US4130600A
Expired / Lapsed
US
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Epoxide resin mixtures
Assignee: BASF Corp
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Filing: 1977-06-06
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Granted: 1978-12-19
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Expires: 1997-06-06
Abstract
Abstract The invention relates to storage-stable, thermosetting mixtures which contain polymaleimides, epoxide compounds having at least one allyl group, and optionally, curing agents for epoxide compounds, and/or curing accelerators for epoxide resin mixtures. These mixtures can be converted by curing into high-polymers which have excellent electrical properties (especially at high temperatures) and very good thermal properties.
Inventors
- 👤 Abdul-Cader Zahir
- 👤 Siegfried Wyler
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 17:25
CPC Classifications
C; C08; C08L; C08L77/00; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/12; C08L63/00; C08L79/00; C08L79/04; C08L79/08; C08L79/085; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31518; Y10T428/31522
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
202 words
A storage-stable, thermosetting mixture which comprises: (a) a polyimide containing in the molecule at least two radicals of the general formula ##STR11## wherein d represents a bivalent radical containing a carbon-carbon double bond; (b) 0.05 to 10 moles per equivalent of polyimide of an epoxide compound which contains at least one allyl group selected from the group consisting of (α) glycidyl ethers of the formula ##STR12## (β) glycidyl ethers of novolaks (x) which contain two or more epoxide groups per molecule and are substituted on an aromatic nuclei with at least one allyl group, (γ) polyepoxy adducts (Y), having two or more epoxy groups per molecule, produced by an advancement reaction of one or more diepoxide compounds with one or more bisphenols, where at least one reactant is substituted on an aromatic nuclei with at least one allyl group, (δ) epoxide compounds (Z) produced by the reaction of bisphenols, which are substituted on an aromatic nuclei with at least one allyl group, with epichlorohydrin in alkaline solution; (c) up to 2 moles of a curing agent for epoxide compounds per equivalent of polyimide; and, (d) up to 3 percent by weight, relative to the polyimide, of a curing accelerator for epoxide resins.
Claim 2
Dependent Claim
202 words
A storage-stable, thermosetting mixture which comprises: (a) a polyimide containing in the molecule at least two radicals of the general formula ##STR11## wherein d represents a bivalent radical containing a carbon-carbon double bond; (b) 0.05 to 10 moles per equivalent of polyimide of an epoxide compound which contains at least one allyl group selected from the group consisting of (α) glycidyl ethers of the formula ##STR12## (β) glycidyl ethers of novolaks (x) which contain two or more epoxide groups per molecule and are substituted on an aromatic nuclei with at least one allyl group, (γ) polyepoxy adducts (Y), having two or more epoxy groups per molecule, produced by an advancement reaction of one or more diepoxide compounds with one or more bisphenols, where at least one reactant is substituted on an aromatic nuclei with at least one allyl group, (δ) epoxide compounds (Z) produced by the reaction of bisphenols, which are substituted on an aromatic nuclei with at least one allyl group, with epichlorohydrin in alkaline solution; (c) up to 2 moles of a curing agent for epoxide compounds per equivalent of polyimide; and, (d) up to 3 percent by weight, relative to the polyimide, of a curing accelerator for epoxide resins.
Claim 3
Dependent Claim
63 words
A mixture according to claim 1, which contain as polyepoxy adducts (Y) such products which have been produced by an advancement reaction of a diglycidyl ether of the formula ##STR13## wherein R 2 represents one of the radicals --CH 2 -- and ##STR14## and R 3 represents the allyl group or H, with one or more of the bisphenols of the formulae ##STR15##
Claim 4
Dependent Claim
32 words
A mixture according to claim 1, which contain polyimides having radicals of the formula (I) in which D represents a bivalent radical of the formula ##STR16## wherein R represents hydrogen or methyl.
Claim 5
Dependent Claim
23 words
A mixture according to claim 1, which contain polyimides having the radical of the formula (I) two or three times in the molecule.
Claim 6
Dependent Claim
30 words
A mixture according to claim 2, which contain as polyimide a compound of the general formula ##STR17## wherein L represents a bivalent organic radical having 2 to 30 C atoms.
Claim 7
Dependent Claim
51 words
A mixture according to claim 5, which contain as polyimide a compound of the formula (VII) in which L represents a radical of the formula ##STR18## wherein R 1 represents one of the radicals --CH 2 --, ##STR19## --SO 2 --, --SO--, --S-- and --O--, and n represents 0 or 1.
Claim 8
Dependent Claim
11 words
A mixture according to claim 5, which contain as polyimide 4,4'-bis-maleimidodiphenylmethane.
Claim 9
Dependent Claim
19 words
A mixture according to claim 1, which additionally contain monoimides, preferably monomaleimides, containing the radical of the formula I.
Claim 10
Dependent Claim
26 words
A mixture according to claim 1, which contain as curing agents for epoxide compounds anhydrides of organic acids, or aliphatic or aromatic or mixed aromatic-aliphatic amines.
Claim 11
Dependent Claim
25 words
A mixture according to claim 9, which contain as curing agents for epoxide compounds a compound from the group: phthalic acid anhydride, 4,4'-diaminodiphenylmethane and dicyandiamide.
Claim 12
Dependent Claim
27 words
A mixture according to claim 1, which contain as curing accelerator for epoxide resin mixtures benzyldimethylamine or imidazole, or catalysts forming radicals, preferably organic peroxides or azo-bis-isobutyronitrile.
Claim 13
Dependent Claim
21 words
A mixture according to claim 1 which contain, besides epoxide compounds containing allyl groups, additionally epoxide compounds containing no allyl groups.
Claim 14
Dependent Claim
46 words
Process for producing cross-linked polymers containing imide groups, which process comprises bringing to reaction and a curing mixture according to claim 1 at temperatures of 25° to 250° C., preferably 100° to 250° C., whereby an initial part of the reaction can be performed in solution.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-12-18 | 1982-06-19 | 1982-12-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-12-18 | 1986-06-19 | 1986-12-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-12-18 | 1990-06-19 | 1990-12-19 | $7700.00 | Window Closed / Lapsed |