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Copolymer emulsions for thickening acrylic polymer latices

Assignee: ISP Investments LLC
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Filing: 1977-02-18
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Granted: 1978-08-29
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Expires: 1997-02-18
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Abstract

Abstract Copolymer emulsions comprising (1) an alpha , beta -unsaturated carboxylic acid and (2) methyl acrylate are useful as thickening agents, particularly in acrylic polymer latices.

Inventors

  • 👤 Eugene S. Barabas
  • 👤 Andrew Klein
  • 👤 Dru W. Alwani

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 02:25
CPC Classifications
C; C08; C08L; C08L33/00

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 75 words
A method for thickening acrylic polymer latices which comprises blending therewith a copolymer latex prepared by inducing, at a temperature of about 5° C. to about 80° C, a redox-initiated polymerization in an aqueous dispersion of, as monomers, (1) from about 30 to about 75 wt. % of an α,β-unsaturated carboxylic acid of the formula ##STR4## in which R is methyl or ethyl, and (2) from about 25 to about 70 wt. % of methylacrylate.
Claim 2
Independent Claim 75 words
A method for thickening acrylic polymer latices which comprises blending therewith a copolymer latex prepared by inducing, at a temperature of about 5° C. to about 80° C, a redox-initiated polymerization in an aqueous dispersion of, as monomers, (1) from about 30 to about 75 wt. % of an α,β-unsaturated carboxylic acid of the formula ##STR4## in which R is methyl or ethyl, and (2) from about 25 to about 70 wt. % of methylacrylate.
Claim 3
Dependent Claim 12 words
A method according to claim 1 in which (1) is methacrylic acid.
Claim 4
Dependent Claim 33 words
A method according to claim 1 in which the range of monomer (1) is from 50 to 65 wt. % and the range of monomer (2) is from 35 to 50 wt. %.
Claim 5
Dependent Claim 13 words
A method according to claim 3 in which monomer (1) is methacrylic acid.
Claim 6
Dependent Claim 31 words
A method according to claim 1 wherein the copolymer latex is blended with the acrylic latex in an amount of from about 0.1 to about 5% on a total solids basis.
Claim 7
Dependent Claim 28 words
A method as defined in claim 5 wherein the copolymer latex is blended in an amount ranging from about 0.5 to about 2% on a total solids basis.

References Cited (Backward Citations)

US3035004A Cited
GB870994A Cited
US3657175A Cited
US3810859A Cited
US3894980A Cited
US3891591A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-08-28 1982-02-27 1982-08-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-08-28 1986-02-27 1986-08-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-08-28 1990-02-27 1990-08-29 $7700.00 Window Closed / Lapsed

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