← Back to Patent Explorer
US4137294A Expired / Lapsed US ⏱️ 0.0 years remaining

Process of scrubbing fuel synthesis gases to remove acid gases and organic sulfur compounds

Assignee: GEA Group AG
•
Filing: 1976-04-08
•
Granted: 1979-01-30
•
Expires: 1996-04-08
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract In scrubbing fuel gases or synthesis gas, absorption is improved by using simple oxygen containing water soluble organic compounds such as the lower alcohols, butanols, or water soluble lower ethers.

Inventors

  • 👤 Karl Braizler
  • 👤 Alexander Doerges

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 13:26
CPC Classifications
C; C10; C10K; C10K1/00; C10K1/08; C10K1/10; C10K1/12; C10K1/14; C10K1/143; B; B01; B01D; B01D53/00; B01D53/14; B01D53/1493

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 149 words
In a process for scrubbing fuel and synthesis gases to remove hydrogen sulfide, carbon dioxide and organic sulfur compounds therefrom wherein the gas to be treated to produce substantially pure gas is passed through an absorption zone at a superatmospheric pressure and at a temperature of above 0° C. up to 100° C. and then through a scrubbing zone to recover entrained absorbent, the absorption zone being supplied with a circulating absorbent comprising a primary aliphatic alcohol, one or more alkanolamines and eventually water, whereafter the absorbent is regenerated by flashing and heating, the improvement which comprises washing the gases in the absorption zone using an absorbent consisting essentially of methanol and 0.2 to 4 moles of an alkanolamine per liter of absorbent, flashing the rich absorbent and heating it to a boiling temperature not higher than 100° C., cooling the absorbent and recirculating it to the absorption zone.
Claim 2
Dependent Claim 149 words
In a process for scrubbing fuel and synthesis gases to remove hydrogen sulfide, carbon dioxide and organic sulfur compounds therefrom wherein the gas to be treated to produce substantially pure gas is passed through an absorption zone at a superatmospheric pressure and at a temperature of above 0° C. up to 100° C. and then through a scrubbing zone to recover entrained absorbent, the absorption zone being supplied with a circulating absorbent comprising a primary aliphatic alcohol, one or more alkanolamines and eventually water, whereafter the absorbent is regenerated by flashing and heating, the improvement which comprises washing the gases in the absorption zone using an absorbent consisting essentially of methanol and 0.2 to 4 moles of an alkanolamine per liter of absorbent, flashing the rich absorbent and heating it to a boiling temperature not higher than 100° C., cooling the absorbent and recirculating it to the absorption zone.
Claim 3
Dependent Claim 19 words
Process of claim 1, wherein the alkanolamine is selected from the group consisting of monoethanolamine, diethanolamine and mixtures thereof.
Claim 4
Dependent Claim 39 words
Process of claim 1, wherein 0.01 to 0.2 moles per liter of an acid having a p K value of 7-11 and selected from the group consisting of phenol, boric acid and arsenic trioxide is added to the absorbent.
Claim 5
Dependent Claim 54 words
Process of claim 1, wherein the absorbent entrained by the purified gas is removed in the scrubbing zone by scrubbing the gas with circulating water and/or diethylene glycol and is thereafter recovered from the rich scrubbing agent by distillation, the regenerated scrubbing agent being cooled and recirculated to the top of the scrubbing zone.
Claim 6
Dependent Claim 13 words
Process of claim 1, wherein the absorbent contains 5-20% by weight of water.

References Cited (Backward Citations)

US1964808A Cited
US2031632A Cited
GB461001A Cited
US2163169A Cited
US2524088A Cited
US2445468A Cited
US2863527A Cited
US3653810A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-01-29 1982-07-31 1983-01-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-01-29 1986-07-31 1987-01-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-01-29 1990-07-31 1991-01-30 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag