Conversion of liquid alcohols and ethers with a fluid mass of ZSM-5 type catalyst

Claim 1

A method for converting a chemical reactant selected from the group consisting of methanol, ethanol, ether derivatives of lower alcohols and mixtures of alcohols and ethers to gasoline boiling range constituents with fluidizable catalyst particles comprising a crystalline zeolite having a pore dimension greater than about 5 Angstroms, a silica to alumina ratio of at least 12 and a constraint index within the range of 1 to 12 which comprises, maintaining said fluidizable catalysts particles flowing from the lower portion of a reaction zone to an upper portion thereof and through a plurality of adjacent and vertically spaced apart confined passageways in said reaction zone, said passageways arranged to promote a continuous upward flow of dispersed reactant, formed product thereof and suspended catalyst particles through the reaction zone, charging chemical reactant to the lower portion of said reaction zone as a plurality of separate streams each in alignment with a lower most confined passageway, recycling a plurality of separate confined catalyst streams from an upper portion of said reaction zone to a lower portion thereof so that recycled catalysts is discharged beneath and adjacent a lower most confined passageway, effecting temperature restraint in the reaction zone not to exceed about 1000° F. and imposing a temperature restraint in the chemical reactant and entrained catalyst in the lower portion of the reaction zone by effecting at least partial vaporization of the chemical reactant upon contact with hot recycled catalysts and thereafter passed upwardly through said confined passageways in said reaction zone.

Claim 2

A method for converting a chemical reactant selected from the group consisting of methanol, ethanol, ether derivatives of lower alcohols and mixtures of alcohols and ethers to gasoline boiling range constituents with fluidizable catalyst particles comprising a crystalline zeolite having a pore dimension greater than about 5 Angstroms, a silica to alumina ratio of at least 12 and a constraint index within the range of 1 to 12 which comprises, maintaining said fluidizable catalysts particles flowing from the lower portion of a reaction zone to an upper portion thereof and through a plurality of adjacent and vertically spaced apart confined passageways in said reaction zone, said passageways arranged to promote a continuous upward flow of dispersed reactant, formed product thereof and suspended catalyst particles through the reaction zone, charging chemical reactant to the lower portion of said reaction zone as a plurality of separate streams each in alignment with a lower most confined passageway, recycling a plurality of separate confined catalyst streams from an upper portion of said reaction zone to a lower portion thereof so that recycled catalysts is discharged beneath and adjacent a lower most confined passageway, effecting temperature restraint in the reaction zone not to exceed about 1000° F. and imposing a temperature restraint in the chemical reactant and entrained catalyst in the lower portion of the reaction zone by effecting at least partial vaporization of the chemical reactant upon contact with hot recycled catalysts and thereafter passed upwardly through said confined passageways in said reaction zone.