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US4138538A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing a transparent shaped polymeric product

Assignee: Japan Atomic Energy Agency
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Filing: 1976-03-24
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Granted: 1979-02-06
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Expires: 1996-03-24
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Abstract

Abstract This invention provides a process for preparing a transparent polymeric product free from strain and bubbles and having improved physical and chemical properties. The product can be produced from a bis-allylcarbonate-based monomer mixture by cast polymerization for extremely shortened polymerization time.

Inventors

  • 👤 Isao Kaetsu
  • 👤 Hiroshi Okubo
  • 👤 Fumio Yoshii

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 06:37
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/04; C; C08; C08F; C08F218/00; C08F218/24

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 230 words
A process for efficiently producing a transparent shaped polymeric product, free from defects such as bubbles and strain, of sufficiently high mechanical strength, surface hardness, weather resistance, and impact resistance to serve as a substitute for inorganic glass, consisting essentially of the steps of: mixing (A) one or more compounds represented by the formula ##STR4## wherein X is H or CH 3 and l is an integer of from 1 to 4, or a prepolymer thereof, in an amount of from 30 to 80% by weight, (B) one or more compounds represented by the formula ##STR5## wherein X is H or CH 3 , n is an integer of 2, 3 or 4 and m is an integer of from 3 to 6, or a prepolymer thereof, in an amount of from 70 to 20% by weight based on the total amount of (A) and (B), and (C) a radical polymerization catalyst in an amount of from 0.5 to 5 parts by weight per 100 parts of the total amount of (A) and (B); pouring the mixture into a cell or mold adapted to cast polymerization; irradiating it with light of ionizing radiation at a temperature below room temperature to subject it to cast polymerization; and then heating it to a temperature ranging from 80° C. to the decomposition temperature of the copolymer to be produced to complete the polymerization.
Claim 2
Dependent Claim 230 words
A process for efficiently producing a transparent shaped polymeric product, free from defects such as bubbles and strain, of sufficiently high mechanical strength, surface hardness, weather resistance, and impact resistance to serve as a substitute for inorganic glass, consisting essentially of the steps of: mixing (A) one or more compounds represented by the formula ##STR4## wherein X is H or CH 3 and l is an integer of from 1 to 4, or a prepolymer thereof, in an amount of from 30 to 80% by weight, (B) one or more compounds represented by the formula ##STR5## wherein X is H or CH 3 , n is an integer of 2, 3 or 4 and m is an integer of from 3 to 6, or a prepolymer thereof, in an amount of from 70 to 20% by weight based on the total amount of (A) and (B), and (C) a radical polymerization catalyst in an amount of from 0.5 to 5 parts by weight per 100 parts of the total amount of (A) and (B); pouring the mixture into a cell or mold adapted to cast polymerization; irradiating it with light of ionizing radiation at a temperature below room temperature to subject it to cast polymerization; and then heating it to a temperature ranging from 80° C. to the decomposition temperature of the copolymer to be produced to complete the polymerization.
Claim 3
Dependent Claim 34 words
A process according to claim 1 wherein the component (A) is a compound represented by the formula ##STR6## wherein X is H or CH 3 and l is an integer of 1,2 or 3.
Claim 4
Dependent Claim 14 words
A process according to claim 1 wherein the component (A) is diethyleneglycol-bis-allylcarbonate or diethyleneglycol-bis-methallylcarbonate.
Claim 5
Dependent Claim 26 words
A process according to claim 1 wherein the component (B) is a compound represented by the formula ##STR7## wherein X is H or CH 3 .
Claim 6
Dependent Claim 15 words
A process according to claim 1 wherein said temperature during irradiation is below -30° C.
Claim 7
Dependent Claim 16 words
A process according to claim 1 wherein said ionizing radiation is gamma rays or electron beams.
Claim 8
Dependent Claim 40 words
A process according to claim 1 wherein said irradiation of ionizing radiation is carried out at a dose rate of from 10 2 to 10 9 roentgen/hr and with a total dose of from 10 4 to 10 7 roentgen.
Claim 9
Dependent Claim 46 words
A process according to claim 1 wherein a monomer copolymerizable with said components (A) and (B) is mixed with said components (A) and (B) in an amount less than 40% by weight based on the total amount of the components (A) and (B) and this monomer.
Claim 10
Dependent Claim 16 words
A process according to claim 8 wherein said monomer is a lower alkyl acrylate or methacrylate.
Claim 11
Dependent Claim 15 words
A process according to claim 1 wherein said temperature during irradiation is below 0° C.

References Cited (Backward Citations)

US2480751A Cited
US3221083A Cited
US3880818A Cited
US3872042A Cited
US3955015A Cited
US4010088A Cited
US3787378A Cited
US3983083A Cited
US3944637A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-02-05 1982-08-07 1983-02-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-02-05 1986-08-07 1987-02-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-02-05 1990-08-07 1991-02-06 $7700.00 Window Closed / Lapsed

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