US4062804A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the production of a catalyst component for use in the polymerization of alpha olefins
Assignee: Tonen General Sekiyu KK
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Filing: 1976-07-08
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Granted: 1977-12-13
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Expires: 1996-07-08
Abstract
Abstract The invention relates to a method for preparing a catalyst composition for polymerization of propylene, having high activity and producing polypropylene of high stereoregularity in narrow particle size distribution, which comprises:
Inventors
- 👤 Hiroshi Ueno
- 👤 Naomi Inaba
- 👤 Tokuo Makishima
- 👤 Shozo Wada
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 01:50
CPC Classifications
C; C08; C08F; C08F10/00; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
187 words
A process for the production of a catalyst component for use in polymerization of alpha-olefins which comprises: reducing titanium tetrachloride with a mixture of a dialkyl aluminum halide with an alkyl aluminum dihalide, wherein said dialkyl aluminum halide is employed in an amount of at least 1 mole per 1 mole of titanium tetrachloride and said alkyl aluminum dihalide is employed in an amount within the range of from 0.3 to 1.2 moles per 1 mole of titanium tetrachloride, to obtain a violet titanium trichloride reduced solid containing aluminum compounds; removing aluminum compounds from said violet titanium trichloride reduced solid; and thereafter contacting said violet titanium trichloride reduced solid in an inert diluent with an activator selected from the group consisting of a complex of diisoamyl ether and titanium tetrachloride, and a mixture of diisoamyl ether and titanium tetrachloride at a temperature within the range of from -30° to 100° C for at least 30 minutes, wherein the mole ratio of diisoamyl ether to titanium trichloride is at least 0.1 and the concentration of titanium tetrachloride in the diluent is maintained at at least 1 volume percent.
Claim 2
Dependent Claim
187 words
A process for the production of a catalyst component for use in polymerization of alpha-olefins which comprises: reducing titanium tetrachloride with a mixture of a dialkyl aluminum halide with an alkyl aluminum dihalide, wherein said dialkyl aluminum halide is employed in an amount of at least 1 mole per 1 mole of titanium tetrachloride and said alkyl aluminum dihalide is employed in an amount within the range of from 0.3 to 1.2 moles per 1 mole of titanium tetrachloride, to obtain a violet titanium trichloride reduced solid containing aluminum compounds; removing aluminum compounds from said violet titanium trichloride reduced solid; and thereafter contacting said violet titanium trichloride reduced solid in an inert diluent with an activator selected from the group consisting of a complex of diisoamyl ether and titanium tetrachloride, and a mixture of diisoamyl ether and titanium tetrachloride at a temperature within the range of from -30° to 100° C for at least 30 minutes, wherein the mole ratio of diisoamyl ether to titanium trichloride is at least 0.1 and the concentration of titanium tetrachloride in the diluent is maintained at at least 1 volume percent.
Claim 3
Dependent Claim
18 words
A process according to claim 1 wherein the aluminum compounds are removed by washing with a complexing agent.
Claim 4
Dependent Claim
28 words
A process according to claim 2 wherein the complexing agent is selected from the group consisting of ethers, thioethers, thiols, organo-phosphorus compounds, organo nitrogen compounds, ketones and esters.
Claim 5
Dependent Claim
13 words
A process according to claim 3 wherein the complexing agent is di-n-butyl ether.
Claim 6
Dependent Claim
18 words
A process according to claim 1 wherein the activator is a complex of diisoamyl ether and titanium tetrachloride.
Claim 7
Dependent Claim
18 words
A process according to claim 1 wherein the activator is a mixture of diisoamyl ether and titanium tetrachloride.
Claim 8
Dependent Claim
68 words
A process according to claim 1, wherein, in said contacting of violet titanium trichloride reduced solid in inert diluent with said activator, the mole ratio of diisoamyl ether to titanium trichloride is within the range of 0.1 to 0.6, the concentration of titanium tetrachloride in the diluent is at least 5 volume percent and the reduced solid concentration in the diluent is at least 50 grams per liter.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-12-12 | 1981-06-13 | 1981-12-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-12-12 | 1985-06-13 | 1985-12-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-12-12 | 1989-06-13 | 1989-12-13 | $7700.00 | Window Closed / Lapsed |