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US4139616A Expired / Lapsed US ⏱️ 0.0 years remaining

Fungicidal compositions based on phosphorous acid esters and salts thereof

Assignee: Bayer CropScience SA
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Filing: 1974-12-10
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Granted: 1979-02-13
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Expires: 1994-12-10
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Abstract

Abstract Compositions for controlling fungus disease are disclosed which contain as active material a fungicidally effective amount of at least one compound of the formula ##STR1## IN WHICH R is an optionally halogenated or nitrated, linear or branched alkyl radical containing from 1 to 18 carbon atoms and preferably from 1 to 8 carbon atoms, an optionally halogenated alkenyl or alkinyl radical, an alkoxy alkyl radical, an alkenoxy alkyl radical, the hydrocarbon portion of these four types of radicals containing from 1 to 8 and preferably from 1 to 5 carbon atoms, a cyclohexyl radical, an optionally substituted aryl radical, preferably phenyl, or aryl alkyl radical, preferably phenyl alkyl, or even a heterocyclic radical optionally attached to the oxygen through an aliphatic chain, preferably tetrahydrofurfuryl, M represents an ammonium cation, ammonium substituted by 1 to 4 alkyl or hydroxy alkyl radicals containing from 1 to 5 carbon atoms or by 1 to 2 cyclohexyl radicals or a phenyl radical, or a cation of a metal from the group comprising the alkali metals, preferably sodium and potassium, alkaline earth metals, preferably magnesium, barium, calcium, and polyvalent metals such as, preferably, zinc, manganese, copper(I) and (II), iron, nickel, aluminium, N is an integer equal to the valency of M.

Inventors

  • 👤 Jacques Ducret
  • 👤 Guy Lacroix
  • 👤 Jean-Michel Gaulliard

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 19:44
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; A; A01; A01N; A01N57/00; A01N57/10; C07F9/06; C07F9/08; C07F9/141

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 188 words
A fungicidal composition for controlling fungus disease in plants comprising as an active material, a fungicidally effective quantity of at least one compound of the formula ##STR58## in which R is selected from a member of the group consisting of an alkyl, halogen-substituted alkyl or nitro-substituted alkyl radical, the alkyl portion of said alkyl radicals containing from 1 to 8 carbon atoms, an alkenyl, halogen-substituted alkenyl, alkinyl, halogen-substituted alkinyl and an alkoxy-substituted alkyl radical, the hydrocarbon portion of said alkenyl, alkinyl and alkoxy-alkyl radicals containing from 2 to 5 carbon atoms, M is selected from a member of the group consisting of an ammonium cation; ammonium substituted by a member of the group consisting of 1 to 4 alkyl or hydroxy-alkyl radicals each containing from 1 to 5 carbon atoms, 1 to 2 cyclohexyl radicals and a phenyl radical; and a cation of a metal from the group consisting of the alkali metals, alkaline earth metals, and polyvalent metals of zinc, manganese, copper (I) and (II), iron, nickel and aluminum and n is an integer equal to the valency of M in combination with an agriculturally acceptable carrier.
Claim 2
Dependent Claim 188 words
A fungicidal composition for controlling fungus disease in plants comprising as an active material, a fungicidally effective quantity of at least one compound of the formula ##STR58## in which R is selected from a member of the group consisting of an alkyl, halogen-substituted alkyl or nitro-substituted alkyl radical, the alkyl portion of said alkyl radicals containing from 1 to 8 carbon atoms, an alkenyl, halogen-substituted alkenyl, alkinyl, halogen-substituted alkinyl and an alkoxy-substituted alkyl radical, the hydrocarbon portion of said alkenyl, alkinyl and alkoxy-alkyl radicals containing from 2 to 5 carbon atoms, M is selected from a member of the group consisting of an ammonium cation; ammonium substituted by a member of the group consisting of 1 to 4 alkyl or hydroxy-alkyl radicals each containing from 1 to 5 carbon atoms, 1 to 2 cyclohexyl radicals and a phenyl radical; and a cation of a metal from the group consisting of the alkali metals, alkaline earth metals, and polyvalent metals of zinc, manganese, copper (I) and (II), iron, nickel and aluminum and n is an integer equal to the valency of M in combination with an agriculturally acceptable carrier.
Claim 3
Dependent Claim 16 words
A fungicidal composition according to claim 1 which contains an inert carrier and a compatible surfactant.
Claim 4
Dependent Claim 81 words
A fungicidal composition according to claim 1 in the form of a wettable powder containing about 20 to 95% by weight of said active material, about 0 to 5% by weight of a wetting agent, from 3 to 10% by weight of a dispersant and from 0 to 10% by weight of other additives selected from the group consisting of a stabilizer, a penetration agent, an adhesive, an anti-lumping agent, a colorant and mixtures thereof, the balance being inert solid support.
Claim 5
Dependent Claim 44 words
A fungicidal composition according to claim 1 in which said composition is in the form of a soluble powder containing about 20 to 95% of said active material, 0 to 10% of an anti-lumping agent and the balance being a hydrosoluble inert solid support.
Claim 6
Dependent Claim 33 words
A fungicidal composition according to claim 1 which contains an inert solid carrier and a compatible surfactant, wherein said composition is in the form selected from a wettable powder and a soluble powder.
Claim 7
Dependent Claim 41 words
A composition as claimed in claim 1, wherein M is an ammonium cation substituted by 1 to 4 alkyl radicals or hydroxy-alkyl radicals containing from 1 to 5 carbon atoms or by 1 to 2 cyclohexyl radicals or a phenyl radical.
Claim 8
Dependent Claim 14 words
A composition as claimed in claim 1, wherein M is an alkali metal cation.
Claim 9
Dependent Claim 15 words
A composition as claimed in claim 1, wherein M is an alkaline earth metal cation.
Claim 10
Dependent Claim 32 words
A composition as claimed in claim 1, wherein M is a cation of a metal from the group comprising zinc, manganese, copper (I) and (II), iron (II) and (III) nickel and aluminum.
Claim 11
Dependent Claim 39 words
A composition as claimed in claim 1, wherein R is an alkyl radical, a halogen substituted alkyl radical containing from 1 to 4 carbon atoms, an allyl, propargyl, allyl-oxy or alkoxy-alkyl radical containing from 2 to 3 carbon atoms.
Claim 12
Dependent Claim 13 words
A composition as claimed in claim 10, wherein R is the ethyl radical.
Claim 13
Dependent Claim 13 words
A composition as claimed in claim 10, wherein R is the isopropyl radical.
Claim 14
Dependent Claim 15 words
A composition as claimed in claim 11, wherein the active material is sodium O-ethyl phosphite.
Claim 15
Dependent Claim 15 words
A composition as claimed in claim 11, wherein the active material is calcium O-ethyl phosphite.
Claim 16
Dependent Claim 15 words
A composition as claimed in claim 11, wherein the active material is aluminum O-ethyl phosphite.
Claim 17
Dependent Claim 15 words
A composition as claimed in claim 11, wherein the active material is magnesium O-ethyl phosphite.
Claim 18
Dependent Claim 15 words
A composition as claimed in claim 11, wherein the active material is zinc O-ethyl phosphite.
Claim 19
Dependent Claim 15 words
A composition as claimed in claim 11, wherein the active material is cuprous O-ethyl phosphite.
Claim 20
Dependent Claim 15 words
A composition as claimed in claim 11, wherein the active material is cupric O-ethyl phosphite.
Claim 21
Dependent Claim 15 words
A composition as claimed in claim 12, wherein the active material is sodium O-isopropyl phosphite.
Claim 22
Dependent Claim 15 words
A composition as claimed in claim 12, wherein the active material is calcium O-isopropyl phosphite.
Claim 23
Dependent Claim 15 words
A composition as claimed in claim 12, wherein the active material is aluminum O-isopropyl phosphonate.
Claim 24
Dependent Claim 15 words
A composition as claimed in claim 12, wherein the active material is magnesium O-isopropyl phosphite.
Claim 25
Dependent Claim 15 words
A composition as claimed in claim 12, wherein the active material is zinc O-isopropyl phosphite.
Claim 26
Dependent Claim 15 words
A composition as claimed in claim 12, wherein the active material is cuprous O-isopropyl phosphite.
Claim 27
Dependent Claim 15 words
A composition as claimed in claim 12, wherein the active material is cupric O-isopropyl phosphite.
Claim 28
Dependent Claim 13 words
A composition as claimed in claim 1, which additionally contains a known fungicide.
Claim 29
Dependent Claim 18 words
A fungicidal composition as claimed in claim 1 wherein R is said alkyl radical containing 1-8 carbon atoms.
Claim 30
Independent Claim 179 words
A method for controlling fungal diseases in plants which comprises applying a fungicidally effective amount of at least one compound of the formula ##STR59## in which R is selected from a member of the group consisting of an alkyl, halogen-substituted alkyl or nitro-substituted alkyl radical, the alkyl portion of said alkyl radicals containing from 1 to 8 carbon atoms, an alkenyl, halogen-substituted alkenyl, alkinyl, halogen-substituted alkinyl and an alkoxy-substituted alkyl radical, the hydrocarbon portion of said alkenyl, alkinyl and alkoxy-alkyl radicals each containing from 2 to 5 carbon atoms, M is selected from a member of the group consisting of an ammonium cation; ammonium substituted by a member of the group consisting of 1 to 4 alkyl or hydroxy-alkyl radicals each containing from 1 to 5 carbon atoms, 1 to 2 cyclohexyl radicals, and a phenyl radical; and a cation of a metal from the group consisting of the alkali metals, alkaline earth metals, and polyvalent metals of zinc, manganese, copper (I) and (II), iron, nickel and aluminum and n is an integer equal to the valency of M.
Claim 31
Independent Claim 179 words
A method for controlling fungal diseases in plants which comprises applying a fungicidally effective amount of at least one compound of the formula ##STR59## in which R is selected from a member of the group consisting of an alkyl, halogen-substituted alkyl or nitro-substituted alkyl radical, the alkyl portion of said alkyl radicals containing from 1 to 8 carbon atoms, an alkenyl, halogen-substituted alkenyl, alkinyl, halogen-substituted alkinyl and an alkoxy-substituted alkyl radical, the hydrocarbon portion of said alkenyl, alkinyl and alkoxy-alkyl radicals each containing from 2 to 5 carbon atoms, M is selected from a member of the group consisting of an ammonium cation; ammonium substituted by a member of the group consisting of 1 to 4 alkyl or hydroxy-alkyl radicals each containing from 1 to 5 carbon atoms, 1 to 2 cyclohexyl radicals, and a phenyl radical; and a cation of a metal from the group consisting of the alkali metals, alkaline earth metals, and polyvalent metals of zinc, manganese, copper (I) and (II), iron, nickel and aluminum and n is an integer equal to the valency of M.

References Cited (Backward Citations)

US2792374A Cited
GB1334850A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-02-12 1982-08-14 1983-02-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-02-12 1986-08-14 1987-02-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-02-12 1990-08-14 1991-02-13 $7700.00 Window Closed / Lapsed

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