Patent US4137294A successfully refreshed from Google Patents.
US4137294A
Expired / Lapsed
US
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Process of scrubbing fuel synthesis gases to remove acid gases and organic sulfur compounds
Assignee: GEA Group AG
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Filing: 1976-04-08
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Granted: 1979-01-30
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Expires: 1996-04-08
Abstract
Abstract In scrubbing fuel gases or synthesis gas, absorption is improved by using simple oxygen containing water soluble organic compounds such as the lower alcohols, butanols, or water soluble lower ethers.
Inventors
- 👤 Karl Braizler
- 👤 Alexander Doerges
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 17:37
CPC Classifications
C; C10; C10K; C10K1/00; C10K1/08; C10K1/10; C10K1/12; C10K1/14; C10K1/143; B; B01; B01D; B01D53/00; B01D53/14; B01D53/1493
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
149 words
In a process for scrubbing fuel and synthesis gases to remove hydrogen sulfide, carbon dioxide and organic sulfur compounds therefrom wherein the gas to be treated to produce substantially pure gas is passed through an absorption zone at a superatmospheric pressure and at a temperature of above 0° C. up to 100° C. and then through a scrubbing zone to recover entrained absorbent, the absorption zone being supplied with a circulating absorbent comprising a primary aliphatic alcohol, one or more alkanolamines and eventually water, whereafter the absorbent is regenerated by flashing and heating, the improvement which comprises washing the gases in the absorption zone using an absorbent consisting essentially of methanol and 0.2 to 4 moles of an alkanolamine per liter of absorbent, flashing the rich absorbent and heating it to a boiling temperature not higher than 100° C., cooling the absorbent and recirculating it to the absorption zone.
Claim 2
Dependent Claim
149 words
In a process for scrubbing fuel and synthesis gases to remove hydrogen sulfide, carbon dioxide and organic sulfur compounds therefrom wherein the gas to be treated to produce substantially pure gas is passed through an absorption zone at a superatmospheric pressure and at a temperature of above 0° C. up to 100° C. and then through a scrubbing zone to recover entrained absorbent, the absorption zone being supplied with a circulating absorbent comprising a primary aliphatic alcohol, one or more alkanolamines and eventually water, whereafter the absorbent is regenerated by flashing and heating, the improvement which comprises washing the gases in the absorption zone using an absorbent consisting essentially of methanol and 0.2 to 4 moles of an alkanolamine per liter of absorbent, flashing the rich absorbent and heating it to a boiling temperature not higher than 100° C., cooling the absorbent and recirculating it to the absorption zone.
Claim 3
Dependent Claim
19 words
Process of claim 1, wherein the alkanolamine is selected from the group consisting of monoethanolamine, diethanolamine and mixtures thereof.
Claim 4
Dependent Claim
39 words
Process of claim 1, wherein 0.01 to 0.2 moles per liter of an acid having a p K value of 7-11 and selected from the group consisting of phenol, boric acid and arsenic trioxide is added to the absorbent.
Claim 5
Dependent Claim
54 words
Process of claim 1, wherein the absorbent entrained by the purified gas is removed in the scrubbing zone by scrubbing the gas with circulating water and/or diethylene glycol and is thereafter recovered from the rich scrubbing agent by distillation, the regenerated scrubbing agent being cooled and recirculated to the top of the scrubbing zone.
Claim 6
Dependent Claim
13 words
Process of claim 1, wherein the absorbent contains 5-20% by weight of water.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-01-29 | 1982-07-31 | 1983-01-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-01-29 | 1986-07-31 | 1987-01-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-01-29 | 1990-07-31 | 1991-01-30 | $7700.00 | Window Closed / Lapsed |