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Process and bath composition for increasing the rate of polymer deposition in electrocoating

Assignee: 555794 ONTARIO Inc
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Filing: 1975-11-12
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Granted: 1979-01-23
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Expires: 1995-11-12
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Abstract

Abstract There is provided an electrocoating bath composition for depositing a coat of polymer material onto an anode. This bath composition comprises an essentially aqueous solution, emulsion or dispersion of the polymer and 0.01 by 2.0% by weight with reference to the bath composition of a compound of one of the general formulae: X -- R -- X' or R' -- X -- R -- X' wherein R and R' are each an organic radical, X is one of the following groups: -SH, -OH (phenolic or enolic), ═NH, -- NH.H, and X' is a hydrogen atom or X, the groups X being in such electronic configuration with reference to the organic radical R or the organic radicals R and R' that there is always a presence of labile protons therein under operative conditions of the electrocoating bath, or of a salt of said compound, and the compound or its salt being in an at least partially disassociated state in the electrocoating bath composition and capable of proton association in close vicinity of the anode under conditions of operation. When the electrocoating process is carried out in such bath, be it batchwise or continuously, an increased rate of polymer deposition onto the anode is achieved.

Inventors

  • 👤 Michael A. Dudley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 23:39
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/44; C09D5/4484; Y; Y10; Y10S; Y10S524/00; Y10S524/901

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 156 words
An electrocoating bath composition for depositing a coat of electrodepositable polymer material onto an anode, said bath composition comprising an essentially aqueous solution, emulsion or dispersion of said polymer suitable for electrodeposition on the anode when an electric current is passed therethrough, and comprising 0.01 to 2.0% by weight with reference to the bath composition of a compound of the general formula: X -- R -- X' wherein R is an organic radical, X is -SH, and X' is a hydrogen atom or X, said groups X being in such electronic configuration with reference to the organic radical R that there is always a presence of labile protons therein under operative conditions of the electrocoating bath, or of a salt of said compound, said compound or its salt being in an at least partially disassociated state in said electrocoating bath composition and capable or proton association in close vicinity of the anode under conditions of operation.
Claim 2
Dependent Claim 156 words
An electrocoating bath composition for depositing a coat of electrodepositable polymer material onto an anode, said bath composition comprising an essentially aqueous solution, emulsion or dispersion of said polymer suitable for electrodeposition on the anode when an electric current is passed therethrough, and comprising 0.01 to 2.0% by weight with reference to the bath composition of a compound of the general formula: X -- R -- X' wherein R is an organic radical, X is -SH, and X' is a hydrogen atom or X, said groups X being in such electronic configuration with reference to the organic radical R that there is always a presence of labile protons therein under operative conditions of the electrocoating bath, or of a salt of said compound, said compound or its salt being in an at least partially disassociated state in said electrocoating bath composition and capable or proton association in close vicinity of the anode under conditions of operation.
Claim 3
Dependent Claim 27 words
Electrocoating bath composition according to claim 1, wherein said compound is used in a proportion of 0.3 to 0.5% by weight with reference to said bath composition.
Claim 4
Dependent Claim 17 words
Electrocoating bath composition according to claim 1, wherein said polymer is an electrodepositable synthetic polycarboxylic acid resin.
Claim 5
Dependent Claim 16 words
Electrocoating bath composition according to claim 1, wherein said polymer is an electrodepositable epoxy ester resin.
Claim 6
Dependent Claim 15 words
Electrocoating bath composition according to claim 1, wherein said polymer is an electrodepositable alkyd resin.
Claim 7
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is 2-mercaptobenzimidazole.
Claim 8
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is 2-mercaptobenzoxazole.
Claim 9
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is 2,5-dimercapto-1,3,4-thiadiazole.
Claim 10
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is 3-mercapto-1,2-propanediol.
Claim 11
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is 2-mercapto-benzoselenazole.
Claim 12
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is ethyl-2-mercapto-acetate.
Claim 13
Dependent Claim 15 words
Electrocoating bath composition according to claim 1, wherein said compound is N-phenyl thioglycolic acid amide.
Claim 14
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is 3-amino-5-mercapto-1,2,4-triazole.
Claim 15
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is benzenethiol.
Claim 16
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is 5-amino-1,3,4-thiadiazole-2-thiol.
Claim 17
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is 2,6-dimercapto-purine.
Claim 18
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is 2-mercaptopyrimidene.
Claim 19
Dependent Claim 14 words
Electrocoating bath composition according to claim 1, wherein said compound is ethyleneglycol bis mercaptoacetate.
Claim 20
Dependent Claim 13 words
Electrocoating bath composition according to claim 1, wherein said compound is 1H 1,2,4-triazole-3-thiol.
Claim 21
Dependent Claim 12 words
Electrocoating bath composition according to claim 1, wherein said compound is 5-mercapto-3-phenyl-1,3,4-thiadiazole-2-thione.
Claim 22
Dependent Claim 23 words
Electrocoating bath composition according to claim 1, wherein said salt of the compound is dipotassium salt of 2,5-dimercapto-1,3,4-thiadiazole or sodium salt of 2-mercaptobenzoxazole.

References Cited (Backward Citations)

US3300431A Cited
US3296177A Cited
US3657092A Cited
US3736276A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-01-22 1982-07-24 1983-01-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-01-22 1986-07-24 1987-01-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-01-22 1990-07-24 1991-01-23 $7700.00 Window Closed / Lapsed

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