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US4132436A
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Recording material
Assignee: Fujifilm Holdings Corp
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Filing: 1977-02-01
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Granted: 1979-01-02
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Expires: 1997-02-01
Abstract
Abstract A recording material comprising (1) at least one thiazine compound capable of forming a color when contacted with an electron accepting material and represented by the following general formula (I): ##STR1## wherein A 1 and A 2 , which may be the same or different, each represents an aryl group or a hetero ring residue or, when taken together, A 1 and A 2 represent a hetero ring or a fluorene ring; ring B represents an aromatic hydrocarbon ring or a hetero ring; and Y represents a hydrogen atom, an alkyl group, an aralkyl group, an alkenyl group, an alkynyl group, an aryl group, a hetero ring residue, an amino group, an amido group, a hydroxy group or a thio group; provided that at least one of A 1 and A 2 or, when A 1 and A 2 are taken together, the ring formed by A 1 and A 2 , is an electron donating aryl group, an electron donating hetero ring residue or an electron donating fluorene ring residue; and (2) an electron accepting material.
Inventors
- 👤 Sadao Ishige
- 👤 Hideo Usui
- 👤 Keiso Saeki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 12:51
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/20; B41M5/124; B41M5/132; B41M5/136; B41M5/26; B41M5/30; B41M5/323; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10S428/914
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
171 words
A recording material comprising (1) at least one thiazine compound capable of forming a color when contacted with an electron accepting material and represented by the following general formula (I): ##STR14## wherein A 1 and A 2 may be the same or different and represent an aryl group or a 5 or 6-membered hetero ring residue containing a hetero atom selected from the group consisting of oxygen, sulfur and nitrogen atoms and at least one of A 1 and A 2 representing an electron donating heterocyclic ring or an electron donating fluorene ring or an aryl group substituted with an amino group; or A 1 and A 2 combine to form an electron donating hetero ring; ring B represents an aromatic hydrocarbon ring or a hetero ring; and Y represents a hydrogen atom, an alkyl group, an arylalkyl group, an alkyenyl group, an alkynyl group, an aryl group, a hetero ring residue, an amino group, an amido group, a hydroxy group or a thio group; and (2) an electron accepting material.
Claim 2
Dependent Claim
171 words
A recording material comprising (1) at least one thiazine compound capable of forming a color when contacted with an electron accepting material and represented by the following general formula (I): ##STR14## wherein A 1 and A 2 may be the same or different and represent an aryl group or a 5 or 6-membered hetero ring residue containing a hetero atom selected from the group consisting of oxygen, sulfur and nitrogen atoms and at least one of A 1 and A 2 representing an electron donating heterocyclic ring or an electron donating fluorene ring or an aryl group substituted with an amino group; or A 1 and A 2 combine to form an electron donating hetero ring; ring B represents an aromatic hydrocarbon ring or a hetero ring; and Y represents a hydrogen atom, an alkyl group, an arylalkyl group, an alkyenyl group, an alkynyl group, an aryl group, a hetero ring residue, an amino group, an amido group, a hydroxy group or a thio group; and (2) an electron accepting material.
Claim 3
Dependent Claim
100 words
The recording material of claim 1, wherein one of A 1 and A 2 represents an electron donating heterocyclic ring or an aryl group substituted with an amino group and the other represents a phenyl group, a naphthyl group, or a biphenylyl group, which may be unsubstituted or substituted with one or more of an alkyl group, a fluoroalkyl group, an aralkyl group, a halogen atom, an alkoxy group, an aralkyloxy group, an aryloxy group, a heteroaryloxy group, an alkenyloxy group, an alkynyloxy group, an acyloxy group, a sulfonyloxy group, an amino group, an amido group, or a thio group.
Claim 4
Dependent Claim
110 words
The recording material of claim 1, wherein said hetero ring formed by A 1 and A 2 when taken together is a 9H-xanthene ring, a 10-alkyl-9,10-dihydroacridine ring, a 9H-thioxanthene ring, a 1-alkyl-4H-chromeno[2,3-C]pyrazole ring, a 11H-benzo[b]thieno[3,2-b]chromene ring, a 6-alkyl-5-oxo-5,6-dihydro-12H-chromeno[2,3-C]isoquinoline ring, a 4H-chromene ring, or a 2H-chromene ring and said hetero ring and said fluorene ring may be unsubstituted or substituted with one or more of an alkyl group, a fluoroalkyl group, an aralkyl group, a halogen atom, an alkoxy group, an aralkyloxy group, an aryloxy group, a heteroaryloxy group, an alkenyloxy group, an alkynyloxy group, an acyloxy group, a sulfonyloxy group, an amino group, an amido group or a thio group.
Claim 5
Dependent Claim
71 words
The recording material of claim 1, wherein said substituent an amino group, an oxy group, or a thio group in a said electron donating hetero ring residue is a hetero ring having an excess of π electrons or is a residue of a hetero ring having an ethylenic carbon-carbon double bond in a position with respect to the hetero ring residue conjugatable with a hetero atom in said hetero ring residue.
Claim 6
Dependent Claim
67 words
The recording material of claim 1, wherein said recording material comprises a support having thereon said thiazine compound represented by the general formula (I) dissolved in a solvent and encapsulated in microcapsules coated as a layer on said support and said electron accepting material is coated on the same surface of said support or on the opposite surface of said support or is coated on another support.
Claim 7
Dependent Claim
65 words
The recording material of claim 1, wherein said recording material comprises a support having thereon said thiazine compound represented by the general formula (I) and a thermofusible material dispersed in a binder and coated on said support and said electron accepting material is coated on the same surface of said support or on the opposite surface of said support or is coated on another support.
Claim 8
Dependent Claim
28 words
The recording material of claim 6, wherein said binder containing said thiazine compound represented by the general formula (I) and said thermofusible material also contains an electroconductive material.
Claim 9
Dependent Claim
21 words
The recording material of claim 1 wherein A 1 and A 2 represent an aryl group substituted with an amino group.
Claim 10
Dependent Claim
100 words
The recording material of claim 8 wherein said amino group substituting said aryl group is selected from the group consisting of an anilino group, an ethylamino group, a benzylamino group, an allylamino group, a propargylamino group, a cyclohexylamino group, an acetonylamino group, an ethoxycarbonylmethylamino group, a β-methoxyethylamino group, a dimethylamino group, a diethylamino group, a dibenzylamino group, a bis(ethoxymethyl)amino group, a bis(β-chloroethyl)amino group, a bis(β-cyanoethyl)amino group, an N-benzyl-N-ethylamino group, an N-ethyl-N-(p-tolyl)amino group, an N-benzyl-N-(β-ethoxyethyl)amino group, an N-methyl-N-phenacylamino group, a morpholino group, a piperidino group, a pyrrolidino group, an α-pyridylamino group, a β-furylamino group, an α-thienylamino group, and a 2-pyrimidinylamino group.
Claim 11
Dependent Claim
18 words
The recording material of claim 8 wherein B forms a benzene ring and Y represents an amino group.
Claim 12
Dependent Claim
21 words
The recording material of claim 1 wherein A 1 and A 2 represent a 5- or 6-electron donating hetero ring residue.
Claim 13
Dependent Claim
47 words
The recording material of claim 11 wherein said heterocyclic ring represented by A 1 and A 2 is selected from the group consisting of p-julolidyl, 1,2,3,4-tetrahydroquinolin-6-yl, 3,3-dimethylindolin-5-yl, 3,4-methylenedioxypehnyl, 1,2-dimethyl-5-benzimidazolyl, 10-ethylphenothiazin-3-yl, 10-ethylphenoxazin-3-yl, 9-ethylcarbazol-3-yl, dibenzofuran3-yl, dibenzothiophen-3-yl, quinolin-8-yl, 1,2-dimethylindol-3-yl, 1-ethylindazol-3-yl, benzo[b]furan-3-yl, benzo[b]thiophen-3-yl, 1-ethylpyrrol-3-yl, 3-furyl, 3-thienyl, 2-thiazolyl, 2-benzoxazolyl, 2-pyridyl, and 4-quinolyl.
Claim 14
Dependent Claim
20 words
The recording material of claim 1 wherein A 1 and A 2 combine to form an electron donating hetero ring.
Claim 15
Dependent Claim
110 words
The recording material of claim 13, wherein said hetero ring formed by A 1 and A 2 when taken together is a 9H-xanthene ring, a 10-alkyl-9,10-dihydroacridine ring, a 9H-thioxanthene ring, a 1-alkyl-4H-chromeno[2,3-C]pyrazole ring, a 11H-benzo[b]thieno[3,2-b]chromene ring, a 6-alkyl-5-oxo-5,6-dihydro-12H-chromeno[2,3-C]isoquinoline ring, a 4H-chromene ring, or a 2H-chromene ring and said hetero ring and said fluorene ring may be unsubstituted or substituted with one or more of an alkyl group, a fluoroalkyl group, an aralkyl group, a halogen atom, an alkoxy group, an aralkyloxy group, an aryloxy group, a heteroaryloxy group, an alkenyloxy group, an alkynyloxy group, an acyloxy group, a sulfonyloxy group, an amino group, an amido group or a thio group.
Claim 16
Dependent Claim
100 words
The recording material of claim 1 wherein said amino group substituting said aryl group is selected from the group consisting of an anilino group, an ethylamino group, a benzylamino group, an allylamino group, a propargylamino group, a cyclohexylamino group, an acetonylamino group, an ethoxycarbonylmethylamino group, a β-methoxyethylamino group, a dimethylamino group, a diethylamino group, a dibenzylamino group, a bis(ethoxymethyl)amino group, a bis(β-chloroethyl)amino group, a bis(β-cyanoethyl)amino group, an N-benzyl-N-ethylamino group, an N-ethyl-N-(p-tolyl)amino group, an N-benzyl-N-(β-ethoxyethyl)amino group, an N-methyl-N-phenacylamino group, a morpholino group, a piperidino group, a pyrrolidino group, an α-pyridylamino group, a β-furylamino group, an α-thienylamino group, and a 2-pyrimidinylamino group.
Claim 17
Dependent Claim
47 words
The recording material of claim 1 wherein said heterocyclic ring represented by A 1 and A 2 is selected from the group consisting of p-julolidyl, 1,2,3,4-tetrahydroquinolin-6-yl, 3,3-dimethylindolin-5-yl, 3,4-methylenedioxyphenyl, 1,2-dimethyl-5-benzimidazolyl, 10-ethylphenothiazin-3-yl, 10-ethylphenoxazin-3-yl, 9-ethylcarbazol-3-yl, dibenzofuran-3-yl, dibenzothiophen-3-yl, quinolin-8-yl, 1,2-dimethylindol-3-yl, 1-ethylindazol-3-yl, benzo[b]furan-3-yl, benzo[b]thiophen3-yl, 1-ethylpyrrol-3-yl, 3-furyl, 3-thienyl, 2-thiazolyl, 2-benzoxazolyl, 2-pyridyl, and 4-quinolyl.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-01-01 | 1982-07-03 | 1983-01-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-01-01 | 1986-07-03 | 1987-01-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-01-01 | 1990-07-03 | 1991-01-02 | $7700.00 | Window Closed / Lapsed |