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US4123277A Expired / Lapsed US ⏱️ 0.0 years remaining

Copolymer subbing material for photographic elements

Assignee: Fujifilm Holdings Corp
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Filing: 1977-03-24
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Granted: 1978-10-31
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Expires: 1997-03-24
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Abstract

Abstract A photographic element which comprises a resin film or resin coated paper support having superimposed thereon a layer of a composition comprising a copolymer containing therein the moiety of the general formula (I) ##STR1## wherein R 1 and R 2 each is a hydrogen atom or an alkyl group having 1 to 12 carbon atoms.

Inventors

  • 👤 Takeji Ochiai

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 18:21
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/91; G03C1/93

Claims Analysis

Total Claims: 32
Claim 1
Independent Claim 305 words
A photographic element which comprises a resin film or resin coated paper having superimposed thereon a subbing layer of a composition consisting essentially of a copolymer of components (A), (B) and (C), wherein component (A) is present in an amount from about 0.1 to 15% by weight, component (B) is present in an amount of from 0.01 to 5% by weight, and component (C) is present in an amount of from about 20 to 80% by weight, component (A) being a monomer containing therein a moiety of the general formula (I) ##STR8## wherein R 1 and R 2 each is a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, component (B) being a monomer containing a carboxyl group or a branched alkoxy carbonyl group selected from the group consisting of acrylic acid, methacrylic acid, ethacrylic acid, chloroacrylic acid, maleic acid, fumaric acid, itaconic acid, mesaconic acid, citraconic acid, sorbic acid, acryloxypropionic acid, itaconic acid anhydride, maleic acid anhydride or a mixture of these acids, and component (C) being at least one monomer selected from the group consisting of isoprene, butadiene, butene, octene, styrene, methylstyrene, methyl vinyl ether, ethyl vinyl ether, chloroethyl vinyl ether, butyl vinyl ether, unsubstituted vinyl esters, acrylates, methacrylates, and acrylonitrile and a hydrophilic colloid layer coated on the layer of said composition comprising said copolymer containing therein the moiety of the general formula (I), said copolymer having a molecular weight of about 10,000 to 1,000,000 and being present in an amount effective to provide increased adhesion, of a degree useful in photographic element, between said resin film or resin coated paper and said hydrophilic colloid layer, and said resin film or resin coated paper having at least one layer containing a light-sensitive silver halide, physical development nuclei as used in a diffusion transfer process or a diazo compound.
Claim 2
Dependent Claim 305 words
A photographic element which comprises a resin film or resin coated paper having superimposed thereon a subbing layer of a composition consisting essentially of a copolymer of components (A), (B) and (C), wherein component (A) is present in an amount from about 0.1 to 15% by weight, component (B) is present in an amount of from 0.01 to 5% by weight, and component (C) is present in an amount of from about 20 to 80% by weight, component (A) being a monomer containing therein a moiety of the general formula (I) ##STR8## wherein R 1 and R 2 each is a hydrogen atom or an alkyl group having 1 to 12 carbon atoms, component (B) being a monomer containing a carboxyl group or a branched alkoxy carbonyl group selected from the group consisting of acrylic acid, methacrylic acid, ethacrylic acid, chloroacrylic acid, maleic acid, fumaric acid, itaconic acid, mesaconic acid, citraconic acid, sorbic acid, acryloxypropionic acid, itaconic acid anhydride, maleic acid anhydride or a mixture of these acids, and component (C) being at least one monomer selected from the group consisting of isoprene, butadiene, butene, octene, styrene, methylstyrene, methyl vinyl ether, ethyl vinyl ether, chloroethyl vinyl ether, butyl vinyl ether, unsubstituted vinyl esters, acrylates, methacrylates, and acrylonitrile and a hydrophilic colloid layer coated on the layer of said composition comprising said copolymer containing therein the moiety of the general formula (I), said copolymer having a molecular weight of about 10,000 to 1,000,000 and being present in an amount effective to provide increased adhesion, of a degree useful in photographic element, between said resin film or resin coated paper and said hydrophilic colloid layer, and said resin film or resin coated paper having at least one layer containing a light-sensitive silver halide, physical development nuclei as used in a diffusion transfer process or a diazo compound.
Claim 3
Dependent Claim 17 words
The photographic element of claim 1, wherein R 2 is a hydrogen atom or a methyl group.
Claim 4
Dependent Claim 17 words
The photographic element of claim 1, wherein R 1 is a hydrogen atom or a methyl group.
Claim 5
Dependent Claim 18 words
The photographic element of claim 1, wherein the moiety of the general formula (I) is an N-methylolamide moiety.
Claim 6
Dependent Claim 20 words
The photographic element of claim 1, wherein the monomer (B) component is an α,β-unsaturated carboxylic acid or a derivative thereof.
Claim 7
Dependent Claim 14 words
The photographic element of claim 1, wherein the monomer (C) component is a diene.
Claim 8
Dependent Claim 25 words
The photographic element of claim 1, wherein said monomer (A) is present in said copolymer in an amount of about 0.1 to 15% by weight.
Claim 9
Dependent Claim 26 words
The photographic element of claim 1, wherein the monomer (B) component is present in said copolymer in an amount of about 0.01 to 5% by weight.
Claim 10
Dependent Claim 32 words
The photographic element of claim 1, wherein said layer of said composition comprising said copolymer containing therein the moiety of the general formula (I) adheres well to a hydrophilic photographic colloid layer.
Claim 11
Dependent Claim 16 words
The photographic element of claim 1, wherein said hydrophilic colloid layer is a photographic emulsion layer.
Claim 12
Dependent Claim 22 words
The photographic element of claim 1, wherein said support is a polyester resin film support or a polyester resin coated paper support.
Claim 13
Dependent Claim 17 words
The photographic element of claim 1, wherein said monomer (A) is N-methyloacrylamide, N-methylol methacrylamide or N,N-dimethylol acrylamide.
Claim 14
Dependent Claim 18 words
The photographic element of claim 1, wherein said monomer (B) is acrylic acid, methacrylic acid or itaconic acid.
Claim 15
Dependent Claim 14 words
The photographic element of claim 1, wherein said monomer (C) is butadiene or styrene.
Claim 16
Dependent Claim 12 words
The photographic element of claim 1, wherein said copolymer is water insoluble.
Claim 17
Dependent Claim 53 words
The photographic element of claim 1, wherein component (A) is present in an amount of from about 0.1 to 15% by weight, component (B) is present in an amount of from about 0.01 to 5% by weight, and component (C) is present in an amount of from about 20 to 80% by weight.
Claim 18
Dependent Claim 24 words
The photographic element of claim 1, wherein said subbing layer is applied so as to have a dry thickness of about 0.1 to 2μ.
Claim 19
Dependent Claim 16 words
The photographic element of claim 1, wherein said hydrophilic colloid layer contains a light-sensitive silver halide.
Claim 20
Dependent Claim 22 words
The photographic element of claim 1, wherein said hydrophilic colloid layer contains physical development nuclei as used in a diffusion transfer process.
Claim 21
Dependent Claim 15 words
The photographic element of claim 1, wherein said hydrophilic colloid layer contains a diazo compound.
Claim 22
Dependent Claim 14 words
The photographic element of claim 1, wherein said hydrophilic colloid layer contains a coupler.
Claim 23
Dependent Claim 14 words
The photographic element of claim 1, wherein said hydrophilic colloid layer contains carbon black.
Claim 24
Dependent Claim 11 words
The photographic element of claim 1, wherein monomer (C) is methylmethacrylate.
Claim 25
Dependent Claim 12 words
The photographic element of claim 1, wherein monomer (C) is methyl acrylate.
Claim 26
Dependent Claim 70 words
The photographic element of claim 1, wherein said subbing layer contains epichlorohydrin, 2,2'-bis(p-glycidyloxy)benzene, 1,3-bis(2',3'-epoxy propoxy)ethane, mucochloric acid, glyceraldehyde, proparglyacetal, an antistatic agent, a matting agent or a cross-linking agent having a carboxyl group, a methylol group, an hydroxyl group, an oxirane group, an epoxy group, an isocyanate group, an acetal group, a vinyl group, an oxy group, a carbo-diimide group or a phenolic hydroxyl group, or a metal cross-linking agent.
Claim 27
Dependent Claim 29 words
The photographic element of claim 17, wherein said hydrophilic colloid layer contains a silver halide, physical development nuclei as used in a diffusion transfer process or a diazo compound.
Claim 28
Dependent Claim 21 words
The photographic element of claim 17, wherein said copolymer consists essentially of butadiene, styrene, acrylic acid, methacrylic acid and N-methylol acrylamide.
Claim 29
Dependent Claim 21 words
The photographic element of claim 17, wherein said copolymer consists essentially of butadiene, styrene, acrylic acid, methacrylic acid and N,N-dimethylol acrylamide.
Claim 30
Dependent Claim 19 words
The photographic element of claim 17, wherein said copolymer consists essentially of butadiene, styrene, itaconic acid and N-methylol acrylamide.
Claim 31
Dependent Claim 21 words
The photographic element of claim 17, wherein said copolymer consists essentially of butadiene, styrene, acrylic acid, methacrylic acid and N-methylol methacrylamide.
Claim 32
Dependent Claim 49 words
The photographic element of claim 16, wherein said subbing layer is applied so as to have a dry thickness of about 0.1 to 2 microns and wherein said hydrophilic colloid layer contains a silver halide, physical developing nuclei as used in a diffusion transfer process or a diazo compound.

References Cited (Backward Citations)

US3573951A Cited
US3600208A Cited
US3713829A Cited
US3674531A Cited
US3751280A Cited
US3778272A Cited
US3847620A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-10-30 1982-05-01 1982-10-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-10-30 1986-05-01 1986-10-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-10-30 1990-05-01 1990-10-31 $7700.00 Window Closed / Lapsed

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