Patent US4111860A successfully refreshed from Google Patents.
US4111860A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for the productions of multi-cellular stretched articles
Assignee: BXL Plastics Ltd
•
Filing: 1974-10-29
•
Granted: 1978-09-05
•
Expires: 1994-10-29
Abstract
Abstract A process for the manufacture of a multicellular stretched sheet which comprises melt compounding a thermoplastic matrix polymer and an additive comprising a polymeric or non-polymeric organic compound or a metal salt of an organic acid, forming the blend into a shaped article and stretching the article at a temperature within the normal orientation temperature of the matrix polymer and below the glass-transition temperature of the polymeric additive or below the melting or softening point of the non-polymeric additive.
Inventors
- 👤 James Jack
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 18:26
CPC Classifications
D; D01; D01D; D01D5/00; D01D5/24; D01D5/247; B; B29; B29C; B29C55/00; B29C55/02; B29C67/00; B29C67/20; B29C67/202; C; C08; C08J; C08J9/00; D01D5/12; D01F; D01F1/00; D01F1/02; D01F1/08; D01F1/10; D21; D21H; D21H13/00; Y; Y10; Y10S; Y10S264/00; Y10S264/17
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
257 words
A process for the production of a multi-cellular stretched article, which process comprises the steps of forming a composition comprising mixing a melted blend of a stretchable thermoplastic organic polymer matrix and an additive which reduces the density of the resulting article and is non-molten or non-softened in the normal orientation temperature range of the matrix polymer, at a temperature at which the matrix polymer and additive are molten, forming an article from said composition, and then stretching the article at a temperature which is within the normal orientation temperature range for the matrix polymer so that micro-voids are formed in the matrix polymer, said additive constituting from about 2 to 50% by weight of the total weight of the blend, being at least partially incompatible with the matrix polymer in the concentration employed when and at the temperature at which said article is subsequently stretched, being selected from the group consisting of organic polymeric, organic acids, and those metal salts of organic acids other than metal resinates and rosin esters, except when the matrix polymer is a crystallizable polymer other than an olefin, in which case said additive is selected from the group consisting of organic acids and their metal salts other than metal resinates and rosin esters, the temperature at which said article is stretched being below the glass-transition temperature of said additive when said additive is a polymer, and below the melting or softening point of the additive when said additive is an organic acid, organic derivative or a modified or unmodified natural product.
Claim 2
Dependent Claim
257 words
A process for the production of a multi-cellular stretched article, which process comprises the steps of forming a composition comprising mixing a melted blend of a stretchable thermoplastic organic polymer matrix and an additive which reduces the density of the resulting article and is non-molten or non-softened in the normal orientation temperature range of the matrix polymer, at a temperature at which the matrix polymer and additive are molten, forming an article from said composition, and then stretching the article at a temperature which is within the normal orientation temperature range for the matrix polymer so that micro-voids are formed in the matrix polymer, said additive constituting from about 2 to 50% by weight of the total weight of the blend, being at least partially incompatible with the matrix polymer in the concentration employed when and at the temperature at which said article is subsequently stretched, being selected from the group consisting of organic polymeric, organic acids, and those metal salts of organic acids other than metal resinates and rosin esters, except when the matrix polymer is a crystallizable polymer other than an olefin, in which case said additive is selected from the group consisting of organic acids and their metal salts other than metal resinates and rosin esters, the temperature at which said article is stretched being below the glass-transition temperature of said additive when said additive is a polymer, and below the melting or softening point of the additive when said additive is an organic acid, organic derivative or a modified or unmodified natural product.
Claim 3
Dependent Claim
24 words
The process of claim 1, wherein the matrix material is an olefin polymer or copolymer, a polyester, a polyamide, polystyrene, or a vinyl polymer.
Claim 4
Dependent Claim
13 words
The process of claim 1, wherein the matrix material is a crystallizable polymer.
Claim 5
Dependent Claim
12 words
The process of claim 3, wherein the matrix material is a polyolefin.
Claim 6
Dependent Claim
17 words
The process of claim 4, wherein he matrix material is an ethylene or propylene polymer or copolymer.
Claim 7
Dependent Claim
14 words
The process of claim 5, wherein the matrix material is a high density polyethylene.
Claim 8
Dependent Claim
31 words
The process of claim 1 wherein the additive is a polymeric additive and is a polycarbonate, polyvinyl carbazole, polyvinyl acetal, a phenoxy resin, a phenol-formaldehyde resin or a non-linear polyester resin.
Claim 9
Dependent Claim
50 words
The process of claim 1 wherein the additive is a non-polymeric additive and is substituted or unsubstituted benzoic acid, adipic acid, tartaric acid, itaconic acid or a metal salt of such an acid, a benzoic acid derivative, isonicotinic acid hydrazide, lactose, trimellitic anhydride or a modified or unmodified natural product.
Claim 10
Dependent Claim
16 words
The process of claim 1 in which the composition also contains a filler and/or a pigment.
Claim 11
Dependent Claim
20 words
The process of claim 9, wherein the filler is calcium carbonate or diatomaceous earth and/or the pigment is titanium dioxide.
Claim 12
Dependent Claim
24 words
The process of claim 9, where the filler or pigment has a particle size of 1 to 10 μ, preferably 2 to 8 μ.
Claim 13
Dependent Claim
29 words
The process of claim 9, wherein the filler and/or pigment is present in an amount of up to 30% by weight calculated on the total weight of the composition.
Claim 14
Dependent Claim
23 words
The process claim 17, wherein the additive is present in an amount of from 5 to 25% by weight, calculated on the blend.
Claim 15
Dependent Claim
18 words
The process of claim 1, wherein the shaped article is a fiber, filament, tape, sheet, film or tube.
Claim 16
Dependent Claim
12 words
The multicellular stretched article produced by a process as of claim 1.
Claim 17
Dependent Claim
10 words
A synthetic paper produced by the process of claim 1.
References Cited (Backward Citations)
US3775521A
Cited
US3790435A
Cited
US3783093A
Cited
US3840625A
Cited
US3741860A
Cited
US3765999A
Cited
US3725520A
Cited
US3694399A
Cited
US3903234A
Cited
US4067938A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-09-04 | 1982-03-06 | 1982-09-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-09-04 | 1986-03-06 | 1986-09-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-09-04 | 1990-03-06 | 1990-09-05 | $7700.00 | Window Closed / Lapsed |