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US4122266A Expired / Lapsed US ⏱️ 0.0 years remaining

Reaction of aryl sulfonic acid ester and amines

Assignee: Chevron USA Inc
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Filing: 1975-12-29
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Granted: 1978-10-24
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Expires: 1995-12-29
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Abstract

Abstract Oil-soluble, nitrogen-containing compositions, useful as lubricating oil additives, are provided. These compositions are prepared by reacting: (a) an aryl ester of a hydrocarbylethylsulfonic acid; or (b) a hydrocarbylsulfonyl chloride with a nitrogen-containing compound containing at least one amine hydrogen, i.e., --NH function. Also provided are processes for preparing these compositions and lubricating oil additive concentrates and lubricating oil compositions containing these compositions.

Inventors

  • 👤 Louis De Vries

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 23:49
CPC Classifications
C; C07; C07D; C07D295/00; C07D295/22; C07D295/26; C07C; C07C309/00; C07C309/63; C07C309/64; C07C309/67; C08; C08F; C08F8/00; C08F8/30; C08F8/32; C10; C10M; C10M1/00; C10M1/08; C10M2205/00; C10M2205/02; C10M2205/026; C10M2211/00; C10M2211/08; C10M2219/00; C10M2219/02; C10M2219/022; C10M2219/024; C10M2219/04; C10M2219/044; C10M2219/046; C10M2219/06; C10M2219/062; C10M2219/066; C10M2219/068; C10M2219/08; C10M2219/082; C10M2219/083; C10M2219/087; C10M2219/088; C10M2219/089; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/042; C10M2223/045; C10N; C10N2010/00; C10N2010/04; C10N2040/00; C10N2040/25; C10N2040/255; C10N2040/26; C10N2070/00; C10N2070/02

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 62 words
A process for preparing an oil-soluble, nitrogen-containing composition comprising combining, at a temperature from about 50° C. to about 250° C., an aryl ester of a substantially saturated hydrocarbylethylsulfonic acid, the substantially saturated hydrocarbyl substitutent containing at least 20 aliphatic carbon atoms, with from 0.1 to 15 mols, per equivalent of said ester, of a nitrogen-containing compound containing at least one--NH function.
Claim 2
Dependent Claim 62 words
A process for preparing an oil-soluble, nitrogen-containing composition comprising combining, at a temperature from about 50° C. to about 250° C., an aryl ester of a substantially saturated hydrocarbylethylsulfonic acid, the substantially saturated hydrocarbyl substitutent containing at least 20 aliphatic carbon atoms, with from 0.1 to 15 mols, per equivalent of said ester, of a nitrogen-containing compound containing at least one--NH function.
Claim 3
Dependent Claim 87 words
The process of claim 1 wherein the aryl ester is selected from those of the formulas ##STR7## wherein (a) R 1 represents a substantially saturated hydrocarbyl containing from about 20-350 carbon atoms and 0-3 sites of olefinic unsaturation, and (b) Aryl represents an aryl radical or a substituted aryl radical; and (c) the amine has the formula ##STR8## in which R 2 and R 3 (A) each independently represent hydrogen, hydrocarbyl, alicyclic hydrocarbyl or alkylene polyamine hydrocarbyl or (B) together represent the remainder of a heterocyclic amine.
Claim 4
Dependent Claim 94 words
A process for preparing an oil-soluble, nitrogen-containing composition comprising combining an alkyl chlorosulfonate wherein the alkyl portion contains from 1 to 4 carbon atoms, and an olefinically unsaturated hydrocarbon compound containing at least 20 carbon atoms to form alkyl hydrocarbylsulfonate, treating with an alcoholic solution of an alkali metal hydroxide to form the alkali metal hydrocarbylsulfonate, treating said alkali metal hydrocarbylsulfonate with a chlorinating agent to form a hydrocarbylsulfonyl chloride, and combining the hydrocarbylsulfonyl chloride with 0.1 to 15 mols per mol of hydrocarbylsulfonyl chloride, of a nitrogen-containing compound containing at least one--NH function.
Claim 5
Dependent Claim 94 words
A process for preparing an oil-soluble, nitrogen-containing composition comprising combining an alkyl chlorosulfonate wherein the alkyl portion contains from 1 to 4 carbon atoms, and an olefinically unsaturated hydrocarbon compound containing at least 20 carbon atoms to form alkyl hydrocarbylsulfonate, treating with an alcoholic solution of an alkali metal hydroxide to form the alkali metal hydrocarbylsulfonate, treating said alkali metal hydrocarbylsulfonate with a chlorinating agent to form a hydrocarbylsulfonyl chloride, and combining the hydrocarbylsulfonyl chloride with 0.1 to 15 mols per mol of hydrocarbylsulfonyl chloride, of a nitrogen-containing compound containing at least one--NH function.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-10-23 1982-04-24 1982-10-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-10-23 1986-04-24 1986-10-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-10-23 1990-04-24 1990-10-24 $7700.00 Window Closed / Lapsed

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