Polyhydroxy-alkyl-3,5-disubstituted-2,4,6-triiodocarbanilates

Claim 2

A compound of the formula: ##STR25## wherein X and Y are each selected from the group consisting of lower alkoxy, hydroxy-(lower alkoxy), lower alkoxy-(lower alkoxy), lower acylamino, lower acylamino-(lower alkyl), lower acylamino-(lower acylamino), hydroxy-lower acylamino, N-(lower alkyl)-lower acylamino, lower alkylsulfonamido, N-(lower alkyl)-lower alkylsulfonamido, 3,3-bis-(lower alkyl)-ureido, lower perfluoroacylamino, carbamyl, N-(lower alkyl)carbamyl, N,N-di-(lower alkyl) carbamyl, lower alkoxy-(lower acylamino), lower alkoxyalkoxy-(lower acylamino), hydroxy and hydroxy-lower alkyl and Z is the monovalent residue of a polyol selected from the group consisting of linear and branched chain polyols, said monovalent residue containing not more than 7 carbon atoms in its chain or ring.

Claim 3

A compound as set forth in claim 1 wherein one of X and Y is selected from the group consisting of hydrogen and a member of the group set forth in claim 1 and the other of X and Y is ##STR26## where Z is as defined in claim 1.

Claim 4

A compound as set forth in claim 1 wherein X and Y are each selected from the group consisting of lower acylamino, N-(lower alkyl)-lower acylamino, carbamyl, N-(lower alkyl)carbamyl and N,N-di-(lower alkyl)carbamyl.

Claim 5

A compound as set forth in claim 1 wherein X is N-methylcarbamyl, Y is N,N-dimethylcarbamyl and Z is the monovalent residue of the linear polyol which is the ketose L-sorbose, attached at the 1-position.

Claim 6

A compound as set forth in claim 1 wherein X is N-methylcarbamyl, Y is N-methylacetamido and Z is the monovalent residue of the linear polyol which is the aldose galactose, substituted at the 6-position.

Claim 7

A compound of the formula: ##STR27## wherein X and Y are each selected from the group consisting of lower alkoxy, lower alkoxy-(lower alkoxy), lower acylamino, lower acylamino-(lower alkyl), lower acylamino-(lower acylamino), N-(lower alkyl)-lower acylamino, lower alkylsulfonamido, N-(lower alkyl)-lower alkysulfonamido, 3,3-bis-(lower alkyl)-ureido, lower perfluoroacylamino, carbamyl, N-(lower alkyl)carbamyl, N,N-di-(lower alkyl)carbamyl, lower alkoxy-(lower acylamino), lower alkoxy-alkoxy-(lower acylamino) functions and ester, acetal or ketal derivatives of hydroxy, hydroxy-lower alkyl, hydroxy-(lower alkoxy) and hydroxy-lower acylamino and Z p is selected from the group consisting of ester, acetal and ketal derivatives of a monovalent residue of a polyol selected from the group consisting of linear and branched chain polyols, said derivatives containing at least one hydroxyl group in an unprotected form and said monovalent residue containing not more than 7 carbon atoms in its chain or ring.

Claim 8

A compound of the formula: ##STR27## wherein X and Y are each selected from the group consisting of lower alkoxy, lower alkoxy-(lower alkoxy), lower acylamino, lower acylamino-(lower alkyl), lower acylamino-(lower acylamino), N-(lower alkyl)-lower acylamino, lower alkylsulfonamido, N-(lower alkyl)-lower alkysulfonamido, 3,3-bis-(lower alkyl)-ureido, lower perfluoroacylamino, carbamyl, N-(lower alkyl)carbamyl, N,N-di-(lower alkyl)carbamyl, lower alkoxy-(lower acylamino), lower alkoxy-alkoxy-(lower acylamino) functions and ester, acetal or ketal derivatives of hydroxy, hydroxy-lower alkyl, hydroxy-(lower alkoxy) and hydroxy-lower acylamino and Z p is selected from the group consisting of ester, acetal and ketal derivatives of a monovalent residue of a polyol selected from the group consisting of linear and branched chain polyols, said derivatives containing at least one hydroxyl group in an unprotected form and said monovalent residue containing not more than 7 carbon atoms in its chain or ring.

Claim 9

A compound as set forth in claim 6 wherein said derivatives contain not more than one primary and one secondary hydroxyl group in an unprotected form.

Claim 10

A compound as set forth in claim 6 wherein one of X and Y is selected from the group consisting of hydrogen and a member of the group set forth in claim 6 and the other of X and Y is ##STR28## where Z p is as defined in claim 6.

Claim 11

A compound as set forth in claim 6 wherein X and Y are each selected from the group consisting of lower acylamino, N-(lower alkyl)-lower acylamino, carbamyl, N-(lower alkyl)carbamyl and N,N-di-(lower alkyl)carbamyl.

Claim 12

In a method for preparing a compound of the formula: ##STR29## wherein X and Y are each selected from the group consisting of lower alkoxy, hydroxy-(lower alkoxy), lower alkoxy-(lower alkoxy), lower acylamino, lower acylamino-(lower alkyl), lower acylamino-(lower acylamino), hydroxy-lower acylamino, N-(lower alkyl)-lower acylamino, lower alkylsulfonamido, N-(lower alkyl)-lower alkylsulfonamido, 3,3-bis-(lower alkyl)-ureido, lower perfluoroacylamino, carbamyl, N-(lower alkyl)carbamyl, N,N-di-(lower alkyl) carbamyl, lower alkoxy-(lower acylamino), lower alkoxy-alkoxy-(lower acylamino), hydroxy and hydroxy-lower alkyl and Z is the monovalent residue of a polyol selected from the group consisting of linear and branched chain polyols, said monovalent residue containing not more than 7 carbon atoms in its chain or ring, the step which comprises reacting a compound of the formula: ##STR30## wherein X and Y are as defined above and R' is selected from the group consisting of isocyanate and carbamyl chloride functions, with a compound selected from the group consisting of the ester, acetal and ketal derivatives of a polyol selected from the group consisting of linear and branched chain polyols, said derivatives containing at least one hydroxyl group in an unprotected form and said polyol containing not more than 7 carbon atoms in its chain or ring.

Claim 13

In a method for preparing a compound of the formula: ##STR29## wherein X and Y are each selected from the group consisting of lower alkoxy, hydroxy-(lower alkoxy), lower alkoxy-(lower alkoxy), lower acylamino, lower acylamino-(lower alkyl), lower acylamino-(lower acylamino), hydroxy-lower acylamino, N-(lower alkyl)-lower acylamino, lower alkylsulfonamido, N-(lower alkyl)-lower alkylsulfonamido, 3,3-bis-(lower alkyl)-ureido, lower perfluoroacylamino, carbamyl, N-(lower alkyl)carbamyl, N,N-di-(lower alkyl) carbamyl, lower alkoxy-(lower acylamino), lower alkoxy-alkoxy-(lower acylamino), hydroxy and hydroxy-lower alkyl and Z is the monovalent residue of a polyol selected from the group consisting of linear and branched chain polyols, said monovalent residue containing not more than 7 carbon atoms in its chain or ring, the step which comprises reacting a compound of the formula: ##STR30## wherein X and Y are as defined above and R' is selected from the group consisting of isocyanate and carbamyl chloride functions, with a compound selected from the group consisting of the ester, acetal and ketal derivatives of a polyol selected from the group consisting of linear and branched chain polyols, said derivatives containing at least one hydroxyl group in an unprotected form and said polyol containing not more than 7 carbon atoms in its chain or ring.

Claim 14

A method as set forth in claim 10 wherein the product of said reaction is converted into a compound of the formula: ##STR31## wherein X, Y and Z are as defined in claim 10.

Claim 15

A method as set forth in claim 10 wherein one of X and Y is selected from the group consisting of hydrogen and a member of the group set forth in claim 10 and the other of X and Y is ##STR32## where Z is the monovalent residue of a polyol selected from the group set forth in claim 10.

Claim 16

A method as set forth in claim 10 wherein X and Y are each selected from the group consisting of lower acylamino, N-(lower alkyl)-lower acylamino, carbamyl, N-(lower alkyl)carbamyl and N,N-di-(lower alkyl)carbamyl.