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Decoloration of bisphenol-A recycle stream with cation exchange resin

Assignee: Chiyoda Corp
•
Filing: 1977-05-06
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Granted: 1978-08-15
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Expires: 1997-05-06
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Abstract

Abstract All or part of bisphenol-A process mother liquor recycle stream is contacted with acidic cation exchange resin to remove color bodies. The acidic cation exchange resin is periodically washed and reactivated after use by a mixed phenol/water wash.

Inventors

  • 👤 Frederick Miller Konrad
  • 👤 Stephen Howard Mason

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 13:57
CPC Classifications
C; C07; C07C; C07C39/00; C07C39/12; C07C39/15; C07C39/16

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 176 words
A process for removing color bodies from 4,4'-bisphenol-A process recycle stream wherein a stoichiometric excess of phenol is reacted with acetone in a reaction mixture containing an acid catalyst to produce a product mixture containing phenol and 4,4'-bisphenol-A, wherein said product mixture is separated into a 4,4'-bisphenol-A/phenol adduct and a mother liquor recycle stream, wherein said mother liquor recycle stream is recycled to said reaction mixture, wherein at least a portion of said mother liquor recycle stream is contacted with an adsorbent comprising a substantially insoluble acidic cationic exchange resin for a period of time and at a temperature sufficient to reduce the content of color bodies contained in said mother liquor recycle stream, said temperature being within the range of from about 40° to about 150° C., prior to recycling said mother liquor to said reaction mixture, wherein said absorbent is periodically washed with a phenol/water mixture to remove absorbed color bodies therefrom, and wherein the water content of said absorbent is substantially in equilibrium with the water content of said mother liquor recycle stream.
Claim 2
Dependent Claim 176 words
A process for removing color bodies from 4,4'-bisphenol-A process recycle stream wherein a stoichiometric excess of phenol is reacted with acetone in a reaction mixture containing an acid catalyst to produce a product mixture containing phenol and 4,4'-bisphenol-A, wherein said product mixture is separated into a 4,4'-bisphenol-A/phenol adduct and a mother liquor recycle stream, wherein said mother liquor recycle stream is recycled to said reaction mixture, wherein at least a portion of said mother liquor recycle stream is contacted with an adsorbent comprising a substantially insoluble acidic cationic exchange resin for a period of time and at a temperature sufficient to reduce the content of color bodies contained in said mother liquor recycle stream, said temperature being within the range of from about 40° to about 150° C., prior to recycling said mother liquor to said reaction mixture, wherein said absorbent is periodically washed with a phenol/water mixture to remove absorbed color bodies therefrom, and wherein the water content of said absorbent is substantially in equilibrium with the water content of said mother liquor recycle stream.
Claim 3
Dependent Claim 19 words
The process of claim 1 wherein the phenol/water mixture contains from about 2 to about 70 weight percent water.
Claim 4
Dependent Claim 19 words
The process of claim 1 wherein the phenol/water mixture contains from about 20 to about 50 weight percent water.
Claim 5
Dependent Claim 19 words
The process of claim 1 wherein the phenol/water mixture contains from about 20 to about 30 weight percent water.

References Cited (Backward Citations)

US2861948A Cited
US2911363A Cited
US3049568A Cited
US3049569A Cited
US3221061A Cited
US3896006A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-08-14 1982-02-13 1982-08-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-08-14 1986-02-13 1986-08-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-08-14 1990-02-13 1990-08-15 $7700.00 Window Closed / Lapsed

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