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Polymers stabilized by esters of piperidinols

Assignee: BASF Corp
•
Filing: 1976-11-15
•
Granted: 1978-08-29
•
Expires: 1996-11-15
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Abstract

Abstract New alkyl substituted p-hydroxy aryl esters and alkyl substituted p-hydroxy aralkyl esters of 2,2,6,6-tetrasubstituted piperidin-4-ols are used as stabilizers for organic materials, especially for polymers.

Inventors

  • 👤 Brian Holt
  • 👤 Donald R. Randell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 20:29
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3432; C08K5/3435; C07; C07D; C07D211/00; C07D211/04; C07D211/06; C07D211/36; C07D211/40; C07D211/44; C07D211/46

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 143 words
A composition of matter stabilized against ultraviolet deterioration which comprises a synthetic organic polymer normally subject to ultraviolet deterioration containing from 0.1% to 2% by weight of the polymer of a stabilizing compound of the formula ##STR19## wherein A is --CH 2 --, --CH 2 CH 2 -- or ##STR20## R 1 and R 2 are the same or different and each is a straight- or branched-chain alkyl group having from 1 to 6 carbon atoms, or 1-methylcyclohexyl or α,α-dimethylbenzyl, R 3 and R 4 ar the same or different and each is an alkyl group having from 1 to 12 carbon atoms or R 3 and R 4 together with the carbon atom to which they are bound form a saturated alicyclic residue having from 5 to 8 carbon atoms or the group of formula: ##STR21## and n is 0 or 1.
Claim 2
Dependent Claim 143 words
A composition of matter stabilized against ultraviolet deterioration which comprises a synthetic organic polymer normally subject to ultraviolet deterioration containing from 0.1% to 2% by weight of the polymer of a stabilizing compound of the formula ##STR19## wherein A is --CH 2 --, --CH 2 CH 2 -- or ##STR20## R 1 and R 2 are the same or different and each is a straight- or branched-chain alkyl group having from 1 to 6 carbon atoms, or 1-methylcyclohexyl or α,α-dimethylbenzyl, R 3 and R 4 ar the same or different and each is an alkyl group having from 1 to 12 carbon atoms or R 3 and R 4 together with the carbon atom to which they are bound form a saturated alicyclic residue having from 5 to 8 carbon atoms or the group of formula: ##STR21## and n is 0 or 1.
Claim 3
Dependent Claim 13 words
A composition as claimed in claim 1, wherein the polymers is a polyolefine.
Claim 4
Dependent Claim 10 words
A composition of claim 2 wherein the polymer is polypropylene.
Claim 5
Dependent Claim 30 words
A composition according to claim 2 wherein the stabilizer is of the formula ##STR22## wherein R is a straight- or branched-chain alkyl group having from 1 to 6 carbon atoms.
Claim 6
Dependent Claim 30 words
A composition according to claim 2 wherein the stabilizer is of the formula ##STR23## wherein R is a straight- or branched-chain alkyl group having from 1 to 6 carbon atoms.
Claim 7
Dependent Claim 10 words
A composition of claim 2 wherein the stabilizer is 2,2,6,6-tetramethylpiperidinyl-4-3',5'-di-t-butyl-4'-hydroxybenzoate.
Claim 8
Dependent Claim 10 words
A composition of claim 2 wherein the stabilizer is 2,2,6,6-tetramethylpiperidinyl-4-β-(3',5'-di-t-butyl-4'-hydroxyphenyl)-propionate.

References Cited (Backward Citations)

US3435065A Cited
US3640928A Cited
US3840494A Cited
US3833636A Cited
US3984371A Cited
US3993655A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-08-28 1982-02-27 1982-08-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-08-28 1986-02-27 1986-08-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-08-28 1990-02-27 1990-08-29 $7700.00 Window Closed / Lapsed

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