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US4139569A
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Vapor phase cracking of dicyclopentadiene and synthesis of 2,3-dihydroxycyclopentadiene and cyclopentene
Assignee: Goodrich Corp
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Filing: 1977-11-14
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Granted: 1979-02-13
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Expires: 1997-11-14
Abstract
Abstract Improved process for vapor phase cracking of dicyclopentadiene and synthesis of 2,3-dihydrodicyclopentadiene therefrom. Initially, a feedstock consisting essentially of dicyclopentadiene and cyclopentene is subjected to thermocracking in the vapor phase, resulting in the conversion of dicyclopentadiene to monomeric cyclopentadiene. The presence of cyclopentene in the feed stock is believed to minimize coke formation on the interior walls of the cracking chamber. Subsequent selective catalytic hydrogenation of the resulting mixture converts substantially all of the monomeric cyclopentadiene to cyclopentene. The cyclopentene, prepared in the above manner, can be combined with additional quantitie;s of dicyclopentadiene and the resultant mixture subjected to dimerization in the liquid phase at elevated temperatures, thereby forming the monomer, 2,3-dihydrodicyclopentadiene.
Inventors
- 👤 Parley C. Lane, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 11:51
CPC Classifications
C; C07; C07C; C07C13/00; C07C13/28; C07C13/32; C07C13/54; C07C13/605; C07C13/61; C07C2/00; C07C2/02; C07C2/50; C07C4/00; C07C4/22; C07C2601/00; C07C2601/06; C07C2601/10; C07C2603/00; C07C2603/56; C07C2603/58; C07C2603/60; C07C2603/66; C07C2603/68
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
74 words
A process for vapor phase cracking of dicyclopentadiene, said process comprising: providing a feedstock consisting essentially of dicyclopentadiene and cyclopentene; and introducing said feedstock in the vapor phase into a pyrolytic chamber, said pyrolytic chamber being maintained at a temperature in the range of from about 200° to 400° C. and the residence time of the feedstock in said chamber being sufficient to effect cracking of at least some of said dicyclopentadiene to cyclopentadiene.
Claim 2
Dependent Claim
74 words
A process for vapor phase cracking of dicyclopentadiene, said process comprising: providing a feedstock consisting essentially of dicyclopentadiene and cyclopentene; and introducing said feedstock in the vapor phase into a pyrolytic chamber, said pyrolytic chamber being maintained at a temperature in the range of from about 200° to 400° C. and the residence time of the feedstock in said chamber being sufficient to effect cracking of at least some of said dicyclopentadiene to cyclopentadiene.
Claim 3
Dependent Claim
14 words
The process of claim 1 wherein the pyrolytic chamber is maintained at superatmospheric pressures.
Claim 4
Dependent Claim
24 words
The process of claim 1 wherein the temperature of the pyrolytic chamber is maintained within a range of from about 300° to 350° C.
Claim 5
Dependent Claim
20 words
The process of claim 1 wherein the feedstock contains a minor amount of dicyclopentadiene and a major amount of cyclopentene.
Claim 6
Dependent Claim
143 words
A process for preparation of 2,3-dihydrodicyclopentadiene, said process comprising: providing a feedstock consisting essentially of dicyclopentadiene and cyclopentene; introducing said feedstock in the vapor phase into a pyrolytic chamber, said pyrolytic chamber being maintained at a temperature in the range of from about 200° to 400° C. and the residence time of the feedstock in said chamber being sufficient to effect cracking of at least some of said dicyclopentadiene to cyclopentadiene hydrogenating the lighter of the two fractions of an effluent, obtained from pyrolysis of the feedstock, to a suitable hydrogenation catalyst and hydrogen thereby converting substantially all of the monomeric cyclopentadiene of said effluent to cyclopentene; and introducing the effluent produced during the said hydrogenation and a source of cyclopentadiene into a liquid phase dimerizer, the temperature within said dimerizer being maintained within a range of from about 200° to 240° C.
Claim 7
Dependent Claim
143 words
A process for preparation of 2,3-dihydrodicyclopentadiene, said process comprising: providing a feedstock consisting essentially of dicyclopentadiene and cyclopentene; introducing said feedstock in the vapor phase into a pyrolytic chamber, said pyrolytic chamber being maintained at a temperature in the range of from about 200° to 400° C. and the residence time of the feedstock in said chamber being sufficient to effect cracking of at least some of said dicyclopentadiene to cyclopentadiene hydrogenating the lighter of the two fractions of an effluent, obtained from pyrolysis of the feedstock, to a suitable hydrogenation catalyst and hydrogen thereby converting substantially all of the monomeric cyclopentadiene of said effluent to cyclopentene; and introducing the effluent produced during the said hydrogenation and a source of cyclopentadiene into a liquid phase dimerizer, the temperature within said dimerizer being maintained within a range of from about 200° to 240° C.
Claim 8
Dependent Claim
18 words
The process of claim 5 wherein the products of said dimerization are separated from one another by distillation.
Claim 9
Dependent Claim
22 words
The process of claim 6 wherein at least some of the products recovered from distillation are recycled back into the initial feedstock.
Claim 10
Dependent Claim
75 words
A process for vapor phase cracking of dicyclopentadiene, said process comprising: providing a feedstock consisting essentially of dicyclopentadiene, cyclopentene and hydrogen; and introducing said feedstock in the vapor phase into a pyrolytic chamber, said pyrolytic chamber being maintained at a temperature in the range of from about 200° to 400° C. and the residence time of the feedstock in said chamber being sufficient to effect cracking of at least some of said dicyclopentadiene to cyclopentadiene.
Claim 11
Dependent Claim
75 words
A process for vapor phase cracking of dicyclopentadiene, said process comprising: providing a feedstock consisting essentially of dicyclopentadiene, cyclopentene and hydrogen; and introducing said feedstock in the vapor phase into a pyrolytic chamber, said pyrolytic chamber being maintained at a temperature in the range of from about 200° to 400° C. and the residence time of the feedstock in said chamber being sufficient to effect cracking of at least some of said dicyclopentadiene to cyclopentadiene.
Claim 12
Dependent Claim
140 words
A process for preparation of 2,3-dihydrodicyclopentadiene, said process comprising: providing a feedstock consisting essentially of dicyclopentadiene, cyclopentene and hydrogen; introducing said feedstock in the vapor phase into a pyrolytic chamber, said pyrolytic chamber being maintained at a temperature in the range of from about 200° to 400° C. and the residence time of the feedstock in said chamber being sufficient to effect cracking of at least some of said dicyclopentadiene to cyclopentadiene. subjecting the lighter of the two fractions of an effluent, obtained from pyrolysis of the feedstock, to selective hydrogenation thereby converting substantially all of the monomeric cyclopentadiene of said effluent to cyclopentene; and introducing the effluent produced during the said hydrogenation and a source of cyclopentadiene into a liquid phase dimerizer, the temperature within said dimerizer being maintained within a range of from about 220° to 240° C.
Claim 13
Dependent Claim
140 words
A process for preparation of 2,3-dihydrodicyclopentadiene, said process comprising: providing a feedstock consisting essentially of dicyclopentadiene, cyclopentene and hydrogen; introducing said feedstock in the vapor phase into a pyrolytic chamber, said pyrolytic chamber being maintained at a temperature in the range of from about 200° to 400° C. and the residence time of the feedstock in said chamber being sufficient to effect cracking of at least some of said dicyclopentadiene to cyclopentadiene. subjecting the lighter of the two fractions of an effluent, obtained from pyrolysis of the feedstock, to selective hydrogenation thereby converting substantially all of the monomeric cyclopentadiene of said effluent to cyclopentene; and introducing the effluent produced during the said hydrogenation and a source of cyclopentadiene into a liquid phase dimerizer, the temperature within said dimerizer being maintained within a range of from about 220° to 240° C.
References Cited (Backward Citations)
US2793238A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-02-12 | 1982-08-14 | 1983-02-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-02-12 | 1986-08-14 | 1987-02-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-02-12 | 1990-08-14 | 1991-02-13 | $7700.00 | Window Closed / Lapsed |