Patent US4113687A successfully refreshed from Google Patents.
US4113687A
Expired / Lapsed
US
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Process for preparing latex
Assignee: SINTEF AS
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Filing: 1977-08-16
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Granted: 1978-09-12
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Expires: 1997-08-16
Abstract
Abstract A process for preparing a latex by efficiently homogenizing an aqueous mixture containing an emulsifier and a water-insoluble solvent for the monomer(s) to be polymerized, adding monomer and if desired further water to the homogenized mixture and also a water-soluble polymerization initiator. Instead of a water-soluble polymerization initiator an oil-soluble polymerization may be used having sufficient solubility to diffuse through the aqueous phase into the drops of water-insoluble solvent and monomer.
Inventors
- 👤 John Ugelstad
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 11:40
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/12; C08F2/16
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
158 words
A process for preparing a latex which comprises homogenizing under pressure an aqueous mixture containing an emulsifier and a water-insoluble solvent for the vinylic monomer(s) to be polymerized, said solvent having a water-solubility at 25° C. of <10 -3 g/l H 2 O to form a stable preemulsion of said solvent in water, whereby the increased pressure of homogenization resulting in smaller but more drops in said preemulsion and consequently in the final latex, and then adding to said preemulsion the monomer(s) to be polymerized and optionally additional water, together with or followed by a polymerization initiator selected from water-soluble polymerization initiators and oil-soluble polymerization initiators having sufficient water solubility to diffuse through the aqueous phase into the drops formed by diffusion of the monomer(s) into said solvent, the weight ratio of emulsifier and solvent to total water being 1:500-1:50 and 1:1000-3:100, respectively, and the weight ratio of emulsifier and solvent to monomer(s) being 1:500-1:30 and 1:1000-1:20, respectively.
Claim 2
Dependent Claim
158 words
A process for preparing a latex which comprises homogenizing under pressure an aqueous mixture containing an emulsifier and a water-insoluble solvent for the vinylic monomer(s) to be polymerized, said solvent having a water-solubility at 25° C. of <10 -3 g/l H 2 O to form a stable preemulsion of said solvent in water, whereby the increased pressure of homogenization resulting in smaller but more drops in said preemulsion and consequently in the final latex, and then adding to said preemulsion the monomer(s) to be polymerized and optionally additional water, together with or followed by a polymerization initiator selected from water-soluble polymerization initiators and oil-soluble polymerization initiators having sufficient water solubility to diffuse through the aqueous phase into the drops formed by diffusion of the monomer(s) into said solvent, the weight ratio of emulsifier and solvent to total water being 1:500-1:50 and 1:1000-3:100, respectively, and the weight ratio of emulsifier and solvent to monomer(s) being 1:500-1:30 and 1:1000-1:20, respectively.
Claim 3
Dependent Claim
31 words
A process according to claim 1, wherein said water-insoluble solvent is capable of dissolving the monomer(s) in an amount of at least 100 times its own weight under the reaction conditions.
Claim 4
Dependent Claim
21 words
A process according to claim 2, wherein said water-insoluble solvent comprises an optionally halogenated alkane having at least 10 carbon atoms.
Claim 5
Dependent Claim
26 words
A process according to claim 1 wherein vinyl chloride is employed as monomer, and said water-insoluble solvent comprises a plasticiser or a stabiliser for polyvinyl chloride.
Claim 6
Dependent Claim
16 words
A process according to claim 4, wherein said plasticiser comprises a phthalate, phosphate, adipate or sebacate.
Claim 7
Dependent Claim
13 words
A process according to claim 4, wherein said plasticiser comprises an epoxy compound.
Claim 8
Dependent Claim
25 words
A process according to claim 1, wherein said water-insoluble solvent comprises a water-insoluble vinyl compound which will copolymerise with the main monomer during the polymerisation.
Claim 9
Dependent Claim
26 words
A process according to claim 7, wherein a vinyl ether, a vinyl ester, an acrylate or methacrylate or a substituted styrene is used as vinyl compound.
Claim 10
Dependent Claim
33 words
A process according to claim 8, wherein said vinyl ether comprises a higher vinyl ether of the formula CH 2 ═CHOR in which R is an alkyl group having at least 15 C-atoms.
Claim 11
Dependent Claim
28 words
A process according to claim 8, wherein said vinyl ester has the formula CH 2 ═CHOOCR in which R is an alkyl group having at least 15 C-atoms.
Claim 12
Dependent Claim
32 words
A process according to claim 8, wherein said acrylate or methacrylate has the formula CH 2 ═CH--COOR or ##STR3## respectively, in which R is an alkyl group having at least 15 C-atoms.
Claim 13
Dependent Claim
26 words
A process according to claim 8, wherein said substituted styrene has the formula ##STR4## in which R is an alkyl group having at least 6 C-atoms.
Claim 14
Dependent Claim
38 words
A process according to claim 1 wherein said aqueous mixture which is homogenised additionally comprises a further substance which is partly water-soluble, the mixture of the water-insoluble and the partly water-soluble substance being a solvent for the monomer.
Claim 15
Dependent Claim
29 words
A process according to claim 13, wherein a latex of vinyl chloride is prepared and wherein said partly water-soluble substance comprises a plasticiser or a stabiliser for polyvinyl chloride.
Claim 16
Dependent Claim
14 words
A process according to claim 14, wherein said plasticiser comprises dibutylphthalate, dioctylphthalate or tricresylphosphate.
Claim 17
Dependent Claim
30 words
A process according to claim 13, wherein said partly water-soluble substance comprises a portion of the main monomer or a comonomer which will copolymerise with the main monomer upon polymerisation.
Claim 18
Dependent Claim
20 words
A process according to claim 16, wherein vinyl chloride is the main monomer, and said comonomer comprises a vinyl ester.
Claim 19
Dependent Claim
15 words
A process according to claim 17, wherein said comonomer comprises vinyl acetate or vinyl propionate.
Claim 20
Dependent Claim
49 words
A process according to claim 1 wherein from 1 to 30 parts by weight of said water-insoluble substance is homogenised in 25 to 500 parts by weight of water, whereafter the water is made up to 1000 parts and 600 to 1000 parts by weight of monomer are added.
Claim 21
Dependent Claim
22 words
A process according to claim 13 wherein from 5 to 200 parts by weight of said partly water-soluble substance are also homogenised.
Claim 22
Dependent Claim
14 words
The process of claim 1, wherein said oil-soluble initiator is azo-iso butyric acid nitrile.
References Cited (Backward Citations)
US2575553A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-09-11 | 1982-03-13 | 1982-09-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-09-11 | 1986-03-13 | 1986-09-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-09-11 | 1990-03-13 | 1990-09-12 | $7700.00 | Window Closed / Lapsed |