Polyphenylene ether compositions containing rubber modified polystyrene

Claim 2

A high impact thermoplastic composition comprising from 1 to 99% by weight of a polyphenylene ether having the repeating structural formula: ##STR3## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next adjoining unit, n is a positive integer and is at least 50, and each Q is a monovalent substituent selected from the group consisting of hydrogen, halogen, hydrocarbon radicals free of a tertiary alpha-carbon atom, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, from 99 to 1% of a polystyrene resin, on a rubber-free basis, and from 0.1 to 30% by weight of the total weight of the composition of a rubber, said composition having a dispersed particulate rubber phase in which the particles have a maximum mean diameter of about 2 microns.

Claim 3

A composition as defined in claim 1 wherein said particles have a mean diameter of from about 0.5 to about 2 microns.

Claim 4

A high impact strength thermoplastic composition comprising from 1 to 99% by weight of a polyphenylene ether having the repeating structural formula: ##STR4## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next adjoining unit, n is a positive integer and is at least 50, and each Q is a monovalent substituent selected from the group consisting of hydrogen, halogen, hydrocarbon radicals free of a tertiary alpha-carbon atom, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus and (a) a polystyrene resin and a rubber; (b) a rubber modified polystyrene resin; or (c) a mixture of (a) and (b), said polystyrene resin comprising from 99 to 1%, on a rubber-free basis, the composition having a dispersed particulate elastomeric phase in which the particles have a maximum mean diameter of about 2 microns and wherein the elastomeric phase comprises from 0.1 to 30% of the total weight of said composition.

Claim 5

A high impact strength thermoplastic composition comprising from 1 to 99% by weight of a polyphenylene ether having the repeating structural formula: ##STR4## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next adjoining unit, n is a positive integer and is at least 50, and each Q is a monovalent substituent selected from the group consisting of hydrogen, halogen, hydrocarbon radicals free of a tertiary alpha-carbon atom, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals and halohydrocarbonoxy radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus and (a) a polystyrene resin and a rubber; (b) a rubber modified polystyrene resin; or (c) a mixture of (a) and (b), said polystyrene resin comprising from 99 to 1%, on a rubber-free basis, the composition having a dispersed particulate elastomeric phase in which the particles have a maximum mean diameter of about 2 microns and wherein the elastomeric phase comprises from 0.1 to 30% of the total weight of said composition.

Claim 6

A composition as defined in claim 3 wherein the mean diameter of the dispersed elastomeric particles is from about 0.5 microns to about 2 microns.

Claim 7

A composition as defined in claim 3 wherein said polystyrene resin, on a rubber-free basis, comprises from 20 to 80% by weight of the combined weight of said polystyrene resin, on a rubber-free basis, and said polyphenylene ether.

Claim 8

A composition as defined in claim 5 wherein said polystyrene resin, on a rubber-free basis, comprises from 40 to 60% by weight of the combined weight of said polystyrene resin, on a rubber-free basis, and said polyphenylene ether.

Claim 9

A composition as defined in claim 3 wherein the elastomeric phase comprises from 1 to 15% of the total weight of said composition.

Claim 10

A composition as defined in claim 7 wherein the elastomeric phase comprises from 1.5 to 6% of the total weight of said composition.

Claim 11

A composition as defined in claim 3 comprising polyphenylene oxide, a polystyrene resin and a rubber, and wherein said elastomeric phase comprises particles of rubber.

Claim 12

A composition as defined in claim 3 comprising a polyphenylene ether and a rubber modified polystyrene, and wherein said elastomeric phase comprises particles of a polystyrene grafted elastomeric gel.

Claim 13

A composition as defined in claim 10 wherein said rubber modified polystyrene comprises from 70-99 parts by weight of polystyrene and 1-30 parts by weight of a particulate diene elastomer-styrene graft copolymer gel phase.

Claim 14

A composition as defined in claim 11 wherein the mean particulate diameter of said graft copolymer gel phase is from about 0.5 microns to about 2 microns.

Claim 15

A composition as defined in claim 11 wherein the elastomeric phase comprises from 1.5 to 6% of the total weight of said composition.

Claim 16

A composition as defined in claim 11 wherein the diene elastomer is polybutadiene.

Claim 17

A composition as defined in claim 14 wherein the elastomeric phase comprises from 1.5 to 6% of the total weight of said composition.

Claim 18

A composition as defined in claim 11 wherein the diene elastomer is a styrene-butadiene copolymer.

Claim 19

A composition defined in claim 16 wherein the elastomeric phase comprises from 1.5 to 6% of the total weight of said composition.

Claim 20

A composition as defined in claim 3 wherein Q is alkyl having from 1 to 4 carbon atoms.

Claim 21

A composition as defined in claim 18 wherein Q is methyl.