Patent US4110094A successfully refreshed from Google Patents.
US4110094A
Expired / Lapsed
US
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Method of forming glass fiber
Assignee: PPG Industries Inc
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Filing: 1977-05-10
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Granted: 1978-08-29
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Expires: 1997-05-10
Abstract
Abstract A glass fiber sizing composition comprising a phenolic epoxy resin; the reaction product of a partial ester of a polycarboxylic acid which contains one or more unesterified carboxyl groups with a compound containing more than one epoxy group; a glass fiber lubricant; sufficient emulsifiers to impart a homogeneous mixture; a saturated fatty triglyceride; a silane coupling agent and a major amount of water. Glass fibers sized in accordance with the invention exhibit excellent reinforcing characteristics.
Inventors
- 👤 Donald L. Motsinger
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 18:16
CPC Classifications
C; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26; C03C25/32; C03C25/36
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
147 words
In the method of forming glass fiber strands useful for the reinforcement of resinous articles which comprises drawing glass streams through orifices in a bushing to form individual glass fibers, moving the fibers away from the bushing at a high rate of speed, applying an aqueous sizing solution thereto while they are moving at this speed and gathering the fibers into the form of the strand the improvement comprising: applying as the aqueous sizing solution an aqueous sizing composition comprising a phenolic epoxy resin; the reaction product of a partial ester of a polycarboxylic acid containing one or more unesterified carboxyl groups with a compound containing more than one epoxy group; a dual component emulsifier system having therein a polyethylene glycol emulsifier and a second emulsifier consisting essentially of the reaction product of propylene glycols and ethylene oxide; a silane coupling agent and a saturated fatty triglyceride.
Claim 2
Dependent Claim
147 words
In the method of forming glass fiber strands useful for the reinforcement of resinous articles which comprises drawing glass streams through orifices in a bushing to form individual glass fibers, moving the fibers away from the bushing at a high rate of speed, applying an aqueous sizing solution thereto while they are moving at this speed and gathering the fibers into the form of the strand the improvement comprising: applying as the aqueous sizing solution an aqueous sizing composition comprising a phenolic epoxy resin; the reaction product of a partial ester of a polycarboxylic acid containing one or more unesterified carboxyl groups with a compound containing more than one epoxy group; a dual component emulsifier system having therein a polyethylene glycol emulsifier and a second emulsifier consisting essentially of the reaction product of propylene glycols and ethylene oxide; a silane coupling agent and a saturated fatty triglyceride.
Claim 3
Dependent Claim
23 words
The method of claim 1 wherein said phenolic epoxy resin is a difunctional epoxy resin having a molecular weight of 300 to 400.
Claim 4
Dependent Claim
61 words
The method of claim 1 wherein said reaction product of the partial ester of the polycarobyxlic acid containing one or more unesterified carboxyl groups with the compound containing more than one epoxy group is the reaction product of maleic anhydride, 3,4 epoxy cyclohexylmethyl 3,4 epoxy cyclohexane carboxylate and the monomethylether of polyoxyethyleneglycol said glycol having an average molecular weight of 750.
Claim 5
Dependent Claim
12 words
The method of claim 1 wherein said silane coupling agent is gamma-methacryloxypropyltrimethoxysilane.
Claim 6
Dependent Claim
12 words
The method of claim 1 wherein said silane coupling agent is glycidoxypropyltrimethoxysilane.
Claim 7
Dependent Claim
14 words
The method of claim 1 wherein said saturated fatty triglyceride is hydrogenated corn oil.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-08-28 | 1982-02-27 | 1982-08-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-08-28 | 1986-02-27 | 1986-08-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-08-28 | 1990-02-27 | 1990-08-29 | $7700.00 | Window Closed / Lapsed |