US4118201A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Production of low sulfur fuels from coal
Assignee: Mobil Oil AS
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Filing: 1977-07-08
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Granted: 1978-10-03
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Expires: 1997-07-08
Abstract
Abstract A general method for producing low-sulfur gas and solid fuel is disclosed. Such method involves partial gasification of coal, using steam and an oxygen-containing gas, to produce low-B.t.u. fuel which can be used as a feedstock for power plants and industrial boilers. Also disclosed is a method for simultaneously producing low-sulfur gas, liquid, and solid fuels from coal in a single reaction vessel using a multi-stage fluidized gasification and desulfurization system. Synthesis gas produced in a first stage gas generator by reaction of steam, an oxygen-containing gas, and auxiliary carbonaceous fuel, is reacted with high-sulfur coal in a second stage desulfurization unit forming a solid phase consisting of low-sulfur fuel and a fluid phase consisting of sulfur-containing gaseous and liquid fuels. After disengagement of solid and fluid phases present in the second stage reaction zone, a solid fuel of reduced sulfur content is recovered.
Inventors
- 👤 Tsoung-Yuan Yan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 21:58
CPC Classifications
C; C10; C10L; C10L9/00
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
212 words
A process for desulfurizing sulfur-containing solid carbonaceous fuel in the form of pulverized coal in a multi-stage fluidized reaction system comprising a gas generating zone, a desulfurization zone and a gas-solids separating zone, the generating and desulfurization zones having operating conditions dependent upon one another, to produce a maximum amount of solid, low-sulfur carbonaceous fuel which is useful as a direct supply of fuel for power plants or industrial boilers which utilize low B.T.U. fuel comprising the steps: (a) reacting an oxygen-containing gas, steam, and auxiliary carbonaceous fuel in a fluidized state at a temperature of 1800° to 3000° F. in a gas generating zone to form synthesis gas comprising hydrogen and carbon monoxide; (b) continuously passing heated synthesis gas upwardly into a desulfurization zone and introducing into said zone fresh pulverized coal solids; (c) maintaining the coal solids in said zone in a fluidized state at a temperature in the range of 1100° F. to 1700° F. under a pressure of about 100 to 1000 psig for a period of time sufficient to form hydrogen sulfide and thereby reduce the sulfur content of the coal to below about 1 percent by weight, and (d) disengaging sulfur-containing gases from the desulfurization zone and recovering a solid fuel product of reduced sulfur content.
Claim 2
Dependent Claim
212 words
A process for desulfurizing sulfur-containing solid carbonaceous fuel in the form of pulverized coal in a multi-stage fluidized reaction system comprising a gas generating zone, a desulfurization zone and a gas-solids separating zone, the generating and desulfurization zones having operating conditions dependent upon one another, to produce a maximum amount of solid, low-sulfur carbonaceous fuel which is useful as a direct supply of fuel for power plants or industrial boilers which utilize low B.T.U. fuel comprising the steps: (a) reacting an oxygen-containing gas, steam, and auxiliary carbonaceous fuel in a fluidized state at a temperature of 1800° to 3000° F. in a gas generating zone to form synthesis gas comprising hydrogen and carbon monoxide; (b) continuously passing heated synthesis gas upwardly into a desulfurization zone and introducing into said zone fresh pulverized coal solids; (c) maintaining the coal solids in said zone in a fluidized state at a temperature in the range of 1100° F. to 1700° F. under a pressure of about 100 to 1000 psig for a period of time sufficient to form hydrogen sulfide and thereby reduce the sulfur content of the coal to below about 1 percent by weight, and (d) disengaging sulfur-containing gases from the desulfurization zone and recovering a solid fuel product of reduced sulfur content.
Claim 3
Dependent Claim
23 words
The process of claim 1 wherein the residence time of the solids in the desulfurization zone is from 10 seconds to 100 minutes.
Claim 4
Dependent Claim
12 words
The process of claim 1 wherein the auxiliary carbonaceous fuel is coal.
Claim 5
Dependent Claim
42 words
The process of claim 3 wherein the temperature in the synthesis gas generating zone is about 100° F. higher than the ash fusion temperature of the auxiliary coal fuel and molten ash is discharged from the synthesis gas generating zone as slag.
Claim 6
Dependent Claim
46 words
The process of claim 4 wherein the fluid phase disengaged from the solid and fluid phases present in the fluidized reaction zone is cooled to recover heat and to separate sulfur-containing gaseous and liquid fuels which fuels are purified to produce a substantially sulfur-free liquid fuel.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-10-02 | 1982-04-03 | 1982-10-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-10-02 | 1986-04-03 | 1986-10-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-10-02 | 1990-04-03 | 1990-10-03 | $7700.00 | Window Closed / Lapsed |