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US4127504A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of a catalyst component for use in the polymerization of alphaolefins

Assignee: Tonen General Sekiyu KK
•
Filing: 1976-11-24
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Granted: 1978-11-28
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Expires: 1996-11-24
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Abstract

Abstract A process for the production of a catalyst component for use in the polymerization of alpha -olefins, which comprises reducing titanium tetrachloride with an organo aluminum compound having the general formula Al Rn X3-n wherein R represents a hydrocarbon group having 1 to 18 carbon atoms, x represents a halogen atom and n represents a suitable numeral between o<n</=3, to thus obtain a reduced solid, then removing aluminum compounds contained in said reduced solid and activating with a mixture or a complex of titanium tetrachloride and a dialkyl ether of the general formula R'OR'' wherein R' and R'' are (a) alkyl groups having 1-4 carbon atoms, (b) normal alkyl groups having five carbon atoms, or (c) alkyl groups having 6-20 carbon atoms.

Inventors

  • 👤 Hiroshi Ueno
  • 👤 Naomi Inaba
  • 👤 Tokuo Makishima
  • 👤 Shozo Wada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 23:36
CPC Classifications
C; C08; C08F; C08F10/00

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 220 words
A process for the production of a catalyst component for use in the polymerization of α-olefins which comprises reducing titanium tetrachloride at a temperature of from -50° to +30° C. with an organoaluminum compound or mixture of such compounds having the general formula A1R n X 3-n wherein R represents a hydrocarbon group having 1 to 18 carbon atoms, X represents a halogen atom and n represents a number expressed as 0<n≦3, to obtain a brown or black-brown titanium trichloride reduced solid containing aluminum compounds, removing aluminum compounds contained in said reduced solid, and thereafter contacting said reduced solid in an inert diluent and at a temperature within the range of from -30° to 100° C. for at least 30 minutes with an activator which is a complex or mixture of titanium tetrachloride and a dialkyl ether wherein the mole ratio of dialkyl ether to titanium tetrachloride is at least 0.1 and the concentration of titanium tetrachloride is maintained at at least 1 volume percent of the liquid phase, said dialkyl ether having the formula R'OR", in which R' and R" are the same or different and each are selected from the group consisting of (a) alkyl groups having 1 to 4 carbon atoms, (b) normal alkyl groups having 5 carbon atoms, and (c) alkyl groups having 6-20 carbon atoms.
Claim 2
Dependent Claim 220 words
A process for the production of a catalyst component for use in the polymerization of α-olefins which comprises reducing titanium tetrachloride at a temperature of from -50° to +30° C. with an organoaluminum compound or mixture of such compounds having the general formula A1R n X 3-n wherein R represents a hydrocarbon group having 1 to 18 carbon atoms, X represents a halogen atom and n represents a number expressed as 0<n≦3, to obtain a brown or black-brown titanium trichloride reduced solid containing aluminum compounds, removing aluminum compounds contained in said reduced solid, and thereafter contacting said reduced solid in an inert diluent and at a temperature within the range of from -30° to 100° C. for at least 30 minutes with an activator which is a complex or mixture of titanium tetrachloride and a dialkyl ether wherein the mole ratio of dialkyl ether to titanium tetrachloride is at least 0.1 and the concentration of titanium tetrachloride is maintained at at least 1 volume percent of the liquid phase, said dialkyl ether having the formula R'OR", in which R' and R" are the same or different and each are selected from the group consisting of (a) alkyl groups having 1 to 4 carbon atoms, (b) normal alkyl groups having 5 carbon atoms, and (c) alkyl groups having 6-20 carbon atoms.
Claim 3
Dependent Claim 14 words
A process according to claim 1, wherein the organoaluminum compound is diethyl aluminum chloride.
Claim 4
Dependent Claim 14 words
A process according to claim 1, wherein the organoaluminum compound is ethyl aluminum dichloride.
Claim 5
Dependent Claim 37 words
A process according to claim 1, wherein the reduction of titanium tetrachloride is effected at a temperature of -50° to +30° C. and thereafter the temperature of the reaction mixture is raised to 20° to 120° C.
Claim 6
Dependent Claim 30 words
A process according to claim 1, wherein the aluminum compounds are removed by complexing with an ether and then extracting the ehter complex of the aluminum compounds with a solvent.
Claim 7
Dependent Claim 44 words
A process according to claim 5, wherein the ether complexing agent is selected from the group consisting of diethyl ether, diisopropyl ether, di-n-butyl ether, di-isobutyl ether, diisoamyl ether, di-2-ethylhexyl ether, di-2-ethylheptyl ether, allyl ethyl ether, allyl butyl ether, anisole, phenetole, chloroanisole, bromoanisole and dimethoxybenzene.
Claim 8
Dependent Claim 58 words
A process according to claim 1, wherein the alkyl ether employed in mixture or complexed with titanium tetrachloride is an alkyl ether selected from the group consisting of di-n-propyl ether, diisopropyl ether, di-n-butyl ether, diisobutyl ether, isobutyl-n-butyl ether, di-n-amyl ether, di-n-hexyl ether, di-n-heptyl ether, diisoheptyl ether, di-2-ethylhexyl ether, di-n-dodecyl ether, n-butyl-2-ethylhexyl ether, and isobutyl-2-ethylhexyl ether and mixtures thereof.
Claim 9
Dependent Claim 13 words
A process according to claim 7, wherein the alkyl ether is di-n-amyl ether.
Claim 10
Dependent Claim 24 words
A process according to claim 2, wherein the mol ratio of the diethyl aluminum chloride to titanium tetrachloride is 1 or more to 1.
Claim 11
Dependent Claim 25 words
A process according to claim 3, wherein the mol ratio of ethyl aluminum dichloride to titanium tetrachloride is 0.3 to 1 to 1.2 to 1.
Claim 12
Dependent Claim 10 words
The catalyst component produced by the process of claim 1.
Claim 13
Dependent Claim 10 words
The catalyst component produced by the process of claim 9.
Claim 14
Dependent Claim 10 words
The catalyst component produced by the process of claim 10.
Claim 15
Dependent Claim 10 words
The catalyst component produced by the process of claim 4.
Claim 16
Dependent Claim 10 words
The catalyst component produced by the process of claim 5.
Claim 17
Dependent Claim 10 words
The catalyst component produced by the process of claim 6.
Claim 18
Dependent Claim 10 words
The catalyst component produced by the process of claim 7.
Claim 19
Dependent Claim 10 words
The catalyst component produced by the process of claim 8.
Claim 20
Dependent Claim 72 words
A process according to claim 1, wherein, in said contacting of brown or black-brown titanium trichloride reduced solid in an inert diluent with said activator, the mole ratio of the dialkyl ether to titanium trichloride is within the range of 0.1 to 2.0, the concentration of titanium tetrachloride in the diluent is at least 5 volume percent and the reduced solid concentration in the diluent is at least 50 grams per liter.

References Cited (Backward Citations)

US3769233A Cited
US3825524A Cited
US3862257A Cited
US3960765A Cited
US3984350A Cited
US4062804A Cited
US4064069A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-11-27 1982-05-29 1982-11-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-11-27 1986-05-29 1986-11-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-11-27 1990-05-29 1990-11-28 $7700.00 Window Closed / Lapsed

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