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US4138371A
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Washing method using amphoteric surface active agents
Assignee: Rhone Poulenc Surfactants and Specialties LP
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Filing: 1977-08-08
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Granted: 1979-02-06
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Expires: 1997-08-08
Abstract
Abstract Compounds having the formula <IMAGE> wherein R represents a C8-C14 aliphatic radical; R1 represents a C1-C4 lower alkyl radical; R2 and R3 each represent H or CH3; M1 and M2 represent cations of hydrogen, ammonium, alkyl ammonium, alkali metal, or an equivalent of alkaline earth metal; n is an integer having an average value of from 5 to 10; s and t can either be 0 or 1 but both cannot be simultaneously 0; and A represents an anionic radical such as hydroxide, halogen, sulfate, alkyl sulfate, etc. are useful as essentially non-iritating and high foaming amphoteric surface active agents for shampoo and other cosmetic applications. Preferably R is a naturally derived or synthetic alkyl group containing 10-12 carbon atoms.
Inventors
- 👤 Robert J. Verdiccio
- 👤 Louis J. Nehmsmann
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 10:31
CPC Classifications
A; A61; A61Q; A61Q19/00; A61Q19/10; A61K; A61K8/00; A61K8/18; A61K8/30; A61K8/46; A61K8/463; A61Q5/00; A61Q5/02; C; C08; C08G; C08G65/00; C08G65/02; C08G65/26; C08G65/2618; C08G65/2621; C08G65/2624; C08G65/32; C08G65/329; C08G65/334; C08G65/3344; C11; C11D; C11D1/00; C11D1/88
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
114 words
A method comprising washing human hair and skin with an aqueous composition containing an effective washing amount of an amphoteric surface active compound of the formula: ##STR4## wherein R is C 8-14 alkyl, R 1 is C 1-2 alkyl or benzyl; y 1 and y 2 are each integers, the sum of which ranges from about 5 to about 50; Z 1 is, with the bonded O atom, a sulfate ester group in free acid form or in the form of its sodium, potassium, magnesium or calcium salt, Z 2 is H or Z 1 ; and A is a halide, sulfate or C 1-2 alkyl sulfate anion; or a mixture of such compounds.
Claim 2
Independent Claim
114 words
A method comprising washing human hair and skin with an aqueous composition containing an effective washing amount of an amphoteric surface active compound of the formula: ##STR4## wherein R is C 8-14 alkyl, R 1 is C 1-2 alkyl or benzyl; y 1 and y 2 are each integers, the sum of which ranges from about 5 to about 50; Z 1 is, with the bonded O atom, a sulfate ester group in free acid form or in the form of its sodium, potassium, magnesium or calcium salt, Z 2 is H or Z 1 ; and A is a halide, sulfate or C 1-2 alkyl sulfate anion; or a mixture of such compounds.
Claim 3
Dependent Claim
19 words
A method as defined in claim 1 in which Z 1 is in the form of the Na salt.
Claim 4
Dependent Claim
17 words
A method as defined in claim 1 wherein R 1 is ethyl and A is ethyl sulfate.
Claim 5
Dependent Claim
18 words
A method as defined in claim 1 wherein R 1 is benzyl and A is a chlorine anion.
Claim 6
Dependent Claim
22 words
A method as defined in claim 1 wherein the sum of y 1 and y 2 is about 10 to about 20.
Claim 7
Dependent Claim
32 words
A method as defined in claim 5 wherein R is derived from cocoamine, R 1 is ethyl, Z 1 is in the form of the Na salt, and A is ethyl sulfate.
Claim 8
Dependent Claim
13 words
A method as defined in claim 1 wherein R is derived from cocoamine.
Claim 9
Dependent Claim
30 words
A method as defined in claim 1 wherein said composition is an aqueous solution of a shampoo formulation containing 20% of said compound and 1.5% of long chain amine oxide.
Claim 10
Dependent Claim
29 words
A method as defined in claim 1 wherein said composition is an aqueous solution of a bubble bath concentrate containing 20% of said compound and 5% of coconut diethanolamide.
Claim 11
Dependent Claim
32 words
A method as defined in claim 1 wherein said composition is derived from a solid bar containing 5-15% of said compound, 60-80% of tallow coconut oil soap and 0-10% of stearic acid.
Claim 12
Dependent Claim
40 words
A method as defined in claim 1 wherein said composition is derived from a solid bar containing 20-50% of said compound, 5-15% of paraffin wax, 0-20% of stearic acid, 0.5-1.0% of alkyl dimethyl benzyl ammonium cloride, and 20-60% of talc.
Claim 13
Dependent Claim
33 words
A method as defined in claim 1 wherein said composition is derived from a solid bar containing 20-50% of said agent, 5-15% of paraffin wax, 0-20% of stearic acid, and 20-60% of talc.
Claim 14
Dependent Claim
91 words
A method as defined in claim 1 wherein said compound is prepared by reacting 1 mole of the reaction product of 1 mole of an organic amine of the formula RNH 2 with about 5 to about 50 moles of ethylene oxide, with 0.5 to 1.0 mole of a quarternizing agent of the formula R 1 A, and then reacting the reslulting quarternized polyethoxylated amine with about 0.1 to 2.0 mole of a sulfating agent selected from the group consisting of chlorosulfonic acid, sulfur trioxide, sulfamic acid and sulfuric acid oleum.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-02-05 | 1982-08-07 | 1983-02-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-02-05 | 1986-08-07 | 1987-02-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-02-05 | 1990-08-07 | 1991-02-06 | $7700.00 | Window Closed / Lapsed |