Polymeric antioxidants

Claim 2

A vulcanizable polymeric composition comprising a mixture of at least two compatible polymers, a first polymer being a conjugated diolefin polymer of molecular weight from about 1,500 to about 35,000 and being the reaction product of a reactive polymer containing chemically bound to the polymer a multiplicity of chemically reactive groups selected from olefinic carbon-carbon double bonds, aldehyde, carboxyl, hydroxy, halogen and mixtures thereof, with one or more antioxidant functional group containing compounds of form BX, where B is a functional group selected from amine, alkali metal, hydroxyl, aldehyde and mixtures thereof and capable of reacting with said chemically reactive groups, and X is an antioxidant functional group selected from diphenylamines, phenylene diamines, phenyl naphthylamines, hindered phenols and triphenyl phosphite, said antioxidant functional groups forming from about 20 to about 45 weight percent of said first polymer and said first polymer forming from about 5 to about 20 weight percent based on polymeric components of said mixture, the second polymer being at least one rubbery polymer having a molecular weight of about 150,000 to about 500,000 and being selected from polymers of conjugated diolefins, copolymers of conjugated diolefins with vinyl or vinylidene aromatic compounds, copolymers of conjugated diolefins and olefinically unsaturated nitrile compounds, copolymers of isoolefins and diolefins, alpha-mono-olefin copolymers or blends thereof, said first polymer being vulcanizable with said second polymer.

Claim 3

The composition of claim 1 wherein said first polymer has a molecular weight of about 2,000 to about 20,000.

Claim 4

The composition of claim 1 wherein said chemically reactive groups are aldehyde.

Claim 5

The composition of claim 3 wherein the functional group B is an amine group.

Claim 6

The composition of claim 4 in which the compound BX is p-amino-diphenyl-amine.

Claim 7

The composition of claim 1 wherein said second polymer is selected from butadiene-styrene polymers, butadieneacrylonitrile polymers, isoprene-acrylonitrile polymers, butadiene polymers, isoprene polymers, isobutylene-isoprene polymers and ethylene-propylene-non-conjugated diene polymers.

Claim 8

A process of preparing a vulcanized composition having improved aging characteristics which comprises mixing a first polymer with at least one second polymer and heating the mixture in the presence of vulcanization-active agents for the mixture, said first polymer being a conjugated diolefin polymer of molecular weight from about 1,500 to about 35,000 and being the reaction product of a reactive polymer containing chemically bound to the polymer a multiplicity of chemically reactive groups selected from olefinic carbon-carbon double bonds, aldehyde, carboxyl, hydroxy, halogen and mixtures thereof, with one or more antioxidant functional group containing compounds of form BX, where B is a functional group selected from amine, alkali metal, hydroxyl, aldehyde and mixtures thereof and capable of reacting with said chemically reactive groups and X is an antioxidant functional group selected from diphenylamines, phenylene diamines, phenyl naphthylamines, hindered phenols and triphenyl phosphite, said antioxidant functional groups forming from about 20 to about 45 weight percent of said first polymer, said first polymer being covulcanizable with said second polymer, the second polymer being a rubbery polymer having a molecular weight of about 150,000 to about 500,000 and being compatible with said first polymer, said second polymer being selected from polymers of conjugated diolefins, copolymers of conjugated diolefins with vinyl or vinylidene aromatic compounds, copolymers of conjugated diolefins with olefinically unsaturated nitrile compounds, copolymers of isoolefins and diolefins, alpha-mono-olefin copolymers or blends thereof, said first polymer forming from about 5 to about 20 weight percent based on polymeric compounds of said mixture.

Claim 9

A process of preparing a vulcanized composition having improved aging characteristics which comprises mixing a first polymer with at least one second polymer and heating the mixture in the presence of vulcanization-active agents for the mixture, said first polymer being a conjugated diolefin polymer of molecular weight from about 1,500 to about 35,000 and being the reaction product of a reactive polymer containing chemically bound to the polymer a multiplicity of chemically reactive groups selected from olefinic carbon-carbon double bonds, aldehyde, carboxyl, hydroxy, halogen and mixtures thereof, with one or more antioxidant functional group containing compounds of form BX, where B is a functional group selected from amine, alkali metal, hydroxyl, aldehyde and mixtures thereof and capable of reacting with said chemically reactive groups and X is an antioxidant functional group selected from diphenylamines, phenylene diamines, phenyl naphthylamines, hindered phenols and triphenyl phosphite, said antioxidant functional groups forming from about 20 to about 45 weight percent of said first polymer, said first polymer being covulcanizable with said second polymer, the second polymer being a rubbery polymer having a molecular weight of about 150,000 to about 500,000 and being compatible with said first polymer, said second polymer being selected from polymers of conjugated diolefins, copolymers of conjugated diolefins with vinyl or vinylidene aromatic compounds, copolymers of conjugated diolefins with olefinically unsaturated nitrile compounds, copolymers of isoolefins and diolefins, alpha-mono-olefin copolymers or blends thereof, said first polymer forming from about 5 to about 20 weight percent based on polymeric compounds of said mixture.

Claim 10

The process of claim 7 in which the mixture is heated for from 2 minutes to about 200 minutes at a temperature of from about 200° F. to about 450° F.

Claim 11

The process of claim 7 wherein said first and second polymers are mixed prior to the incorporation of the vulcanization-active agents.