Pigmentary bright primrose yellow monoclinic bismuth vanadate and processes for the preparation thereof

Claim 2

A pigmentary bright primrose yellow monoclinic bismuth vanadate.

Claim 3

The bismuth vanadate of claim 1 which when uniformly mixed with 90 weight percent barium sulfate exhibits, in the visible spectrum, from 450 to 525 nm, an increase of at least about 65 reflectance units on a scale in which the barium sulfate exhibits a reflectance of 100 units over the entire visible spectrum.

Claim 4

The bismuth vanadate of claim 2 wherein the increase in powder reflectance is at least about 70 units.

Claim 5

The bismuth vanadate of claim 1 wherein the lightfastness in paint is such as to give a reflectance drop of less than about 11 percent in 44 hours in Fade-Ometer® exposure.

Claim 6

The bismuth vanadate of claim 1 wherein the lightfastness in paint is such as to give a reflectance drop of less than about 7 percent in 44 hours of Fade-Ometer® exposure.

Claim 7

The bismuth vanadate of claim 1 wherein the intensity in paint is such as to give a green filter reflectance of at least about 60 percent.

Claim 8

The bismuth vanadate of claim 1 wherein the intensity in paint is such as to give a green filter reflectance of at least about 64 percent.

Claim 9

The bismuth vanadate of claim 2 wherein the lightfastness in paint is such as to give a reflectance drop of less than about 7% in 44 hours of Fade-Ometer® exposure, and the intensity in paint is such as to give a green filter reflectance of at least about 60%.

Claim 10

The bismuth vanadate of claim 3 wherein the lightfastness in paint is such as to give a reflectance drop of less than about 7% in 44 hours of Fade-Ometer® exposure, and the intensity in paint is such as to give a green filter reflectance of at least about 64%.

Claim 11

A process for preparing a pigmentary bright primrose yellow monoclinic bismuth vanadate comprising: A. mixing a solution of Bi(NO 3 ) 3 .5H 2 O in nitric acid with a solution of alkali vanadate in an aqueous base selected from sodium hydroxide and potassium hydroxide, to precipitate a bismuth vanadate gel suspended in a solution containing dissolved alkali nitrate, wherein the molar ratio of Bi 3+ to VO 4 3- is from about 0.95:1.00 to 1.10:1.00, and wherein the normalities of the acid and base solutions are adjusted prior to mixing so that the pH of the mixture will be from about 1.0-8.0; B. adjusting the pH of the suspension to about 1.9 to 3.6; C. removing the gel from the suspension; D. washing the gel with water until it contains about 20 weight percent or less alkali nitrate, based on the theoretical yield of bismuth vanadate; and E. calcining the gel at a temperature of from about 200°-500° C. for about 0.4-3 hours.

Claim 12

A process for preparing a pigmentary bright primrose yellow monoclinic bismuth vanadate comprising: A. mixing a solution of Bi(NO 3 ) 3 .5H 2 O in nitric acid with a solution of alkali vanadate in an aqueous base selected from sodium hydroxide and potassium hydroxide, to precipitate a bismuth vanadate gel suspended in a solution containing dissolved alkali nitrate, wherein the molar ratio of Bi 3+ to VO 4 3- is from about 0.95:1.00 to 1.10:1.00, and wherein the normalities of the acid and base solutions are adjusted prior to mixing so that the pH of the mixture will be from about 1.0-8.0; B. adjusting the pH of the suspension to about 1.9 to 3.6; C. removing the gel from the suspension; D. washing the gel with water until it contains about 20 weight percent or less alkali nitrate, based on the theoretical yield of bismuth vanadate; and E. calcining the gel at a temperature of from about 200°-500° C. for about 0.4-3 hours.

Claim 13

The process of claim 10 wherein the molar ratio of Bi 3+ to VO 4 3- is from about 0.98:1.00 to 1.02:1.00.

Claim 14

The process of claim 10 wherein the pH in Step B is adjusted to about 3.3 to 3.5.

Claim 15

The process of claim 10 wherein the gel is washed with water until it contains about 5-7 weight percent alkali nitrate.

Claim 16

The process of claim 10 wherein the gel is calcined at about 380°-460° C. for about one hour.

Claim 17

The process of claim 10 wherein the molar ratio of Bi 3+ to VO 4 3- is about 0.98:1.00 to 1.02:1.00, the pH of the mixture will be about 1.5 to 2.0, the pH in Step B is adjusted to a pH of from about 3.3-3.5, the gel is washed with water until it contains about 5-7% alkali nitrate, and the gel is calcined at a temperature of from about 380°-460° C. for about one hour.

Claim 18

The process of claim 15 in which the Na 3 VO 4 is dissolved in aqueous sodium hydroxide.

Claim 19

A bismuth vanadate gel suitable for conversion to pigmentary monoclinic bismuth vanadate prepared by the process of: A. mixing a solution of Bi(NO 3 ) 3 .5H 2 O in nitric acid with a solution of Na 3 VO 4 in sodium hydroxide, to precipitate a bismuth vanadate gel suspended in a solution containing dissolved sodium nitrate, wherein the molar ratio of Bi 3+ to VO 4 3- is from about 0.95:1.00 to 1.10:1.00, and wherein the normalities of the acid and base solutions are adjusted prior to mixing so that the pH of the mixture will be from about 1.0 to 8.0; B. adjusting the pH of the suspension to about 1.9 to 3.6; C. removing the gel from the suspension; and D. washing the gel with water until it contains about 20 weight percent or less sodium nitrate, based on the theoretical yield of bismuth vanadate.

Claim 20

A bismuth vanadate gel suitable for conversion to pigmentary monoclinic bismuth vanadate prepared by the process of: A. mixing a solution of Bi(NO 3 ) 3 .5H 2 O in nitric acid with a solution of Na 3 VO 4 in sodium hydroxide, to precipitate a bismuth vanadate gel suspended in a solution containing dissolved sodium nitrate, wherein the molar ratio of Bi 3+ to VO 4 3- is from about 0.95:1.00 to 1.10:1.00, and wherein the normalities of the acid and base solutions are adjusted prior to mixing so that the pH of the mixture will be from about 1.0 to 8.0; B. adjusting the pH of the suspension to about 1.9 to 3.6; C. removing the gel from the suspension; and D. washing the gel with water until it contains about 20 weight percent or less sodium nitrate, based on the theoretical yield of bismuth vanadate.

Claim 21

The product produced by the process of claim 17 in which excess water remaining at the conclusion of Step D is removed.