Abstract Aliphatic hydrocarbon-substituted sulfonic acids, sulfonyl chlorides, amino sulfonic acids, sulfonamides and alkaline earth metal salts of such acids whose hydrocarbon substituent has an average molecular weight in the range of 300 to 200,000 are novel, useful compounds readily prepared through reaction of chlorosulfonic acid with a polymeric hydrocarbon having at least one carbon to carbon double bond as in the liquid to solid polypropene and polybutene or copolymer of two or more C 2 to C 6 unsaturated hydrocarbons having said average molecular weight. Such sulfonic acids, sulfonyl chlorides, amino sulfonic acids, sulfonamides and alkaline earth metal salts of the acid are soluble in hydrocarbon feeds (i.e., gasoline, diesel and heating fuels) and in lubricating oils as are the alkaline earth metal salts of such acids.
An aliphatic hydrocarbon sulfonic acid of the structure: ##EQU12## wherein R is an alkyl hydrocarbon group, R' and R" are alkyl hydrocarbon group of 1 to 5 carbon atoms and the sum of the weights of R, R' and R" is a 300-3000 Mn.
Claim 2
Dependent Claim
44 words
An aliphatic hydrocarbon sulfonic acid of the structure: ##EQU12## wherein R is an alkyl hydrocarbon group, R' and R" are alkyl hydrocarbon group of 1 to 5 carbon atoms and the sum of the weights of R, R' and R" is a 300-3000 Mn.
Claim 3
Dependent Claim
32 words
The sulfonic acid of claim 1 wherein R is polypropyl or polybutyl and R' and R" have 1 carbon atom when R is polypropyl or 2 carbon atoms when R is polybutyl.
Claim 4
Dependent Claim
95 words
The method of preparing the aliphatic sulfonic acid of the structure ##EQU13## wherein the sum of the weights of R, R' and R" is 300 to 3000 Mn, R is an alkyl hydrocarbon group and R' and R" are alkyl hydrocarbon groups of 1 to 5 carbon atoms, which comprises reacting at a maximum temperature of 90°F. substantially equal molecular proportions of chlorosulfonic acid and a polymeric hydrocarbon of the formula ##EQU14## wherein R, R' and R" are the alkyl hydrocarbon groups of the carbon contents and molecular weight sum as defined in claim 1.
Claim 5
Dependent Claim
14 words
The method of claim 3 wherein the polymeric hydrocarbon is a polypropene or polybutene.