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US4134879A Expired / Lapsed US ⏱️ 0.0 years remaining

Thioether-containing phenolic antioxidant stabilized polymers

Assignee: BASF Corp
•
Filing: 1976-11-05
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Granted: 1979-01-16
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Expires: 1996-11-05
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Abstract

Abstract Compounds of the general formula I ##STR1## in which R 1 and R 5 independently of one another denote hydrogen or lower alkyl, one of R 2 and R 3 denotes hydroxyl and the other denotes alkyl, cycloalkyl or aralkyl, R 4 denotes hydrogen or, if R 3 denotes hydroxyl, additionally also denotes alkyl, cycloalkyl or aralkyl, X denotes a group ##STR2## wherein R 8 is alkyl, aralkyl or phenyl and R 9 is alkyl, aralkyl, phenyl or the group ##STR3## or R 9 and R 8 together are alkylene, Y 1 and Y 2 independently of one another denote oxygen or sulphur, p denotes 1 or 2, q denotes 0 or 1, with the proviso that p + q = 2, and R 6 , if q is 0, denotes alkyl, cycloalkyl, aralkyl or thiaalkyl, in which case Y 1 is linked to a carbon atom in the thiaalkyl radical which does not carry a further hetero-atom, or denotes oxaalkyl, in which case Y 1 is linked to a carbon atom in the oxaalkyl radical which does not carry a further hetero-atom, hydroxycarbonylalkyl, alkoxycarbonylalkyl, cycloalkoxycarbonylalkyl, aralkoxycarbonylalkyl, aryloxycarbonylalkyl or a group ##STR4## wherein m is 2 - 10 and R 10 is alkyl, alkenyl, cycloalkyl, aralkyl, thiaalkyl, oxaalkyl or aryl, or R 6 , if q is 0, and Y 1 and Y 2 both denote sulphur, can also denote aryl, or R 6 , if q is 1, denotes, together with R 7 , 1,2-alkylene, 1,3-alkylene, o-arylene or 1,8-naphthylene, are used to stabilize organic material.

Inventors

  • 👤 Andreas Schmidt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:14
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/0008; C08K5/005; C07; C07C; C07C323/00; C07D; C07D317/00; C07D317/08; C07D317/10; C07D317/14; C07D317/18; C07D317/20; C07D339/00; C07D339/02; C07D339/06

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 113 words
A composition of matter comprising a poly mono-olefin and 0.005 to 5% by weight of a compound of the formula ##STR25## in which R 1 and R 5 independently of one another are hydrogen or lower alkyl, one of R 2 and R 3 is hydroxyl and the other is alkyl, cycloalkyl or aralkyl, R 4 is hydrogen or, if R 3 is hydroxyl, also is alkyl, cycloalkyl or aralkyl, x is a group. ##STR26## wherein R 8 is alkyl, aralkyl or phenyl and R 9 is alkyl, aralkyl, phenyl of the group ##STR27## or R 8 and R 9 together are alkylene and R 6 is hydroxycarbonylalkyl, alkoxycarbonylalkyl, cycloalkoxycarbonylalkyl, aralkoxycarbonylalkyl or aryloxycarbonylalkyl.
Claim 2
Dependent Claim 113 words
A composition of matter comprising a poly mono-olefin and 0.005 to 5% by weight of a compound of the formula ##STR25## in which R 1 and R 5 independently of one another are hydrogen or lower alkyl, one of R 2 and R 3 is hydroxyl and the other is alkyl, cycloalkyl or aralkyl, R 4 is hydrogen or, if R 3 is hydroxyl, also is alkyl, cycloalkyl or aralkyl, x is a group. ##STR26## wherein R 8 is alkyl, aralkyl or phenyl and R 9 is alkyl, aralkyl, phenyl of the group ##STR27## or R 8 and R 9 together are alkylene and R 6 is hydroxycarbonylalkyl, alkoxycarbonylalkyl, cycloalkoxycarbonylalkyl, aralkoxycarbonylalkyl or aryloxycarbonylalkyl.
Claim 3
Dependent Claim 12 words
The composition of claim 1 wherein the compound has the formula ##STR28##
Claim 4
Dependent Claim 12 words
The composition of claim 1 wherein the compound has the formula ##STR29##
Claim 5
Dependent Claim 12 words
The composition of claim 1 wherein the compound has the formula ##STR30##
Claim 6
Dependent Claim 12 words
The composition of claim 1 wherein the compound has the formula ##STR31##
Claim 7
Dependent Claim 10 words
A composition of claim 1 wherein the polymer is polypropylene.
Claim 8
Dependent Claim 16 words
A composition of matter comprising polypropylene and 0.01 to 1.0% of a compound of claim 5.
Claim 9
Dependent Claim 220 words
The composition of claim 1, in which R 1 and R 5 independently of one another are hydrogen or methyl, one of R 2 and R 3 denotes hydroxyl and the other denotes alkyl having 1 to 8 carbon atoms, cycloalkyl having 6 to 8 carbon atoms or aralkyl having 7 to 9 carbon atoms, R 4 denotes hydrogen or, if R 3 denotes hydroxyl, additionally also denotes alkyl having 1 to 8 carbon atoms, cycloalkyl having 6 to 8 carbon atoms or aralkyl having 7 to 9 carbon atoms, x denotes a group ##STR32## wherein R 8 is alkyl having 1 to 8 carbon atoms, aralkyl having 7 to 9 carboxyl atoms or phenyl, and R 9 denotes alkyl having 1 to 8 carbon atoms, aralkyl having 7 to 9 carbon atoms, phenyl or the group ##STR33## or conjointly with R 8 , is alkylene having 2 to 11 carbon atoms and R 6 is hydroxycarbonylalkyl having 2 to 20 carbon atoms, alkoxycarbonylalkyl having 3 to 20 carbon atoms, cycloalkoxycarbonylalkyl having 7 to 10 carbon atoms, aralkoxycarbonylalkyl having 9 to 13 carbon atoms, phenoxycarbonylalkyl having 8 to 12 carbon atoms, alkylphenoxycarbonylalkyl having 9 to 16 carbon atoms, dialkylphenoxycarbonylalkyl having 10 to 16 carbon atoms, chlorophenoxycarbonylalkyl having 8 to 12 carbon atoms, or dichlorophenoxycarbonylalkyl having 8 to 12 carbon atoms.
Claim 10
Dependent Claim 111 words
The composition of claim 1, in which R 1 and R 5 independently of one another denote hydrogen or methyl, one of R 2 and R 3 denotes hydroxyl and the other denotes alkyl having 1 to 4 carbon atoms, R 4 denotes hydrogen or, if R 3 denotes hydroxyl, additionally also denotes alkyl having 1 to 4 carbon atoms, R 8 denotes alkyl having 1 to 4 carbon atoms or phenyl, R 9 denotes alkyl having 1 to 4 carbon atoms, phenyl or the group ##STR34## or together with R 8 denotes alkylene having 4 to 5 carbon atoms and R 6 denotes alkocycarbonylalkyl having 3 to 20 carbon atoms.
Claim 11
Dependent Claim 77 words
The composition of claim 1, in which R 1 and R 5 are hydrogen, R 3 is hydroxyl, R 2 denotes alkyl having from 1 to 4 carbon atoms, R 4 denotes alkyl having 3 to 4 carbon atoms, R 8 denotes alkyl having 1 to 4 carbon atoms, R 9 denotes alkyl having 1 to 4 carbon atoms or together with R 8 denotes pentamethylene and R 6 denotes alkoxycarbonylalkyl having 3 to 20 carbon atoms.

References Cited (Backward Citations)

US3721704A Cited
US3699152A Cited
US3847994A Cited
US3948946A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-01-15 1982-07-17 1983-01-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-01-15 1986-07-17 1987-01-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-01-15 1990-07-17 1991-01-16 $7700.00 Window Closed / Lapsed

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