Patent US4112190A successfully refreshed from Google Patents.
US4112190A
Expired / Lapsed
US
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Metallized plastic molding
Assignee: Mitsubishi Chemical Corp
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Filing: 1977-06-16
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Granted: 1978-09-05
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Expires: 1997-06-16
Abstract
Abstract A metallized plastic molding comprises a plastic substrate, a primer layer having a gel percentage of at least 80% and a swelling degree of 20% or less deposited on said substrate and a metallic film deposited on the primer layer. The metallized plastic molding is prepared by coating a plastic substrate with a primer forming material containing at least one compound having a molecular weight of 150 - 2000 and containing at least two polymerizable unsaturated groups in one molecule, curing the primer forming material so that it has a gel percentage of at least 80% and a swelling degree of 20% or less to form a primer layer and then depositing a metallic film layer by a dry type method on the primer layer.
Inventors
- 👤 Mitsuo Sato
- 👤 Norio Miyagawa
- 👤 Juichi Kobayashi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 10:45
CPC Classifications
C; C23; C23C; C23C14/00; C23C14/06; C23C14/14; C23C14/20; B; B05; B05D; B05D5/00; B05D5/06; B05D5/067; C08; C08J; C08J7/00; C08J7/04; C08J7/042; C08J7/0423; C08J7/0427; C08J7/043; C08J7/046; B05D2201/00; C08J2355/00; C08J2355/02; C08J2433/00; C08J2433/04; C08J2463/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
115 words
A metallized plastic molding, which comprises: (a) a plastic substrate, (b) a primer layer having a gel percentage of at least 80% and a swelling degree of not more than 20%, which is formed by curing a deposited primer forming material which comprises a mixture of a compound (A) having a molecular weight of at least 150 and less than 450 and containing at least two polymerizable unsaturated groups in one molecule and a compound (B) having a molecular weight of 450-2000 and containing at least two polymerizable unsaturated groups in one molecule in a weight ratio (A)/(B) of 1/9-9/1, on a surface of said substrate and (C) a metallic film on said primer layer.
Claim 2
Dependent Claim
115 words
A metallized plastic molding, which comprises: (a) a plastic substrate, (b) a primer layer having a gel percentage of at least 80% and a swelling degree of not more than 20%, which is formed by curing a deposited primer forming material which comprises a mixture of a compound (A) having a molecular weight of at least 150 and less than 450 and containing at least two polymerizable unsaturated groups in one molecule and a compound (B) having a molecular weight of 450-2000 and containing at least two polymerizable unsaturated groups in one molecule in a weight ratio (A)/(B) of 1/9-9/1, on a surface of said substrate and (C) a metallic film on said primer layer.
Claim 3
Dependent Claim
35 words
The metallized plastic molding of claim 1, wherein said compound (A) is the condensation product of a compound having at least two hydroxyl groups in one molecule and a polymerizable monomer having a carboxyl group.
Claim 4
Dependent Claim
40 words
The metallized plastic molding of claim 1, wherein said compound (B) is the addition product of a compound having at least two epoxy groups in one molecule and a polymerizable monomer having carboxyl groups prepared by a ring-opening esterification reaction.
Claim 5
Dependent Claim
68 words
The metallized plastic molding of claim 1, wherein the primer layer is formed by curing a primer forming material comprising a mixture of at least one compound having a molecular weight of 150-2000 and containing at least two polymerizable unsaturated groups in one molecule and a leveling agent which is a surfactant in an amount of 0.01-10% by weight of the total amount of said primer forming material.
Claim 6
Dependent Claim
76 words
The metallized plastic molding of claim 1, wherein the primer layer is formed by curing a primer forming material comprising a mixture of at least one compound having a molecular weight of 150-2000 and containing at least two polymerizable unsaturated groups in one molecule and a leveling agent selected from the group consisting of fluorine containing monomers and silicone compounds in an amount of 0.01-10% by weight of the total amount of said primer forming material.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-09-04 | 1982-03-06 | 1982-09-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-09-04 | 1986-03-06 | 1986-09-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-09-04 | 1990-03-06 | 1990-09-05 | $7700.00 | Window Closed / Lapsed |