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US4137042A Expired / Lapsed US ⏱️ 0.0 years remaining

Dry heat process for dyeing and printing organic material which can be dyed with cationic dyes

Assignee: Ha Whitten & Co
•
Filing: 1975-05-08
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Granted: 1979-01-30
•
Expires: 1995-05-08
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Abstract

Abstract A dry heat process for dyeing and printing and optically brightening organic material which can be dyed with cationic dyes, which process comprises the use of electroneutral, deprotonized cationic dyes or fluorescent brighteners together with at least one indicator dye.

Inventors

  • 👤 Raymond DeFago
  • 👤 Stefan Koller
  • 👤 Peter Moser

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 16:34
CPC Classifications
D; D06; D06P; D06P5/00; D06P5/003; D06P5/004; D06L; D06L4/00; D06L4/60; D06L4/643; D06P1/00; D06P1/41

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 248 words
In a dry heat transfer process for the dyeing, printing or optical brightening of organic material susceptible to dyeing with cationic dyes which comprises (1) bringing the surface of the said organic material to be dyed, printed or optically brightened into contact with the treated surface of an inert carrier, said surface being treated with a printing ink containing at least one finely divided, electroneutral, deprotenized cationic dye or fluorescent brightener of the formula ##STR26## wherein R is an aromatic, heterocyclic or aliphatic radical which contains a deprotonized nitrogen atom (═N--), each of X 1 and X 2 independently is N, CH or CR 2 , in which R 2 is alkyl of 1 to 4 carbon atoms, aryl or aralkyl, Z is a divalent radical which optionally contains further heteroatoms or fused rings and which completes the nitrogen-containing ring to form an unsaturated 5- or 6-membered ring, and R 1 is substituted or unsubstituted alkyl, and the deprotonized nitrogen atom in R is in conjugation to the ##STR27## group, irrespective of the length of the conjugation system which advantageously extends over 3 to 17 members, (2) subjecting the said organic material and inert carrier while in contact to a heat treatment of 120° C. to 210° C., and (3) separating the said organic material from the said inert carrier, the improvement according to which the printing ink employed to treat the surface of the inert carrier additionally contains an indicator dye which does not exhibit acid reaction.
Claim 2
Dependent Claim 248 words
In a dry heat transfer process for the dyeing, printing or optical brightening of organic material susceptible to dyeing with cationic dyes which comprises (1) bringing the surface of the said organic material to be dyed, printed or optically brightened into contact with the treated surface of an inert carrier, said surface being treated with a printing ink containing at least one finely divided, electroneutral, deprotenized cationic dye or fluorescent brightener of the formula ##STR26## wherein R is an aromatic, heterocyclic or aliphatic radical which contains a deprotonized nitrogen atom (═N--), each of X 1 and X 2 independently is N, CH or CR 2 , in which R 2 is alkyl of 1 to 4 carbon atoms, aryl or aralkyl, Z is a divalent radical which optionally contains further heteroatoms or fused rings and which completes the nitrogen-containing ring to form an unsaturated 5- or 6-membered ring, and R 1 is substituted or unsubstituted alkyl, and the deprotonized nitrogen atom in R is in conjugation to the ##STR27## group, irrespective of the length of the conjugation system which advantageously extends over 3 to 17 members, (2) subjecting the said organic material and inert carrier while in contact to a heat treatment of 120° C. to 210° C., and (3) separating the said organic material from the said inert carrier, the improvement according to which the printing ink employed to treat the surface of the inert carrier additionally contains an indicator dye which does not exhibit acid reaction.
Claim 3
Dependent Claim 25 words
A process according to claim 1 wherein in the formula the group ##STR28## is a pyrazole, thiazole, triazole, benzthiazole, indazole, tetrahydroindole, pyridine or quinoline radical.
Claim 4
Dependent Claim 27 words
A process according to claim 1 wherein the indicator dye is present in an amount of 0.1 to 10 percent by weight based on the deprotonized dyes.
Claim 5
Dependent Claim 23 words
A process according to claim 3 wherein the indicator dye is present in an amount of from 0.5 to 1.5 percent by weight.
Claim 6
Dependent Claim 27 words
A process according to claim 1 wherein the indicator dye is present in the salt form of the protonized dyes corresponding to the deprotonized cationic dyes employed.
Claim 7
Dependent Claim 26 words
A process according to claim 1 wherein the indicator dyes present correspond to the shades which are obtained on the organic material after the transfer printing.
Claim 8
Dependent Claim 23 words
A process according to claim 1 wherein the organic material is polyacrylonitrile or modacryl fiber material which can be dyed with cationic dyes.
Claim 9
Dependent Claim 32 words
A process according to claim 1 which comprises subjecting carrier and organic material to be dyed to a heat treatment of 120° to 210° C. for 5 to 40 seconds under vacuum.
Claim 10
Dependent Claim 47 words
A dyeing preparation for use in the dry heat transfer process according to claim 1 which contains dissolved or dispersed in water, a solvent or mixtures thereof at least one electroneutral, deprotonized cationic dye, or fluorescent brightener and an indicator dye which does not exhibit acid reaction.
Claim 11
Dependent Claim 58 words
A carrier for use in the dry heat transfer process according to claim 1 which comprises an inert substrate treated with aqueous, organic-aqueous or organic printing inks which contain at least one electroneutral, deprotonized cationic dye or fluorescent brightener, an indicator dye which does not exhibit acid reaction and optionally a binder which is stable below 230° C.
Claim 12
Dependent Claim 17 words
A carrier according to claim 10 wherein the inert substrate is paper, aluminum foil or steel foil.
Claim 13
Dependent Claim 21 words
A carrier according to claim 10 wherein the printing inks contain a cellulose ether or ester and/or polyvinyl alcohol as binder.

References Cited (Backward Citations)

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NL6917952A Cited
GB1342304A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-01-29 1982-07-31 1983-01-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-01-29 1986-07-31 1987-01-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-01-29 1990-07-31 1991-01-30 $7700.00 Window Closed / Lapsed

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