US4138366A
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Process for producing unsaturated aliphatic acids and catalysts therefore
Assignee: Standard Oil Co
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Filing: 1976-11-17
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Granted: 1979-02-06
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Expires: 1996-11-17
Abstract
Abstract The present invention relates to a process for the production of unsaturated aliphatic acids and the catalyst therefore by the vapor phase oxidation of the corresponding unsaturated aliphatic aldehydes with molecular oxygen, optionally in the presence of steam, in the presence of an oxidation catalyst consisting of the oxides of the elements molybdenum, antimony and vanadium in combination with at least one of the oxides of the element selected from the group consisting of silver, magnesium, thallium and cadmium, and optionally one or more of the oxides of the elements of the group, manganese, cobalt, nickel, copper, iron, tin, chromium, titanium, bismuth, arsenic, phosphorus, rhenium, and zinc.
Inventors
- 👤 Wilfrid G. Shaw
- 👤 David B. Terrill
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 06:30
CPC Classifications
B; B01; B01J; B01J23/00; B01J23/70; B01J23/76; B01J23/84; B01J23/85; B01J23/88; B01J23/887; B01J23/8878; B01J23/002; B01J23/16; B01J23/24; B01J23/28; B01J23/30; B01J23/32; B01J23/34; B01J23/36; B01J23/38; B01J23/54; B01J23/66; B01J23/68; B01J23/8873; B01J23/8874; B01J23/8876; B01J23/89; B01J23/8933; B01J23/8993; B01J27/00; B01J27/14; B01J27/186; B01J27/195; B01J27/198; B01J27/199; C; C07; C07C; C07C51/00; C07C51/16; C07C51/21; C07C51/25; C07C51/252; B01J2523/00
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
134 words
A catalyst having the empirical formula: Mo.sub.a Sb.sub.b V.sub.c Y.sub.d Z.sub.e O.sub.f wherein Y can be one or more of the elements selected from the group consisting of silver, magnesium, thallium and cadmium; and Z can be one or more of the elements of the group consisting of manganese, cobalt, nickel, copper, iron, tin, chromium, titanium, bismuth, arsenic, phosphorus, rhenium, and zinc; and wherein the number of atoms of each element present is represented by a through f, wherein a is a number from 6 to 18 b is a number from 0.1 to 6; c is a number from 0.1 to 6; d is a number from 0.01 to 6; e is a number from 0 to 6; and f is a number that satisfies the valence requirements of the other elements present.
Claim 2
Dependent Claim
134 words
A catalyst having the empirical formula: Mo.sub.a Sb.sub.b V.sub.c Y.sub.d Z.sub.e O.sub.f wherein Y can be one or more of the elements selected from the group consisting of silver, magnesium, thallium and cadmium; and Z can be one or more of the elements of the group consisting of manganese, cobalt, nickel, copper, iron, tin, chromium, titanium, bismuth, arsenic, phosphorus, rhenium, and zinc; and wherein the number of atoms of each element present is represented by a through f, wherein a is a number from 6 to 18 b is a number from 0.1 to 6; c is a number from 0.1 to 6; d is a number from 0.01 to 6; e is a number from 0 to 6; and f is a number that satisfies the valence requirements of the other elements present.
Claim 3
Dependent Claim
10 words
The catalyst composition of claim 1 wherein e is zero.
Claim 4
Dependent Claim
46 words
The catalyst of claim 1 wherein a = 9 to 15; b = 0.7 to 3; c = 0.5 to 5; d = 0.05 to 1; e = 0.0 to 1; and f is a number that satisfies the valence requirements of the other elements present.
Claim 5
Dependent Claim
9 words
The catalyst in claim 1 wherein Y is silver.
Claim 6
Dependent Claim
9 words
The catalyst in claim 1 wherein Y is magnesium.
Claim 7
Dependent Claim
9 words
The catalyst in claim 1 wherein Y is thallium.
Claim 8
Dependent Claim
9 words
The catalyst in claim 1 wherein Y is cadmium.
Claim 9
Dependent Claim
18 words
The catalyst in claim 1 wherein Y is selected from the group consisting of magnesium, thallium and cadmium.
Claim 10
Dependent Claim
9 words
The catalyst in claim 8 wherein e is zero.
Claim 11
Dependent Claim
46 words
The catalyst in claim 8 wherein a = 9 to 15; b = 0.7 to 3; c = 0.5 to 5; d = 0.05 to 1; e = 0.0 to 1; and f is a number that satisfies the valence requirements of the other elements present.
Claim 12
Dependent Claim
132 words
A catalyst having the empirical formula: Mo.sub.a Sb.sub.b V.sub.c Y.sub.d Z.sub.e O.sub.f wherein Y can be one or more of the elements selected from the group consisting of silver, magnesium, thallium and cadmium; and Z can be one or more of the elements of the group consisting of manganese, cobalt, nickel, copper, iron, tin, chromium, titanium, bismuth, rhenium, and zinc; and wherein the number of atoms of each element present is represented by a through f, wherein a is a number from 6 to 18; b is a number from 0.1 to 6; c is a number from 0.1 to 6; d is a number from 0.01 to 6; e is a number from 0 to 6; and f is a number that satisfies the valence requirements of the other elements present.
Claim 13
Dependent Claim
132 words
A catalyst having the empirical formula: Mo.sub.a Sb.sub.b V.sub.c Y.sub.d Z.sub.e O.sub.f wherein Y can be one or more of the elements selected from the group consisting of silver, magnesium, thallium and cadmium; and Z can be one or more of the elements of the group consisting of manganese, cobalt, nickel, copper, iron, tin, chromium, titanium, bismuth, rhenium, and zinc; and wherein the number of atoms of each element present is represented by a through f, wherein a is a number from 6 to 18; b is a number from 0.1 to 6; c is a number from 0.1 to 6; d is a number from 0.01 to 6; e is a number from 0 to 6; and f is a number that satisfies the valence requirements of the other elements present.
Claim 14
Dependent Claim
9 words
The catalyst in claim 11 wherein Y is silver.
Claim 15
Dependent Claim
9 words
The catalyst in claim 11 wherein Y is magnesium.
Claim 16
Dependent Claim
9 words
The catalyst in claim 11 wherein Y is thallium.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-02-05 | 1982-08-07 | 1983-02-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-02-05 | 1986-08-07 | 1987-02-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-02-05 | 1990-08-07 | 1991-02-06 | $7700.00 | Window Closed / Lapsed |