Patent US4115320A successfully refreshed from Google Patents.
US4115320A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Catalysts for isocyanate polyaddition reactions
Assignee: Bayer AG
•
Filing: 1977-01-07
•
Granted: 1978-09-19
•
Expires: 1997-01-07
Abstract
Abstract This invention relates to new catalyst combinations having improved catalytic activity for isocyanate polyaddition reactions. The catalysts are combinations of known metal catalysts with aromatic compounds which contain at least one nitrogen atom as a hetero atom and have at least one primary amino group in the ortho- or para-position to the hetero atom. Preferred aromatic compounds include ##STR1## wherein R 1 , R 2 , R 3 and R 4 which may be the same or different, each represent a hydrogen atom, an aliphatic hydrocarbon group having from 1 to 6 carbon atoms or an aromatic hydrocarbon group having from 6 to 12 carbon atoms or two of the groups R 1 to R 4 represent a condensed aromatic ring.
Inventors
- 👤 Holger Meyborg
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 12:58
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/16; C08G18/161; C08G18/163; C08G18/28; C08G18/2805; C08G18/285; C08G18/2865
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
199 words
Catalyst combinations comprising: (A) 1 mol of a metal compound corresponding to the following formula: Me X.sub.n Y.sub.m, wherein Me represents a metal having a valency of (n+m), X represents an aliphatic hydrocarbon group having from 1 to 18 carbon atoms, an aromatic hydrocarbon group having from 6 to 10 carbon atoms, or an araliphatic hydrocarbon group having from 7 to 15 carbon atoms, Y represents an enolate group having from 5 to 18 carbon atoms or an aliphatic carboxylate group having from 2 to 18 carbon atoms, n represents an integer of from 0 to 2 and m represents an integer of from 0 to 4 such that the sum of (n + m) is from 2 to 4, and (B) from about 0.5 to about 5 mols of a primary amine corresponding to the following general formula: ##STR8## wherein R 1 , R 2 , and R 3 , which may be the same or different, each represent a hydrogen atom, an aliphatic hydrocarbon group having from 1 to 6 carbon atoms, an aromatic group having from 6 to 12 carbon atoms, or two of the groups R 1 to R 3 represent a condensed aromatic ring.
Claim 2
Dependent Claim
199 words
Catalyst combinations comprising: (A) 1 mol of a metal compound corresponding to the following formula: Me X.sub.n Y.sub.m, wherein Me represents a metal having a valency of (n+m), X represents an aliphatic hydrocarbon group having from 1 to 18 carbon atoms, an aromatic hydrocarbon group having from 6 to 10 carbon atoms, or an araliphatic hydrocarbon group having from 7 to 15 carbon atoms, Y represents an enolate group having from 5 to 18 carbon atoms or an aliphatic carboxylate group having from 2 to 18 carbon atoms, n represents an integer of from 0 to 2 and m represents an integer of from 0 to 4 such that the sum of (n + m) is from 2 to 4, and (B) from about 0.5 to about 5 mols of a primary amine corresponding to the following general formula: ##STR8## wherein R 1 , R 2 , and R 3 , which may be the same or different, each represent a hydrogen atom, an aliphatic hydrocarbon group having from 1 to 6 carbon atoms, an aromatic group having from 6 to 12 carbon atoms, or two of the groups R 1 to R 3 represent a condensed aromatic ring.
Claim 3
Dependent Claim
52 words
The catalyst of claim 1, wherein R 1 , R 2 and R 3 all represent hydrogen, or only one of R 1 to R 3 represents methyl and the other represent hydrogen or only two of R 1 to R 3 represent a condensed aromatic ring and the other represents hydrogen.
Claim 4
Dependent Claim
23 words
The catalyst of claim 1, wherein the metal is from Ib, IIb, VIII groups or IVa group of metals of the Periodic Table.
Claim 5
Dependent Claim
21 words
The catalyst of claim 1, wherein from 1 to 3 mols of compound (B) is used per mol of compound (A).
Claim 6
Dependent Claim
29 words
The catalyst of claim 3, wherein the metal is selected from the group consisting of trivalent iron, divalent nickel, divalent zinc, divalent manganese, divalent tin and tetra valent tin.
References Cited (Backward Citations)
DE1950262U
Cited
US3769244A
Cited
US3814707A
Cited
US3635906A
Cited
US3565875A
Cited
US3668146A
Cited
US3899443A
Cited
US4006124A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-09-18 | 1982-03-20 | 1982-09-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-09-18 | 1986-03-20 | 1986-09-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-09-18 | 1990-03-20 | 1990-09-19 | $7700.00 | Window Closed / Lapsed |