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US4141869A Expired / Lapsed US ⏱️ 0.0 years remaining

Heat-sealing thermoplastic adhesive

Assignee: Plate Bonn GmbH
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Filing: 1976-09-28
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Granted: 1979-02-27
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Expires: 1996-09-28
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Abstract

Abstract This invention provides a heat-sealing thermoplastic adhesive of a thermoplastic polymer which is resistant to washing and dry-cleaning, which contains from about 0.05 to about 5% by weight, based on the weight of said polymer, of at least one hydrophobic silicone compound. The invention further provides a process for heat-sealing a substrate which has been at least partly hydrophobized with a silicone compound, which comprises the steps of coating with a heat-sealing thermoplastic adhesive of a thermoplastic polymer which is resistant to washing and dry-cleaning and which contains from about 0.5 to about 5% by weight, based on the weight of said polymer, of at least one hydrophobic silicone compound, sintering, fixing and heat-sealing. The adhesives according to the invention are useful for the bonding of substrates which have been hydrophobically finished with silicone compounds, such as raincoat fabrics.

Inventors

  • 👤 Georg Hoss
  • 👤 Eduard De Jong

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 15:58
CPC Classifications
C; C09; C09J; C09J167/00; C09J167/02; C09J175/00; C09J175/04; C09J177/00; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/14; Y; Y10; Y10S; Y10S8/00; Y10S8/01; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663; Y10T442/00; Y10T442/20; Y10T442/2041; Y10T442/2098; Y10T442/2107; Y10T442/2115; Y10T442/2549; Y10T442/2566; Y10T442/2738; Y10T442/2746

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 251 words
A heat-sealing thermoplastic adhesive of a thermoplastic polymer which is resistant to washing and dry-cleaning, selected from the group consisting of (a) copolyamides containing about 80 to 20% by weight of lauric lactam and 20 to 80% by weight of at least one other polyamide forming material; (b) copolyamides containing 25 to 35% by weight of caprolactam; 20 to 40% by weight of lauric lactam; 8 to 25% by weight of hexamethylene diamine adipate and from 10 to 40% by weight of the hexamethylene diamine salt of the acid of formula I, HOOC--(CH 2 ) n --COOH in which n = 7, 8, 10 or 11; (c) copolyamides containing 30% by weight of caprolactam; 30 to 35% by weight of lauric lactam and 10 to 15% by weight of hexamethylene diamine adipate; (d) a copolyamides containing 30% by weight of caprolactam; 30 to 35% by weight of lauric lactam; and 15 to 35% by weight of the hexamethylene diamine salt of the acid of formula I; (e) copolyamides of a polyamide-forming amide salt containing at least 10 carbon atoms, a polyamide forming w-amino acid and, optionally, a polyamide forming lactam; (f) copolyamides of a polyamide-forming amide salt containing at least 10 carbon atoms and a polyamide-forming lactam and crystallisable copolyesters based on terephthalic acid/diol; which contains from about 0.05 to about 5% by weight, based on the weight of said polymer, of at least one hydrophobic organosilicon polymer selected from the group consisting of polyorganosiloxanes, silicones, polysilalkylenes, polysilarylenes, polyorganosilazanes and polyorganooxysiloxanes.
Claim 2
Dependent Claim 251 words
A heat-sealing thermoplastic adhesive of a thermoplastic polymer which is resistant to washing and dry-cleaning, selected from the group consisting of (a) copolyamides containing about 80 to 20% by weight of lauric lactam and 20 to 80% by weight of at least one other polyamide forming material; (b) copolyamides containing 25 to 35% by weight of caprolactam; 20 to 40% by weight of lauric lactam; 8 to 25% by weight of hexamethylene diamine adipate and from 10 to 40% by weight of the hexamethylene diamine salt of the acid of formula I, HOOC--(CH 2 ) n --COOH in which n = 7, 8, 10 or 11; (c) copolyamides containing 30% by weight of caprolactam; 30 to 35% by weight of lauric lactam and 10 to 15% by weight of hexamethylene diamine adipate; (d) a copolyamides containing 30% by weight of caprolactam; 30 to 35% by weight of lauric lactam; and 15 to 35% by weight of the hexamethylene diamine salt of the acid of formula I; (e) copolyamides of a polyamide-forming amide salt containing at least 10 carbon atoms, a polyamide forming w-amino acid and, optionally, a polyamide forming lactam; (f) copolyamides of a polyamide-forming amide salt containing at least 10 carbon atoms and a polyamide-forming lactam and crystallisable copolyesters based on terephthalic acid/diol; which contains from about 0.05 to about 5% by weight, based on the weight of said polymer, of at least one hydrophobic organosilicon polymer selected from the group consisting of polyorganosiloxanes, silicones, polysilalkylenes, polysilarylenes, polyorganosilazanes and polyorganooxysiloxanes.
Claim 3
Dependent Claim 24 words
Adhesive according to claim 1 which contains up to about 50% by weight of plasticizer, based on the total quantity of polymer and plasticizer.
Claim 4
Dependent Claim 23 words
Adhesive according to claim 2, which contains up to 25% by weight of plasticiser, based on the total quantity of polymer and plasticizer.
Claim 5
Dependent Claim 51 words
Adhesive according to claim 2 wherein said plasticizer is a sulphonic acid derivative of formula ##STR2## wherein R 1 represents a group selected from the group consisting of hydrogen and methyl and R 2 represents a group selected from the group consisting of hydrogen, lower alkyl groups and the cyclohexyl group.
Claim 6
Dependent Claim 13 words
Adhesive according to claim 4 wherein said plasticizer is benzene sulphonic acid ethylamide.
Claim 7
Dependent Claim 13 words
Adhesive according to claim 4 wherein said plasticizer is toluene sulphonic acid ethylamide.
Claim 8
Dependent Claim 12 words
Adhesive according to claim 2 wherein said plasticizer is phenol carboxylic acid.
Claim 9
Dependent Claim 15 words
Adhesive according to claim 2 wherein said plasticizer is a phenol carboxylic acid alkyl ester.
Claim 10
Dependent Claim 27 words
Adhesive according to claim 8 wherein said plasticizer is an ester selected from the group consisting of butyl-p-hydroxy benzoate; lauryl-p-hydroxy benzoate; p-hydroxy benzoic acid and octyl-p-hydroxy benzoate.
Claim 11
Dependent Claim 24 words
Adhesive according to claim 1 wherein said hydrophobic silicone compound is a silicone oil having a viscosity from about 0.65 to 1 million centistokes.
Claim 12
Dependent Claim 30 words
Adhesive according to claim 1 wherein said hydrophobic silicone compound is used in a quantity of from about 0.5 to 3% by weight, based on the weight of the polymer.
Claim 13
Dependent Claim 23 words
Adhesive according to claim 1 wherein said hydrophobic silicone compound is used in a quantity of from about 1 to 2% by weight.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-02-26 1982-08-28 1983-02-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-02-26 1986-08-28 1987-02-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-02-26 1990-08-28 1991-02-27 $7700.00 Window Closed / Lapsed

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