US4138538A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for producing a transparent shaped polymeric product
Assignee: Japan Atomic Energy Agency
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Filing: 1976-03-24
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Granted: 1979-02-06
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Expires: 1996-03-24
Abstract
Abstract This invention provides a process for preparing a transparent polymeric product free from strain and bubbles and having improved physical and chemical properties. The product can be produced from a bis-allylcarbonate-based monomer mixture by cast polymerization for extremely shortened polymerization time.
Inventors
- 👤 Isao Kaetsu
- 👤 Hiroshi Okubo
- 👤 Fumio Yoshii
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 06:37
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/04; C; C08; C08F; C08F218/00; C08F218/24
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
230 words
A process for efficiently producing a transparent shaped polymeric product, free from defects such as bubbles and strain, of sufficiently high mechanical strength, surface hardness, weather resistance, and impact resistance to serve as a substitute for inorganic glass, consisting essentially of the steps of: mixing (A) one or more compounds represented by the formula ##STR4## wherein X is H or CH 3 and l is an integer of from 1 to 4, or a prepolymer thereof, in an amount of from 30 to 80% by weight, (B) one or more compounds represented by the formula ##STR5## wherein X is H or CH 3 , n is an integer of 2, 3 or 4 and m is an integer of from 3 to 6, or a prepolymer thereof, in an amount of from 70 to 20% by weight based on the total amount of (A) and (B), and (C) a radical polymerization catalyst in an amount of from 0.5 to 5 parts by weight per 100 parts of the total amount of (A) and (B); pouring the mixture into a cell or mold adapted to cast polymerization; irradiating it with light of ionizing radiation at a temperature below room temperature to subject it to cast polymerization; and then heating it to a temperature ranging from 80° C. to the decomposition temperature of the copolymer to be produced to complete the polymerization.
Claim 2
Dependent Claim
230 words
A process for efficiently producing a transparent shaped polymeric product, free from defects such as bubbles and strain, of sufficiently high mechanical strength, surface hardness, weather resistance, and impact resistance to serve as a substitute for inorganic glass, consisting essentially of the steps of: mixing (A) one or more compounds represented by the formula ##STR4## wherein X is H or CH 3 and l is an integer of from 1 to 4, or a prepolymer thereof, in an amount of from 30 to 80% by weight, (B) one or more compounds represented by the formula ##STR5## wherein X is H or CH 3 , n is an integer of 2, 3 or 4 and m is an integer of from 3 to 6, or a prepolymer thereof, in an amount of from 70 to 20% by weight based on the total amount of (A) and (B), and (C) a radical polymerization catalyst in an amount of from 0.5 to 5 parts by weight per 100 parts of the total amount of (A) and (B); pouring the mixture into a cell or mold adapted to cast polymerization; irradiating it with light of ionizing radiation at a temperature below room temperature to subject it to cast polymerization; and then heating it to a temperature ranging from 80° C. to the decomposition temperature of the copolymer to be produced to complete the polymerization.
Claim 3
Dependent Claim
34 words
A process according to claim 1 wherein the component (A) is a compound represented by the formula ##STR6## wherein X is H or CH 3 and l is an integer of 1,2 or 3.
Claim 4
Dependent Claim
14 words
A process according to claim 1 wherein the component (A) is diethyleneglycol-bis-allylcarbonate or diethyleneglycol-bis-methallylcarbonate.
Claim 5
Dependent Claim
26 words
A process according to claim 1 wherein the component (B) is a compound represented by the formula ##STR7## wherein X is H or CH 3 .
Claim 6
Dependent Claim
15 words
A process according to claim 1 wherein said temperature during irradiation is below -30° C.
Claim 7
Dependent Claim
16 words
A process according to claim 1 wherein said ionizing radiation is gamma rays or electron beams.
Claim 8
Dependent Claim
40 words
A process according to claim 1 wherein said irradiation of ionizing radiation is carried out at a dose rate of from 10 2 to 10 9 roentgen/hr and with a total dose of from 10 4 to 10 7 roentgen.
Claim 9
Dependent Claim
46 words
A process according to claim 1 wherein a monomer copolymerizable with said components (A) and (B) is mixed with said components (A) and (B) in an amount less than 40% by weight based on the total amount of the components (A) and (B) and this monomer.
Claim 10
Dependent Claim
16 words
A process according to claim 8 wherein said monomer is a lower alkyl acrylate or methacrylate.
Claim 11
Dependent Claim
15 words
A process according to claim 1 wherein said temperature during irradiation is below 0° C.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-02-05 | 1982-08-07 | 1983-02-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-02-05 | 1986-08-07 | 1987-02-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-02-05 | 1990-08-07 | 1991-02-06 | $7700.00 | Window Closed / Lapsed |