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US4123370A
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Preparation and use of basic metal salt compositions of phosphorus-containing acids
Assignee: Lubrizol Corp
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Filing: 1978-03-20
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Granted: 1978-10-31
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Expires: 1998-03-20
Abstract
Abstract Reaction mixtures comprising components (A) Group II metal salts of phosphorus-containing acids, (B) basically reacting alkali metal compounds, and (C) optionally, di- or trivalent metal-containing salts are suitable for the preparation of basic metal salt compositions of phosphorus-containing acids, with the proviso that components (A), (B), and (C) are not the same. The basic metal salt compositions are useful in the preparation of lubricants.
Inventors
- 👤 Norman A. Meinhardt
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 11:47
CPC Classifications
C; C10; C10M; C10M137/00; C10M159/00; C10M159/12; C10M159/20; C10M2203/00; C10M2203/06; C10M2205/00; C10M2205/02; C10M2205/024; C10M2205/026; C10M2205/028; C10M2207/00; C10M2207/04; C10M2207/28; C10M2207/281; C10M2207/282; C10M2207/283; C10M2207/286; C10M2207/34; C10M2207/40; C10M2207/402; C10M2207/404; C10M2209/00; C10M2209/02; C10M2209/10; C10M2209/103; C10M2209/104; C10M2209/105; C10M2209/108; C10M2209/11; C10M2209/111; C10M2211/00; C10M2211/06; C10M2211/08; C10M2213/00; C10M2213/02; C10M2213/06; C10M2213/062; C10M2219/00; C10M2219/02; C10M2219/022; C10M2219/024; C10M2219/04; C10M2219/044; C10M2219/046; C10M2219/06; C10M2219/062; C10M2219/066; C10M2219/068; C10M2219/08; C10M2219/082; C10M2219/083; C10M2219/086; C10M2219/087; C10M2219/089; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/041; C10M2223/042; C10M2223/045; C10M2223/06; C10M2223/061; C10M2223/065; C10M2223/12; C10M2225/00; C10M2225/04; C10M2225/041; C10M2227/00; C10M2227/02; C10M2229/00; C10M2229/04; C10M2229/041; C10M2229/042; C10M2229/045; C10M2229/046; C10M2229/047; C10M2229/048; C10N; C10N2010/00; C10N2010/02; C10N2010/04; C10N2010/06; C10N2010/08; C10N2010/10; C10N2010/14; C10N2010/16; C10N2020/00; C10N2020/01; C10N2040/00; C10N2040/02; C10N2040/08; C10N2040/135; C10N2040/20; C10N2040/25; C10N2040/251; C10N2040/252; C10N2040/253; C10N2040/255; C10N2040/26; C10N2040/28; C10N2050/00; C10N2050/10; C10N2070/00; C10N2070/02
Claims Analysis
Total Claims: 46
Claim 1
Independent Claim
124 words
A reaction mixture suitable for preparation of basic metal salt compositions of one or more phosphorus-containing acids which comprises: (A) at least one Group II metal salt of one or more phosphorus-containing acids of the formula ##STR5## wherein each X and X' are independently oxygen or divalent sulfur with the proviso that each n may be zero or one, each R is independently the same or a different hydrocarbon-based radical and the Group II metal has an atomic weight between about 24 and about 115; and (B) at least one basically reacting alkali metal compound; wherein the equivalent ratio of the acid of (A) : (B) in the reaction mixture is sufficient to form a basic or a more basic metal salt of (A).
Claim 2
Dependent Claim
124 words
A reaction mixture suitable for preparation of basic metal salt compositions of one or more phosphorus-containing acids which comprises: (A) at least one Group II metal salt of one or more phosphorus-containing acids of the formula ##STR5## wherein each X and X' are independently oxygen or divalent sulfur with the proviso that each n may be zero or one, each R is independently the same or a different hydrocarbon-based radical and the Group II metal has an atomic weight between about 24 and about 115; and (B) at least one basically reacting alkali metal compound; wherein the equivalent ratio of the acid of (A) : (B) in the reaction mixture is sufficient to form a basic or a more basic metal salt of (A).
Claim 3
Dependent Claim
25 words
A reaction mixture according to claim 1, wherein at least one X is divalent sulfur; at least one X' is oxygen and n is one.
Claim 4
Dependent Claim
17 words
A reaction mixture according to claim 2, which further comprises (D) a substantially inert liquid solvent/diluent medium.
Claim 5
Dependent Claim
30 words
A reaction mixture according to claim 3, wherein the equivalent ratio of the acid of (A) : (B) is in a range of from about 1:0.05 up to about 1:6.
Claim 6
Dependent Claim
118 words
A process for preparing basic metal salt compositions of phosphoric acids which comprises reacting: (A) at least one Group II metal salt of one or more phosphorus-containing acids of the formula ##STR6## wherein each X and X' are independently oxygen or divalent sulfur with the proviso that each n may be zero or one, each R is independently the same or a different hydrocarbon-based radical, and the Group II metal has an atomic weight between about 24 and about 115; and (B) at least one basically reacting alkali metal compound; wherein the equivalent ratio of the acid of (A) : (B) in the reaction is sufficient to form a basic or a more basic metal salt of (A).
Claim 7
Dependent Claim
118 words
A process for preparing basic metal salt compositions of phosphoric acids which comprises reacting: (A) at least one Group II metal salt of one or more phosphorus-containing acids of the formula ##STR6## wherein each X and X' are independently oxygen or divalent sulfur with the proviso that each n may be zero or one, each R is independently the same or a different hydrocarbon-based radical, and the Group II metal has an atomic weight between about 24 and about 115; and (B) at least one basically reacting alkali metal compound; wherein the equivalent ratio of the acid of (A) : (B) in the reaction is sufficient to form a basic or a more basic metal salt of (A).
Claim 8
Dependent Claim
14 words
A process according to claim 5, wherein at least one X is divalent sulfur.
Claim 9
Dependent Claim
14 words
A process according to claim 6, wherein X' is oxygen and n is one.
Claim 10
Dependent Claim
14 words
A process according to claim 7, wherein (B) comprises one or more inorganic compounds.
Claim 11
Dependent Claim
22 words
A process according to claim 8, wherein the reaction is conducted in the presence of a substantially inert liquid solvent/diluent medium (D).
Claim 12
Dependent Claim
15 words
A process according to claim 9, wherein the liquid solvent/diluent medium (D) comprises polar solvent/diluent.
Claim 13
Dependent Claim
18 words
A process according to claim 9, wherein each R is hydrocarbyl of 1 to about 30 carbon atoms.
Claim 14
Dependent Claim
29 words
A process according to claim 11, wherein the equivalent ratio of the acid of (A) : (B) is in a range of from about 1:0.05 up to about 1:6.
Claim 15
Dependent Claim
17 words
A process according to claim 11, wherein (B) comprises one or more alkali metal hydroxides or oxides.
Claim 16
Dependent Claim
14 words
A process according to claim 13, wherein (A) comprises one or more zinc salts.
Claim 17
Dependent Claim
20 words
A process according to claim 13, wherein (A) is selected from zinc, magnesium, calcium, and cadmium salts and mixtures thereof.
Claim 18
Dependent Claim
19 words
A process according to claim 15, wherein each R is alkyl of from 1 to about 20 carbon atoms.
Claim 19
Dependent Claim
28 words
A process according to claim 16, wherein one R contains at least 5 carbon atoms and together both R's contain a total of at least 8 carbon atoms.
Claim 20
Dependent Claim
10 words
A composition prepared according to the process of claim 5.
Claim 21
Dependent Claim
10 words
A composition prepared according to the process of claim 8.
Claim 22
Dependent Claim
10 words
A composition prepared according to the process of claim 9.
Claim 23
Dependent Claim
10 words
A composition prepared according to the process of claim 10.
Claim 24
Dependent Claim
10 words
A composition prepared according to the process of claim 12.
Claim 25
Dependent Claim
10 words
A composition prepared according to the process of claim 13.
Claim 26
Dependent Claim
10 words
A composition prepared according to the process of claim 14.
Claim 27
Dependent Claim
10 words
A composition prepared according to the process of claim 16.
Claim 28
Dependent Claim
10 words
A composition prepared according to the process of claim 17.
Claim 29
Dependent Claim
22 words
An additive concentrate comprising about 20-90% of at least one composition of claim 18 and a substantially inert, normally liquid, organic diluent.
Claim 30
Dependent Claim
22 words
An additive concentrate comprising about 20-90% of at least one composition of claim 19 and a substantially inert, normally liquid, organic diluent.
Claim 31
Dependent Claim
22 words
An additive concentrate comprising about 20-90% of at least one composition of claim 20 and a substantially inert, normally liquid, organic diluent.
Claim 32
Dependent Claim
22 words
An additive concentrate comprising about 20-90% of at least one composition of claim 21 and a substantially inert, normally liquid, organic diluent.
Claim 33
Dependent Claim
22 words
An additive concentrate comprising about 20-90% of at least one composition of claim 22 and a substantially inert, normally liquid, organic diluent.
Claim 34
Dependent Claim
22 words
An additive concentrate comprising about 20-90% of at least one composition of claim 23 and a substantially inert, normally liquid, organic diluent.
Claim 35
Dependent Claim
22 words
An additive concentrate comprising about 20-90% of at least one composition of claim 24 and a substantially inert, normally liquid, organic diluent.
Claim 36
Dependent Claim
22 words
An additive concentrate comprising about 20-90% of at least one composition of claim 25 and a substantially inert, normally liquid, organic diluent.
Claim 37
Dependent Claim
22 words
An additive concentrate comprising about 20-90% of at least one composition of claim 26 and a substantially inert, normally liquid, organic diluent.
Claim 38
Dependent Claim
25 words
A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one composition of claim 18.
Claim 39
Dependent Claim
25 words
A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one composition of claim 19.
Claim 40
Dependent Claim
25 words
A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one composition of claim 20.
Claim 41
Dependent Claim
25 words
A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one composition of claim 21.
Claim 42
Dependent Claim
25 words
A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one composition of claim 22.
Claim 43
Dependent Claim
25 words
A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one composition of claim 23.
Claim 44
Dependent Claim
25 words
A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one composition of claim 24.
Claim 45
Dependent Claim
25 words
A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one composition of claim 25.
Claim 46
Dependent Claim
25 words
A lubricant composition comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one composition of claim 26.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-10-30 | 1982-05-01 | 1982-10-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-10-30 | 1986-05-01 | 1986-10-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-10-30 | 1990-05-01 | 1990-10-31 | $7700.00 | Window Closed / Lapsed |