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Catalysts for isocyanate polyaddition reactions

Assignee: Bayer AG
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Filing: 1977-01-07
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Granted: 1978-09-19
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Expires: 1997-01-07
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Abstract

Abstract This invention relates to new catalyst combinations having improved catalytic activity for isocyanate polyaddition reactions. The catalysts are combinations of known metal catalysts with aromatic compounds which contain at least one nitrogen atom as a hetero atom and have at least one primary amino group in the ortho- or para-position to the hetero atom. Preferred aromatic compounds include ##STR1## wherein R 1 , R 2 , R 3 and R 4 which may be the same or different, each represent a hydrogen atom, an aliphatic hydrocarbon group having from 1 to 6 carbon atoms or an aromatic hydrocarbon group having from 6 to 12 carbon atoms or two of the groups R 1 to R 4 represent a condensed aromatic ring.

Inventors

  • 👤 Holger Meyborg

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 12:58
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/16; C08G18/161; C08G18/163; C08G18/28; C08G18/2805; C08G18/285; C08G18/2865

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 199 words
Catalyst combinations comprising: (A) 1 mol of a metal compound corresponding to the following formula: Me X.sub.n Y.sub.m, wherein Me represents a metal having a valency of (n+m), X represents an aliphatic hydrocarbon group having from 1 to 18 carbon atoms, an aromatic hydrocarbon group having from 6 to 10 carbon atoms, or an araliphatic hydrocarbon group having from 7 to 15 carbon atoms, Y represents an enolate group having from 5 to 18 carbon atoms or an aliphatic carboxylate group having from 2 to 18 carbon atoms, n represents an integer of from 0 to 2 and m represents an integer of from 0 to 4 such that the sum of (n + m) is from 2 to 4, and (B) from about 0.5 to about 5 mols of a primary amine corresponding to the following general formula: ##STR8## wherein R 1 , R 2 , and R 3 , which may be the same or different, each represent a hydrogen atom, an aliphatic hydrocarbon group having from 1 to 6 carbon atoms, an aromatic group having from 6 to 12 carbon atoms, or two of the groups R 1 to R 3 represent a condensed aromatic ring.
Claim 2
Dependent Claim 199 words
Catalyst combinations comprising: (A) 1 mol of a metal compound corresponding to the following formula: Me X.sub.n Y.sub.m, wherein Me represents a metal having a valency of (n+m), X represents an aliphatic hydrocarbon group having from 1 to 18 carbon atoms, an aromatic hydrocarbon group having from 6 to 10 carbon atoms, or an araliphatic hydrocarbon group having from 7 to 15 carbon atoms, Y represents an enolate group having from 5 to 18 carbon atoms or an aliphatic carboxylate group having from 2 to 18 carbon atoms, n represents an integer of from 0 to 2 and m represents an integer of from 0 to 4 such that the sum of (n + m) is from 2 to 4, and (B) from about 0.5 to about 5 mols of a primary amine corresponding to the following general formula: ##STR8## wherein R 1 , R 2 , and R 3 , which may be the same or different, each represent a hydrogen atom, an aliphatic hydrocarbon group having from 1 to 6 carbon atoms, an aromatic group having from 6 to 12 carbon atoms, or two of the groups R 1 to R 3 represent a condensed aromatic ring.
Claim 3
Dependent Claim 52 words
The catalyst of claim 1, wherein R 1 , R 2 and R 3 all represent hydrogen, or only one of R 1 to R 3 represents methyl and the other represent hydrogen or only two of R 1 to R 3 represent a condensed aromatic ring and the other represents hydrogen.
Claim 4
Dependent Claim 23 words
The catalyst of claim 1, wherein the metal is from Ib, IIb, VIII groups or IVa group of metals of the Periodic Table.
Claim 5
Dependent Claim 21 words
The catalyst of claim 1, wherein from 1 to 3 mols of compound (B) is used per mol of compound (A).
Claim 6
Dependent Claim 29 words
The catalyst of claim 3, wherein the metal is selected from the group consisting of trivalent iron, divalent nickel, divalent zinc, divalent manganese, divalent tin and tetra valent tin.

References Cited (Backward Citations)

DE1950262U Cited
US3769244A Cited
US3814707A Cited
US3635906A Cited
US3565875A Cited
US3668146A Cited
US3899443A Cited
US4006124A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-09-18 1982-03-20 1982-09-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-09-18 1986-03-20 1986-09-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-09-18 1990-03-20 1990-09-19 $7700.00 Window Closed / Lapsed

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