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US4124526A
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Encapsulation process and resulting aqueous dispersion of encapsulated droplets
Assignee: Monsanto Co
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Filing: 1977-06-13
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Granted: 1978-11-07
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Expires: 1997-06-13
Abstract
Abstract Oil droplets are encapsulated by forming a dispersion of the droplets in an aqueous alkaline liquid medium containing a water-soluble salt of a polycarboxylate polymer and acidifying the medium to a pH in the range of 5 to 8 whereby the polycarboxylate polymer precipitates to form walls around the droplets.
Inventors
- 👤 Pierre J. Allart
- 👤 Henri B. May
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 03:37
CPC Classifications
B; B01; B01J; B01J13/00; B01J13/02; B01J13/06; B01J13/08; B41; B41M; B41M5/00; B41M5/124; B41M5/165; Y; Y10; Y10S; Y10S428/00; Y10S428/914; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249994; Y10T428/249995; Y10T428/249997; Y10T428/29; Y10T428/2982; Y10T428/2984; Y10T428/2985; Y10T428/2987
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
210 words
A process for the encapsulation of oil droplets which comprises the steps of: (a) Forming a dispersion of droplets of the oil in an aqueous alkaline liquid medium containing in solution an alkali metal salt of a polycarboxylate polymer; said alkali metal salt having been prepared by contacting an ethylene/maleic anhydride copolymer with an aqueous solution of an alkali metal hydroxide and an alkylamine or alkenylamine of up to 6 carbon atoms, a cycloalkylamine having 5 or 6 ring carbon atoms, a polyamine of the formula H.sub.2 N(CHRCH.sub.2 NH).sub.n CHRCH.sub.2 NH.sub.2 where R is hydrogen or methyl and n is an integer from 1 to 4; or a diamine of the formula H.sub.2 N(CH.sub.2).sub.m NH.sub.2 where m is an integer from 2 to 8; using a molar ratio of hydroxide to amine of from 3:5 to 5:3 and a combined quantity of hydroxide and amine which is from 80 to 120% of the stoichiometric quantity required for opening of the anhydride rings of the ethylene/maleic anhydride copolymer to form pendant alkali metal carboxylate and carboxylic amide groups; and (b) Acidifying the aqueous liquid medium to a pH in the range 5 to 8 while maintaining the droplets in dispersion, whereby polycarboxylate polymer is precipitated to form walls around the droplets.
Claim 2
Dependent Claim
210 words
A process for the encapsulation of oil droplets which comprises the steps of: (a) Forming a dispersion of droplets of the oil in an aqueous alkaline liquid medium containing in solution an alkali metal salt of a polycarboxylate polymer; said alkali metal salt having been prepared by contacting an ethylene/maleic anhydride copolymer with an aqueous solution of an alkali metal hydroxide and an alkylamine or alkenylamine of up to 6 carbon atoms, a cycloalkylamine having 5 or 6 ring carbon atoms, a polyamine of the formula H.sub.2 N(CHRCH.sub.2 NH).sub.n CHRCH.sub.2 NH.sub.2 where R is hydrogen or methyl and n is an integer from 1 to 4; or a diamine of the formula H.sub.2 N(CH.sub.2).sub.m NH.sub.2 where m is an integer from 2 to 8; using a molar ratio of hydroxide to amine of from 3:5 to 5:3 and a combined quantity of hydroxide and amine which is from 80 to 120% of the stoichiometric quantity required for opening of the anhydride rings of the ethylene/maleic anhydride copolymer to form pendant alkali metal carboxylate and carboxylic amide groups; and (b) Acidifying the aqueous liquid medium to a pH in the range 5 to 8 while maintaining the droplets in dispersion, whereby polycarboxylate polymer is precipitated to form walls around the droplets.
Claim 3
Dependent Claim
23 words
A process of claim 1 in which the aqueous liquid medium is acidified to a pH in the range of 5 to 6.
Claim 4
Dependent Claim
19 words
A process of claim 1 in which the alkali metal salt of the polycarboxylate polymer is the sodium salt.
Claim 5
Dependent Claim
15 words
A process of claim 3 in which the amine is an aliphatic or cycloaliphatic amine.
Claim 6
Dependent Claim
16 words
A process of claim 4 in which the amine is n-propylamine, n-butylamine, n-pentylamine or diethylene triamine.
Claim 7
Dependent Claim
21 words
A process of claim 1 in which the ethylene/maleic anhydride copolymer has a molecular weight within the range 20,000 to 70,000.
Claim 8
Dependent Claim
36 words
A process of claim 1 in which the acid used to acidify the aqueous liquid medium is an acid having a dissociation constant not greater than 2 × 10 -3 in aqueous solution at 25° C.
Claim 9
Dependent Claim
12 words
A process of claim 7 in which the acid is acetic acid.
Claim 10
Dependent Claim
17 words
An aqueous dispersion of encapsulated oil droplets that has been obtained by a process of claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-11-06 | 1982-05-08 | 1982-11-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-11-06 | 1986-05-08 | 1986-11-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-11-06 | 1990-05-08 | 1990-11-07 | $7700.00 | Window Closed / Lapsed |