependent Claim
42 words
The PEI-PE blend of claim 6, where the ##STR20## radical of the PEI is situated in the 3,3'-, 3,4'-, 4,3'- and the 4,4'- positions, the ratio of 3:3' and 4:4' positions being within the range of from about 25:75 to about 75:25.
Claim 10
Dependent Claim
13 words
The PEI-PE blend of claim 7, where the PE is a polybutylene terephthalate.
Claim 11
Dependent Claim
13 words
The PEI-PE blend of claim 7, where the PE is a polyethylene terephthalate.
Claim 12
Dependent Claim
53 words
The PEI-PE blend of claim 6, where the ##STR21## radical of the PEI is situated in the 3,3'-, 3,4'-, 4,3'- and the 4,4'- positions, the ratio of 3:3' and 4:4' positions being within the range of from about 25:75 to about 75:25 and where the PE is a polyethylene terephthalate or polybutylene terephthalate.
Claim 13
Dependent Claim
18 words
The PEI-PE blend of claim 10, where the PEI:PE weight ratio is from about 99:1 to about 75:25.
Claim 14
Dependent Claim
18 words
The PEI-PE blend of claim 10, where the PEI:PE weight ratio is from about 10:90 to about 1:99.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-02-26 | 1982-08-28 | 1983-02-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-02-26 | 1986-08-28 | 1987-02-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-02-26 | 1990-08-28 | 1991-02-27 | $7700.00 | Window Closed / Lapsed |