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US4141729A Expired / Lapsed US ⏱️ 0.0 years remaining

1,3,4-Oxadiazole derivatives and electrophotographic plates containing same

Assignee: Ricoh Co Ltd
•
Filing: 1977-05-12
•
Granted: 1979-02-27
•
Expires: 1997-05-12
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Abstract

Abstract 1,3,4-OXADIAZOLE DERIVATIVE EXPRESSED BY THE GENERAL FORMULA ##STR1## wherein R represents alkyl having 1-4 carbon atoms, dialkylamino having 1-4 carbon atoms, diarylamino, phenyl, styryl, halogenophenyl, nitrophenyl, alkylphenyl having 1-4 carbon atoms, alkoxyphenyl having 1-4 carbon atoms, cyanophenyl, carboxylic ester substituted phenyl, dialkylaminophenyl having 1-4 carbon atoms, naphthyl, anthryl, or heterocyclic radical, is a photoconductive substance with high sensitivity and is a compound useful as a constituent of electrophotographic plate.

Inventors

  • 👤 Mitsuo Okazaki
  • 👤 Akihiro Yamaguchi
  • 👤 Masaomi Sasaki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 04:32
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/06; G03G5/0622; G03G5/0644; G03G5/0661

Claims Analysis

Total Claims: 34
Claim 1
Independent Claim 39 words
An electrophotographic plate comprising an electrically conductive support and a photoconductive layer overlying said electrically conductive support, said photoconductive layer consisting essentially of a mixture of a charge-generating pigment, a compound having the formula ##STR28## wherein R is diarylamino.
Claim 2
Dependent Claim 39 words
An electrophotographic plate comprising an electrically conductive support and a photoconductive layer overlying said electrically conductive support, said photoconductive layer consisting essentially of a mixture of a charge-generating pigment, a compound having the formula ##STR28## wherein R is diarylamino.
Claim 3
Dependent Claim 11 words
An electrophotographic plate according to claim 1, wherein R is diphenylamino.
Claim 4
Dependent Claim 53 words
An electrophotographic plate according to claim 2, wherein said charge-generating pigment is a member selected from the group consisting of Se, SeTe, SeAs, SeTeAs, CdS, cadmium sulfoselenide, cyanine dye, phthalocyanine dye, disazo dye, indigoid dye, quinacridone dye, polynuclear quinone dye, bis-benzimidazole dye, perylene dye, methine dye, azo dye, xanthene dye and violanthrone dye.
Claim 5
Dependent Claim 23 words
An electrophotographic plate according to claim 2, wherein the thickness of said photoconductive layer is in the range of about 3 to 5μ.
Claim 6
Dependent Claim 67 words
An electrophotographic plate according to claim 2, wherein said binding agent is a member selected from the group consisting of polyamide, polyurethane, acetal resin, butyral resin, polyester, epoxide resin, alkyd resin, polyketone, polycarbonate, polyvinyl ketone, polystyrene, polyacrylamide, polyethylene, polybutadiene, polyvinyl chloride, maleic resin, acrylic resin, methacrylic resin, silicone resin, poly-N-vinyl carbazole, polyvinyl pyrene, polyvinyl anthracene, polyvinyl benzocarbazole, pyrene-formaldehyde resin, bromopyrene-formaldehyde resin, ethyl carbazole-formaldehyde resin, cellulose and gelatin.
Claim 7
Dependent Claim 35 words
An electrophotographic plate according to claim 2, wherein said compound and said charge-generating pigment are contained in an amount of about 30-80% and about 5-50%, respectively, based on the gross weight of the photoconductive layer.
Claim 8
Dependent Claim 43 words
An electrophotographic plate comprising an electrically conductive support, a charge-generating layer overlying said electrically conductive support and a charge-transport layer overlying said charge-generating layer, said charge-transport layer consisting essentially of a mixture of a compound having the formula ##STR29## wherein R is diarylamino.
Claim 9
Dependent Claim 43 words
An electrophotographic plate comprising an electrically conductive support, a charge-generating layer overlying said electrically conductive support and a charge-transport layer overlying said charge-generating layer, said charge-transport layer consisting essentially of a mixture of a compound having the formula ##STR29## wherein R is diarylamino.
Claim 10
Dependent Claim 11 words
An electrophotographic plate according to claim 7, wherein R is diphenylamino.
Claim 11
Dependent Claim 54 words
An electrophotographic plate according to claim 8, wherein said charge-generating layer is composed of a member selected from the group consisting of Se, SeAs, SeTe, SeTeAs, cadmium sulfoselenide, phthalocyanine dye, cyanine dye, disazo dye, indigoid dye, quinacridone dye, polynuclear quinone dye, bis-benzimidazole dye, perylene dye, methine dye, azo dye, xanthene dye and violanthrone dye.
Claim 12
Dependent Claim 38 words
An electrophotographic plate according to claim 8, wherein the thickness of said charge-generating layer is in the range of 0.1 to 5μ, and the thickness of said charge-transport layer is in the range of about 3 to 50μ.
Claim 13
Dependent Claim 17 words
An electrophotographic plate according to claim 8, wherein said charge-generating layer is formed by depositing through evaporation.
Claim 14
Dependent Claim 27 words
An electrophotographic plate according to claim 8, wherein the amount of said compound is about 30 to 90% based on the gross weight of said charge-transport layer.
Claim 15
Dependent Claim 67 words
An electrophotographic plate according to claim 8, wherein said binding agent is a member selected from the group consisting of polyamide, polyurethane, acetal resin, butyral resin, polyester, epoxide resin, alkyd resin, polyketone, polycarbonate, polyvinyl ketone, polystyrene, polyacrylamide, polyethylene, polybutadiene, polyvinyl chloride, maleic resin, acrylic resin, methacrylic resin, silicone resin, poly-N-vinyl carbazole, polyvinyl pyrene, polyvinyl anthracene, polyvinyl benzocarbazole, pyrene-formaldehyde resin, bromopyrene-formaldehyde resin, ethyl carbazole-formaldehyde resin, cellulose and gelatin.
Claim 16
Dependent Claim 53 words
An electrophotographic plate comprising an electrically conductive support and a photoconductive layer overlying said electrically conductive support, said photoconductive layer consisting essentially of a mixture of a charge-generating pigment, a compound having the formula ##STR30## wherein R is dialkylamino in which said alkyl has 1 to 4 carbon atoms, and a binding agent.
Claim 17
Dependent Claim 53 words
An electrophotographic plate comprising an electrically conductive support and a photoconductive layer overlying said electrically conductive support, said photoconductive layer consisting essentially of a mixture of a charge-generating pigment, a compound having the formula ##STR30## wherein R is dialkylamino in which said alkyl has 1 to 4 carbon atoms, and a binding agent.
Claim 18
Dependent Claim 53 words
An electrophotographic plate according to claim 14, wherein said charge-generating pigment is a member selected from the group consisting of Se, SeTe, SeAs, SeTeAs, CdS, cadmium sulfoselenide, cyanine dye, phthalocyanine dye, disazo dye, indigoid dye, quinacridone dye, polynuclear quinone dye, bis-benzimidazole dye, perylene dye, methine dye, azo dye, xanthene dye and violanthrone dye.
Claim 19
Dependent Claim 23 words
An electrophotographic plate according to claim 14, wherein the thickness of said photoconductive layer is in the range of about 3 to 50μ.
Claim 20
Dependent Claim 67 words
An electrophotographic plate according to claim 14, wherein said binding agent is a member selected from the group consisting of polyamide, polyurethane, acetal resin, butyral resin, polyester, epoxide resin, alkyd resin, polyketone, polycarbonate, polyvinyl ketone, polystyrene, polyacrylamide, polyethylene, polybutadiene, polyvinyl chloride, maleic resin, acrylic resin, methacrylic resin, silicone resin, poly-N-vinyl carbazole, polyvinyl pyrene, polyvinyl anthracene, polyvinyl benzocarbazole, pyrene-formaldehyde resin, bromopyrene-formaldehyde resin, ethyl carbazole-formaldehyde resin, cellulose and gelatin.
Claim 21
Dependent Claim 35 words
An electrophotographic plate according to claim 14, wherein said compound and said charge-generating pigment are contained in an amount of about 30-80% and about 5-50%, respectively, based on the gross weight of the photoconductive layer.
Claim 22
Dependent Claim 57 words
An electrophotographic plate comprising an electrically conductive support, a charge-generating layer overlying said electrically conductive support and a charge-transport layer overlying said charge-generating layer, said charge-transport layer consisting essentially of a mixture of a compound having the formula ##STR31## wherein R is dialkylamino in which said alkyl has 1 to 4 carbon atoms, and a binding agent.
Claim 23
Dependent Claim 57 words
An electrophotographic plate comprising an electrically conductive support, a charge-generating layer overlying said electrically conductive support and a charge-transport layer overlying said charge-generating layer, said charge-transport layer consisting essentially of a mixture of a compound having the formula ##STR31## wherein R is dialkylamino in which said alkyl has 1 to 4 carbon atoms, and a binding agent.
Claim 24
Dependent Claim 54 words
An electrophotographic plate according to claim 19, wherein said charge-generating layer is composed of a member selected from the group consisting of Se, SeAs, SeTe, SeTeAs, cadmium sulfoselenide, phthalocyanine dye, cyanine dye, disazo dye, indigoid dye, quinacridone dye, polynuclear quinone dye, bis-benzimidazole dye, perylene dye, methine dye, azo dye, xanthene dye and violanthrone dye.
Claim 25
Dependent Claim 38 words
An electrophotographic plate according to claim 19, wherein the thickness of said charge-generating layer is in the range of 0.1 to 5μ, and the thickness of said charge-transport layer is in the range of about 3 to 50μ.
Claim 26
Dependent Claim 17 words
An electrophotographic plate according to claim 19, wherein said charge-generating layer is formed by depositing through evaporation.
Claim 27
Dependent Claim 27 words
An electrophotographic plate according to claim 19, wherein the amount of said compound is about 30 to 90% based on the gross weight of said charge-transport layer.
Claim 28
Dependent Claim 67 words
An electrophotographic plate according to claim 19, wherein said binding agent is a member selected from the group consisting of polyamide, polyurethane, acetal resin, butyral resin, polyester, epoxide resin, alkyd resin, polyketone, polycarbonate, polyvinyl ketone, polystyrene, polyacrylamide, polyethylene, polybutadiene, polyvinyl chloride, maleic resin, acrylic resin, methacrylic resin, silicone resin, poly-N-vinyl carbazole, polyvinyl pyrene, polyvinyl anthracene, polyvinyl benzocarbazole, pyrene-formaldehyde resin, bromopyrene-formaldehyde resin, ethyl carbazole-formaldehyde resin, cellulose and gelatin.
Claim 29
Dependent Claim 20 words
A compound having the formula ##STR32## wherein R is dialkylamino in which said alkyl has 1 to 4 carbon atoms.
Claim 30
Dependent Claim 20 words
A compound having the formula ##STR32## wherein R is dialkylamino in which said alkyl has 1 to 4 carbon atoms.
Claim 31
Dependent Claim 10 words
A compound according to claim 25, having the formula ##STR33##
Claim 32
Dependent Claim 10 words
A compound having the formula ##STR34## wherein R is diarylamino.
Claim 33
Dependent Claim 10 words
A compound having the formula ##STR34## wherein R is diarylamino.
Claim 34
Dependent Claim 10 words
A compound according to claim 27, having the formula ##STR35##

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-02-26 1982-08-28 1983-02-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-02-26 1986-08-28 1987-02-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-02-26 1990-08-28 1991-02-27 $7700.00 Window Closed / Lapsed

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